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Disodium EDTA, Edetate Disodium SDS MSDS Sheet
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Disodium EDTA Edetate Disodium USP BP IP FCC Food grade Manufacturers Specifications
Disodium EDTA SDS MSDS Sheet, Material Safety Data Sheet Disodium Edetate, Ethylenediaminetetraacetic Acid Disodium Salt
1. Product Identification
Synonyms: (Ethylenedinitrilo) tetra acetic acid disodium salt; Disodium EDTA; disodium dihydrogen ethylenediaminetetraacetate; disodium edetate; N,N'-1,2-ethanediylbis [N-(carboxymethyl)- glycine], disodium salt, dihydrate; Ethylenediaminetetraacetic acid disodium salt.
CAS No.: 139-33-3 (Anhydrous); 6381-92-6 (Dihydrate)
EC EINECS No. 205-358-3
Molecular Weight: 372.24 Dihydrate
Chemical Formula: C10H14O8N2Na2.2H2O Dihydrate
Supplier: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute Toxicity - Oral Category 5
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2B
Specific target organ toxicity - single exposure, respiration Category 3
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Words: Caution
H303: May be harmful if swallowed.
H315: Causes skin irritation.
H320: Causes eye irritation.
H335: May cause respiratory irritation.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352-IF ON SKIN: Wash with plenty of soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P362: Take off contaminated clothing and wash before reuse.
OSHA Hazards: No hazard as per OSHA.
3. Composition/Information on Ingredients
Ingredient: EDTA Disodium; Edetate Disodium
CAS No.: 6381-92-6 (Dihydrate)
Percent: 90 - 100%
4. First Aid Measures
Always seek medical advice after the first aid treatment.
Inhalation: If EDTA Disodium; Edetate Disodium inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists.
5. Fire Fighting Measures
Fire: EDTA Disodium; Edetate Disodium is not considered to be a fire hazard.
Explosion: Disodium EDTA is not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
6. Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal authority requirements.
Large Spill: Use a shovel to put Disodium EDTA into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and swab.
7. Handling and Storage
Keep EDTA Disodium; Edetate Disodium in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers of EDTA Disodium; Edetate Disodium may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance: EDTA Disodium; Edetate Disodium is white crystals.
Odor: Disodium EDTA is odorless.
Solubility: 10 g in 100 g of water.
Density: No information found.
pH: No information found.
% Volatiles by volume @ 21C (70F): 0
Boiling Point: Not applicable.
Melting Point: 252C (486F) Decomposes.
10. Stability and Reactivity
Stability: EDTA Disodium; Edetate Disodium is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents and Metals.
Conditions to Avoid: Incompatibles.
11. Toxicological Information
Anhydrous: Oral rat LD50: 2000 mg/kg. Investigated as a mutagen, reproductive effector. Hydrate: Investigated as a mutagen.
Carcinogenic Effects: Not a reported carcinogen by IARC NTP ACGIH OSHA.
Mutagenic Effects: Animal studies show it as mutagen.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
12. Ecological Information
Toxicity to fish LC50 -
Leuciscus idus (Golden orfe) - > 500 mg/l - 96h; LC50 bluegill: 159 mg/L (Static) 96h
Toxicity to daphnia & other aquatic invertebrates.
EC50 - Daphnia - > 100 mg/l - 24h
Toxicity to algae EC50 - Algae - 10 - 100 mg/l - 72h
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
14. Transport Information
DOT: Not regulated
TDG: Not regulated
IATA: Not regulated
IMDG/IMO: Not regulated
15. Regulatory Information
OSHA Hazards: No hazard as per OSHA.
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
Section 313: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Acute.
TSCA: Listed for Anhydrous Material.
Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
CERCLA Hazardous Substances and corresponding RQs: None of the chemicals in this material have an RQ.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Massachusetts Right To Know Components: No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components: Edetate disodium dihydrate, CAS-No.: 6381-92-6
New Jersey Right To Know Components: Edetate disodium dihydrate, CAS-No.: 6381-92-6
EC EINECS No. 205-358-3
Hazard Symbols: XI
Risk Phrases: R 22 Harmful if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection.
Canada - DSL/NDSL: Listed
Canadian WHMIS Classifications: D2B
CAS# 6381-92-6 is not listed on Canada's Ingredient Disclosure List.
HMIS (Perceived): Health hazard: 1, Flammability: 1, Physical hazards: 0
NFPA (Perceived): Health hazard: 0, Fire: 1, Reactivity Hazard: 0
Australian Hazchem Code: -
Poison Schedule: -
Section 16 - Additional Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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Last 20 July, 2016
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