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Aluminium Sulphate Aluminum Sulfate SDS MSDS Sheet

Buy Aluminum Sulfate or Aluminium Sulphate; Door Delivery

Aluminum Sulfate USP; Aluminium Sulphate BP IP FCC ACS Specifications

Aluminum Sulfate SDS MSDS Sheet Material Safety Data Sheet

1. Product Identification

Synonyms: Sulfuric acid, aluminum salt (3:2), octadecahydrate; Cake alum; Patent alum
CAS No.: 10043-01-3 (Anhydrous) 7784-31-8 (Octadecahydrate)
EINECS EC Number: 233-135-0
Molecular Weight: 666.44 (Octadecahydrate)
Chemical Formula: Al2(SO4)3.18H2O
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008:

Skin corrosion/irritation Category 1A, B, C
Specific target organ toxicity – repeated exposure, Oral Category 2
Hazardous to the aquatic environment, acute hazard Category 3

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Health Hazard

GHS Label Elements

Signal Words: Danger

Hazard statements:
H314: Causes severe skin burns and eye damage.
H373: Causes damage to organs through prolonged or repeated exposure.
H402: Harmful to aquatic life.

Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P303 + P361 + P352 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P501: Dispose of contents/ container to an approved waste disposal plant.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xn Harmful, N Dangerous for the environment.
R34 Causes Burns
R48 Danger of serious damage to health by prolonged exposure
R52 Harmful to aquatic organisms
For the full text of the S-statement & R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Ingredient: Aluminum Sulfate; Aluminium Sulphate
CAS No.: 10043-01-3
Percent: 98 - 100%

4. First Aid Measures

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.

5. Fire Fighting Measures

Fire: Aluminium Sulphate is not considered to be a fire hazard.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Keep in mind that addition of water can cause the formation of sulfuric acid.
Hazardous Combustion Products: Forms aluminum oxide, sulfur dioxide and/or sulfur trioxide at temperatures above 760°C (1400°F) or when dry alum is encompassed in a fire involving other burning materials.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to authority requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface drain.

7. Handling and Storage

Keep Aluminum Sulfate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Aluminum sulfate absorbs moisture and becomes a safety hazard when spilled because it absorbs moisture and becomes slippery. Containers of may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
-OSHA Permissible Exposure Limit (PEL):
15 mg/m3 (TWA) total dust and 5 mg/m3 (TWA)
respirable fraction for Aluminum metal as Al.
-ACGIH Threshold Limit Value (TLV):
1 mg/m3 respirable fraction (TWA), Aluminum metal and Insoluble compounds, A4.
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece particulate respirator (NIOSH type N100 filters) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: Aluminium Sulphate is colorless crystals.
Odor: Odorless.
Solubility: 87 g/100 cc water @ 0C (32F).
Specific Gravity: 1.3 to 1.7 depending on hydration level.
pH: 2-4.
% Volatile by volume @ 21C (70F): 0
Boiling Point: No information found.
Melting Point: 87C (189F) Decomposes.
Molecular Formula: Al2O12S3.18H2O
Molecular Weight: 666.4

10. Stability and Reactivity

Stability: Aluminium Sulphate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Hydrolyzes to form dilute sulfuric acid. Toxic and corrosive oxides of sulfur may be formed when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents. Corrosive to metals in the presence of water.
Conditions to Avoid: Heat, Moisture and incompatibles.

11. Toxicological Information
LD50: > 5000 mg/kg (oral rat).
--------\Cancer Lists\-----------------------------------------------
------------------------------- ---NTP Carcinogen--
Ingredient -------------------- Known - Anticipated - IARC Category
------------------------------- ----- - ----------- - -------------
Aluminum Sulfate (10043-01-3) - No ---- No -------- - None

12. Ecological Information

Environmental Fate: No information found.
Environmental Toxicity: No information found.
Mobility in soil: The product is water soluble and may spread in water systems.
Other adverse effects: Toxic to aquatic life with long lasting effects.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

DOT ADR/RID: Not regulated.
IMDG: Not regulated.
IATA: Not regulated.
15. Regulatory Information

TSCA 12(b): Not applicable
SARA 302 Extremely hazardous substance: None present or none present in regulated quantities.
SARA 313: Not applicable
SARA 311/312: Hazardous Categorization: Acute Health Hazard
US. California Proposition 65: No ingredient regulated by CA Prop 65 present.

Canada WHMIS Hazard Class: E Corrosive material

16. Other Information

EINECS EC Number: 233-135-0
H314: Causes severe skin burns and eye damage.
H373: Causes damage to organs through prolonged or repeated exposure.
H402: Harmful to aquatic life.
Xn Harmful, N Dangerous for the environment.
R34 Causes Burns
R48 Danger of serious damage to health by prolonged exposure
R52 Harmful to aquatic organisms
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.


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Last 21 September, 2016

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