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Citric Acid SDS MSDS Sheet

Citric Acid Commercial Pure & BP USP IP ACS Analytical Reagent  FCC Food grade Manufacturers Specifications

Citric Acid SDS MSDS Sheet, Material Safety Data Sheet

Section 1 - Chemical Product and Company Identification

MSDS Name: Citric Acid, Anhydrous
Synonyms: 2-Hydroxy-1,2,3-propanetricarboxylic acid
Intended Use: Oil well fracturing and Industrial use.
Supplier: As per letterhead.

Section 2 - Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Dermal (Category 5)
Skin irritation (Category 3)
Eye irritation (Category 2A)

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

Signal Words: Warning

Hazard statements:
H313: May be harmful in contact with skin.
H316: Causes mild skin irritation
H319: Causes serious eye irritation

Precautionary statements:
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P332+313: If skin irritation occurs: Get medical advice/attention.
P302+ P352 - IF ON SKIN: Wash with plenty of soap and water.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Symbols: Xi
R Phrases: R36 Irritating to eyes.
S Phrases: S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Section 3 - Composition, Information on Ingredients

Chemical Name: Citric acid
CAS#: 77-92-9
EINECS EC Number: 201-069-1
Percent: 99.0

Section 4 - First Aid Measures

Always seek medical attention after first aid measures are provided.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Use agent most appropriate to extinguish fire. Do NOT get water inside containers.

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Very fine particles of Citric acid can cause a fire or explosion. Eliminate all ignition sources. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation. Spill of Citric acid may be neutralized with lime. Do not get water inside containers.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container of Citric acid tightly closed. Avoid ingestion and inhalation. Do not allow contact with water. Keep Citric acid from contact with moist air and steam.
Storage: Store Citric acid in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store Citric acid protected from moisture.

Section 8 - Exposure Controls, Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area of Citric acid.

Section 9 - Physical and Chemical Properties

Appearance: Citric acid is white granules.
Odor: Citric acid is odorless.
Solubility: ca. 60 g/100 ml @ 20C (Anhydrous)
Density: 1.542
pH: 2.2 (0.1 N sol)
% Volatiles by volume @ 21C (70F): 0
Boiling Point: No information found.
Melting Point: ca. 100C (ca. 212F)

Section 10 - Stability and Reactivity

Chemical Stability: Citric acid is stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, dust generation, moisture, exposure to moist air or water.
Incompatibilities with Other Materials: Oxidizing agents, sulfides (inorganic, e.g. ferric sulfide, lead sulfide, sodium sulfide), metal nitrates, alkali carbonates, alkalis, potassium tartrate, acetates, bicarbonates.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

Oral rat LD50: 3 gm/kg; irritation skin rabbit: 500 mg/24H mild; eye rabbit: 750 µg/24H severe.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.

Section 12 - Ecological Information

Environmental Fate: No information found.
Environmental Toxicity: No information found.

Section 13 - Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container of Citric acid and unused contents in accordance with local requirements.

Section 14 - Transport Information

DOT: Not regulated as dangerous goods.
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods

Section 15 - Regulatory Information

USA:
TSCA
: CAS# 77-92-9 is listed on the TSCA inventory.
Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
Section 302 (RQ): None of the chemicals in this material have an RQ.
Section 302 (TPQ): None of the chemicals in this product have a TPQ.
SARA Codes: CAS # 77-92-9: acute. CAS# 77-92-9: 0

Canada
CAS# 77-92-9 is listed on Canada's DSL List. CAS# 77-92-9 is listed on Canada's DSL List.
WHMIS (Canada): Citric acid has a WHMIS classification of D2B.
CAS# 77-92-9 is listed on Canada's Ingredient Disclosure List.

HMIS (Perceived): Health Hazard: 2, Fire Hazard: 1, Reactivity: 0, Personal Protection: E
NFPA (Perceived): Health: 2, Flammability: 1, Reactivity: 0
Protective Equipment:
Gloves (impervious). Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate
respirator when ventilation is inadequate. Safety glasses.

Section 16 - Additional Information

European/International Regulations European Labeling in Accordance with EC Directives:
EINECS EC Number: 201-069-1
H313: May be harmful in contact with skin.
H316: Causes mild skin irritation
H319: Causes serious eye irritation
Xi = Irritant
R36 = Irritating to eyes.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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Last 21 August, 2017

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