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Mubychem Group, established in 1976, is the pioneer manufacturer of Zinc Chloride, Ammonium Chloride, Calcium Chloride, Potassium Chloride, Sodium Acetate, Sodium Thiosulphate, Ammonium Alum, Pharmaceutical, Fragrance & Flavor chemicals in India.  Mubychem Group has several manufacturing facilities spread across Western India.

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Ammonium Alum Manufacturers Aluminum Ammonium Sulfate MSDS

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Aluminum Ammonium Sulfate MSDS Sheet; Material Safety Data Sheet.

1. Product Identification

Synonyms: Aluminum ammonium disulfate dodecahydrate; Aluminum ammonium disulfate, 12-hydrate; Ammonium alum; sulfuric acid aluminum ammonium salt (2:1:1), dodecahydrate
CAS No.: 7784-25-0 (Anhydrous) 7784-26-1 (Dodecahydrate)
Molecular Weight: 453.32
Chemical Formula: AlNH4(SO4)2 . 12H2O

2. Composition/Information on Ingredients

Ingredient: Sulfuric Acid, Aluminum Ammonium Salt (2:1:1) or Aluminum Ammonium Sulfate or Ammonium Alum
CAS No.: 7784-25-0
Percent: 98 - 100%
Hazardous: Yes

3. Hazards Identification

Potential Acute Health Effects:
Hazardous in case of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant).

Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure is not known to aggravate medical condition.
Aluminum Ammonium Sulfate or Ammonium Alum hydrolyzes in water to form sulfuric acid, which is responsible for the irritating effects given below.

4. First Aid Measures

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention.

5. Fire Fighting Measures

Flammability of the Product:  Aluminum Ammonium Sulfate or Ammonium Alum Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.

6. Accidental Release Measures

Cover spill with soda ash and mix. Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill. Wear appropriate personal protective equipment. Pick up and place spills in a suitable container for reclamation or disposal, using a method that does not generate dust.

7. Handling and Storage

Keep  Aluminum Ammonium Sulfate or Ammonium Alum in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of  Aluminum Ammonium Sulfate or Ammonium Alum material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
-OSHA Permissible Exposure Limit (PEL):
15 mg/m3 (TWA) total dust and 5 mg/m3 (TWA)
respirable fraction for Aluminum metal as Al.
-ACGIH Threshold Limit Value (TLV):
1 mg/m3 respirable fraction (TWA), Aluminum metal and Insoluble compounds, A4.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): If the exposure limit of Aluminum Ammonium Sulfate or Ammonium Alum is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: Aluminum Ammonium Sulfate or Ammonium Alum is colorless crystals.
Odor: Odorless.
Solubility: 14% in water, 200% in boiling water
Density: 1.65
pH: 4.6 (0.05M solution)
% Volatiles by volume @ 21C (70F): 0
Boiling Point: 280C (536F) Decomposes.
Melting Point: 94.5C (201F)
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity

Stability: Aluminum Ammonium Sulfate or Ammonium Alum is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Toxic oxides of nitrogen, sulfur dioxide, ammonia, and sulfur trioxide may form at elevated temperatures. Hydrolyzes to form sulfuric acid.
Hazardous Polymerization: Will not occur.
Incompatibilities: Contact with alkalis may release ammonia gas. Corrosive to metals in the presence of water.
Conditions to Avoid: Moisture and incompatibles.

11. Toxicological Information
No LD50/LC50 information found relating to normal routes of occupational exposure.
  --------\Cancer Lists\------------------------------------------------------
                                                                ---NTP Carcinogen---
  Ingredient                                               Known    Anticipated    IARC Category
  ------------------------------------        -----        -----------    -------------
  Sulfuric Acid, Aluminum Ammonium        No          No                    None
  Salt (2:1:1) (7784-25-0)
  Aluminum Ammonium Sulfate or Ammonium Alum

12. Ecological Information

Environmental Fate: No information found.
Environmental Toxicity: No information found.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of Aluminum Ammonium Sulfate or Ammonium Alum container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Not regulated.

15. Regulatory Information

--------\Chemical Inventory Status - Part 1\---------------------------------
  Ingredient                                                               TSCA     EC           Japan       Australia
  -----------------------------------------------       ----         ---           -----        ---------
  Sulfuric Acid, Aluminum Ammonium Salt (2:1:1)     Yes         Yes          Yes         Yes
  (7784-25-0)
 
  --------\Chemical Inventory Status - Part 2\---------------------------------
                                                                                 --Canada--
  Ingredient                                                               Korea      DSL        NDSL     Phil.
  -----------------------------------------------       -----        ---           ----         -----
  Sulfuric Acid, Aluminum Ammonium Salt (2:1:1)     Yes         Yes          No          No
  (7784-25-0)
 
  --------\Federal, State & International Regulations - Part 1\----------------
                                                                                -SARA 302-           ------SARA 313------
  Ingredient                                                               RQ    TPQ              List  Chemical Catg.
  -----------------------------------------                ---   -----                ----  --------------
  Sulfuric Acid, Aluminum Ammonium Salt                No    No                 No         No
  (2:1:1) (7784-25-0)
 
  --------\Federal, State & International Regulations - Part 2\----------------
                                                                                                               -RCRA-  -TSCA-
  Ingredient                                                               CERCLA                261.33     8(d)
  -----------------------------------------                ------                      ------      ------
  Sulfuric Acid, Aluminum Ammonium Salt                No                          No          No
  (2:1:1) (7784-25-0)
  
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: Yes      Chronic: No   Fire: No  Pressure: No
Reactivity: No          (Pure / Solid)
Australian Hazchem Code: None allocated. Poison Schedule: None allocated.

WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
R36/37- Irritating to eyes and respiratory system. S24/25- Avoid contact with skin and eyes. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.

16. Other Information

NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0
Label Hazard Warning:
WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT.
Label Precautions:
Avoid breathing dust.
Keep container closed.
Use only with adequate ventilation.
Wash thoroughly after handling.
Avoid contact with eyes, skin and clothing.
Label First Aid:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, wipe off excess material from skin then immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. In all cases, get medical attention.
Disclaimer:
************************************************************************************************************
Our company provides this Aluminum Ammonium Sulfate or Ammonium Alum MSDS information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This Aluminum Ammonium Sulfate MSDS Sheet or Ammonium Alum MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
************************************************************************************************************

Aluminium Ammonium Sulphate Manufacturers
Ammonium Alum manufacturers:

MUBY CHEMICALS
S-8, SARIFA MANSION, 2ND FLANK ROAD, CHINCHBUNDER, MUMBAI 400009, INDIA
TEL: (OFFICE) 91-22-23770100, 23726950, 23774610, 23723564. FAX: 91-22-23728264

 e-mail: info@mubychem.com

Cell Call to Anmol: +91-9821870100
USA & Canadian Customers may Call 773-829-5811

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Last updated
06 December, 2011

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