Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance & Flavor chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc. The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer.
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Benzoic Acid SDS MSDS Sheet

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Benzoic Acid BP USP IP ACS Analytical Reagent FCC Food grade Manufacturers Specifications

Benzoic Acid SDS MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Benzenecarboxylic acid; benzeneformic acid; phenyl carboxylic acid, phenyl formic acid, dracylic acid.
CAS No.: 65-85-0
EINECS EC Number: 200-618-2
Molecular Weight: 122.12
Chemical Formula: C6H5COOH
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin corrosion/irritation (Category 2) H315
Eye damage (Category 1), H318
Specific target organ toxicity, repeated exposure (Category 1) H372
Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
corrosive.png
Corrosive

GHS Label Elements
healthhazard.png
Health Hazard

Signal Words: Warning

Hazard statements:
H315 Causes skin irritation.
H318 Causes serious eye damage.
H372 Causes damage to organs (Lungs) through prolonged or repeated exposure if inhaled.

Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P314 Get Medical advice/attention if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P360 Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xi Irritant R41 Risk of serious damage to eyes, R21 Harmful in contact with skin, R36/38- Irritating to eyes and skin.

3. Composition/Information on Ingredients

Ingredient: Benzoic Acid
CAS No.: 65-85-0
EINECS EC Number: 200-618-2
Percent: 100%

4. First Aid Measures

Inhalation: If Benzoic Acid is inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice.
Skin Contact: Wash exposed area with soap and water. Get medical advice if irritation develops.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention.

5. Fire Fighting Measures

Fire: Flash point: 121C (250F) CC
Auto ignition temperature: 570C (1058F)
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Minimum exposable concentration 0.011 g/l. Vapor may explode if ignited in an enclosed area. Vapor from molten benzoic acid may form explosive mixture with air.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Neutralize the residue with a dilute solution of sodium carbonate. Finish cleaning by spreading water on the contaminated surface and allow to drain.

7. Handling and Storage

Keep Benzoic Acid in a well closed container stored under cold to warm conditions, 2 to 40 C, (36 to 104F). Protect against physical damage. Isolate from any source of heat or ignition. Isolate from oxidizing materials. Isolate from flammable materials.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: Benzoic Acid is white, needle-like crystals.
Odor: Faint pleasant odor.
Solubility: 0.29 g / 100 ml. water; sinks in water.
Density: 1.32
pH: 2.8 (saturated solution @ 25 0C)
% Volatile by volume @ 21C (70F): 0
Boiling Point: 249C (480F)
Melting Point: 122C (252F)
Vapor Density (Air=1): 4.2
Vapor Pressure (mm Hg): 1 @ 96C (205F)
Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity

Stability: Benzoic Acid is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Emits toxic vapors and gas including phenol, benzene, and carbon monoxide when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents, bases, and metals. Water solutions can react with metals to produce hydrogen gas.
Conditions to Avoid: Heat, flame, ignition sources, dusting and incompatibles.

11. Toxicological Information

Oral rat LD50: 1700 mg/kg; LC50 rat > 26,000mg/L/Hr.; irritation skin rabbit: 500 mg/24H mild; eye rabbit: 100 mg severe; investigated as a mutagen.
--------\Cancer Lists\---------------------------------
---------------------- --NTP Carcinogen--
Ingredient ----------- Known Anticipated IARC Category
---------------------- ----- ----------- -------------
Benzoic Acid (65-85-0) No -- No -------- None

12. Ecological Information

Environmental Fate: When released into the soil, Benzoic Acid may leach into groundwater. When released into the soil, Benzoic Acid is expected to readily biodegrade. When released into the soil, this material is expected to have a half-life between 1 and 10 days. When released into water, Benzoic Acid is expected to readily biodegrade. When released into the water, this material is expected to have a half-life between 1 and 10 days. When released into water, this material is not expected to evaporate significantly. This material has a log octanol-water partition coefficient of less than 3.0. This material may bio accumulation to some extent. When released into the air, this material is expected to be moderately removed from the atmosphere by wet deposition. When released to the air, this material is subject to removal from the atmosphere by gravitational settling.
Environmental Toxicity: No information found.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Benzoic Acid in accordance with legal requirements.

14. Transport Information

DOT (USA) & ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods

15. Regulatory Information

Chemical Weapons Convention: No; TSCA 12(b): No; CDTA: No
SARA 311/312: Acute: Yes; Chronic: No; Fire: Yes Pressure: No Reactivity: No (Pure / Solid)
 Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
DSCL (EEC): R36/38- Irritating to eyes and skin.
HMIS (Perceived):
Health Hazard: 2
Fire Hazard: 1
Reactivity: 0
Personal Protection: E
NFPA (Perceived):
Health: 2
Flammability: 1
Reactivity: 0
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles.

16. Other Information

Disclaimer:
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Our company provides this Benzoic Acid SDS information sheet contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This Benzoic Acid MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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Contact

MUBY CHEMICALS
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TEL: (OFFICE) 91-22-23770100, 23726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

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Last 21 August, 2017

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