Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance & Flavor chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc. The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer.
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Gentian Violet SDS MSDS Sheet

Buy Gentian Violet; Door Delivery

Gentian Violet Manufacturers USP Crystal Violet Manufacturers Specifications

Gentian Violet SDS MSDS Sheet, Crystal Violet Methylrosanilinium Chloride Material Safety Data Sheet

1. Product Identification

Synonyms: Crystal violet; CI Basic Violet 3
CAS No.: 548-62-9
EINECS EC Number: 208-953-6
Molecular Weight: 407.99
Chemical Formula: C25H30ClN3
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral Category 4
Serious eye damage Category 1
Carcinogenicity Category 2  
Hazardous to the aquatic environment, long-term hazard Category 1

Labeling according Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

GHS Label Elements
Health Hazard
Health Hazard

GHS Label Elements
Corrosive
Corrosive

GHS Label Elements
Marine Pollutant
Aquatic Toxicity

Signal Words: Warning

Hazard statements:
H302: Harmful if swallowed.
H318: Causes serious eye damage.
H351: Suspected of causing cancer.
H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P264 Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P281: Use personal protective equipment as required.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330 : Rinse mouth
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Symbols:
Xn Harmful
Xi Irritant
N Dangerous for the environment Harmful
R Phrases:
R21/22 Harmful in contact with skin and if swallowed.
R36/38 Irritating to eyes and skin.
R40 Limited evidence of a carcinogenic effect.
R41 Risk of serious damage to eyes.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrases:
S57 Use appropriate container to avoid environmental contamination.
S60 This material and its container must be disposed of as hazardous waste.
S61 Avoid release to the environment.
S36/37 Wear suitable protective clothing and gloves.
For the full text of the H-statements and  R-phrases mentioned in this Section, see Section 16.

HMIS Perceived: Health: 2, Flammability: 0, Reactivity: 1
NFPA Perceived: Health: 2, Health: 0, Health: 1

3. Composition/Information on Ingredients

Ingredient: Gentian Violet or Hexamethyl-p-rosaniline Chloride
CAS No.: 548-62-9
EINECS EC Number: 208-953-6
Percent
: 90 - 100%

4. First Aid Measures

lways seek medical attention after first aid measures are provided.

Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Ingestion: Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes and wash before reuse. Get medical attention if irritation develops.
Eye Contact: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention immediately.

5. Fire Fighting Measures

Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

Small Spill: Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal authority requirements.
Large Spill:
Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the contaminated surface and allow to drain.

7. Handling and Storage

Keep Gentian Violet in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities. Containers Gentian Violet may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established for Gentian Violet.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: Gentian Violet is dark green powder or greenish glistening pieces having a metallic luster.
Odor: Gentian Violet has slight characteristic odor.
Solubility: Soluble in water.
Specific Gravity: No information found.
pH: No information found.
% Volatile by volume @ 21C (70F): 0
Boiling Point: Not applicable.
Melting Point: 215C (419F)

10. Stability and Reactivity

Stability: Gentian Violet is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: When heated to decomposition it emits toxic fumes of nitrogen oxides and hydrogen chloride.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers.
Conditions to Avoid: Incompatibles.

11. Toxicological Information

Acute toxicity:
LD50 Oral - Mouse - 96 mg/kg
LD50 Oral - Rabbit - 150 mg/kg
LD50 Intraperitoneal - Rat - 8,9 mg/kg
LD50 Intraperitoneal - Mouse - 5,1 mg/kg
LD50 Intraperitoneal - Rabbit - 5 mg/kg
LD50 Intraduodenal - Rabbit - 160 mg/kg
Investigated as a tumorigen, mutagen, reproductive effector.
Carcinogenic Effects: Not a reported carcinogen by IARC NTP ACGIH OSHA.

12. Ecological Information

Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 0,35 mg/l - 48 h
Toxicity to algae: EC50 - Pseudokirchneriella subcapitata - 0,42 mg/l - 72 h
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Gentian Violet in accordance with legal requirements.

14. Transport Information

DOT & ADR/RID
UN/ID no UN3077
Hazard Class 9
Packing Group III
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
Description UN3077, Environmentally hazardous substance, solid, n.o.s. (Crystal Violet), 9, III
Emergency Response Guide Number 171
IMDG
UN/ID no UN3077
Hazard Class 9
Packing Group III
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
Description UN3077, Environmentally hazardous substance, solid, n.o.s. (Crystal Violet), 9, III
Special Provisions 274, 335, 966, 967
EmS-No F-A, S-F
IATA
UN/ID no UN3077
Hazard Class 9
Packing Group III
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
Description UN3077, Environmentally hazardous substance, solid, n.o.s. (Crystal Violet), 9, III

15. Regulatory Information

USA:
TSCA (United States): Listed.
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA): This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories: Acute health hazard: Yes, Chronic Health Hazard: Yes, Fire hazard No, Sudden release of pressure hazard: No, Reactive hazard No.
CWA (Clean Water Act): This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).
Clean Air Act: Not applicable
OSHA Occupational Safety and Health Administration: Not applicable
CERCLA: Not Applicable
California Proposition 65: This product does not contain any Proposition 65 chemicals.

Canada (DSL/NDSL): Listed
WHMIS Hazard Class: D1B Toxic materials, D2B Toxic materials

All of the components in the product are on the following Inventory lists:
Europe (EINECS/ELINCS/NLP) Australia (AICS) South Korea (KECL): China (IECSC) ENCS (Japan): Philippines (PICCS)

16. Other Information

EINECS EC Number: 208-953-6
H302 = Harmful if swallowed.
H318 = Causes serious eye damage.
H351 = Suspected of causing cancer.
H410 = Very toxic to aquatic life with long lasting effects.
Xn = Harmful
Xi = Irritant
N = Dangerous for the environment Harmful
R21/22 = Harmful in contact with skin and if swallowed.
R36/38 = Irritating to eyes and skin.
R40 = Limited evidence of a carcinogenic effect.
R41 = Risk of serious damage to eyes.
R50/53 = Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Contact

MUBY CHEMICALS
S-8, SARIFA MANSION, 2ND FLANK ROAD, CHINCHBUNDER, MUMBAI 400009, INDIA
TEL: (OFFICE) 91-22-23770100, 91-22-23774610
Current Date Time in India GMT+5:30 hours

e-mail: info@mubychem.com

USA & Canadian Customers may
e-mail: usa@mubychem.com
Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

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Last 25 March, 2017

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Gentian Violet ( CAS No, 548-62-9; 603-47-4)
Basic violet 3 (C.I. 42555)
Methylrosanilinium chloride
N-{4-{Bis-[4-(diethylamino)-phenyl]-methylene}-2,5-cyclohexadien-1-ylidene}-N-methylmethanaminium chloride
C.I. 42555
Crystal violet
Gentian violet (C.I. 42555)
Hexamethylpararosaniline chloride
Hexamethyl violet
Methyl violet