Potassium Carbonate SDS, MSDS Sheet

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Potassium Carbonate BP USP IP Analytical Reagent FCC Food grade Manufacturers Specifications

Potassium Carbonate SDS, Material Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
05-Dec-20

Section 1: Product and Company Identification

Product Name & Other Names: Potassium Carbonate.
CAS#
: 584-08-7
EINECS EC Number: 209-529-3
Molecular Formula: K2CO3
Molecular Weight: 138.21
Relevant uses and uses advised against (if any):: Industrial Manufacturing.
Supplier: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)

Acute toxicity, oral Category 4, H302
Skin corrosion/irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3, H335

Labeling Regulation EC 1272/2008 (CLP) & GHS

GHS Label Elements
Irritant
Irritant

Signal Words: Warning

Hazards statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P281: Use personal protective equipment as required.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+313: If skin irritation occurs: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.
P501: Dispose of contents/container to an approved agent.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn = Harmful
Xi = Irritant
Risk Phrases:
R22 = Harmful if swallowed.
R36/37/38 = Irritating to eyes, respiratory system, and skin.

Section 3: Composition/Information on Ingredients

Product Name & Other Names: Potassium Carbonate.
CAS#
: 584-08-7
EINECS EC Number: 209-529-3

Section 4: First Aid Measures

Always seek medical attention after first aid measures are provided.
Eye Contact: Immediately flush with copious amounts of water for at least 15 minutes holding the eyelids apart to insure flushing of entire surface.
Skin Contact: Wash contaminated area with copious amounts of water for at least 15 minutes.
Inhalation: Remove to fresh air. Resuscitate if breathing stops. Seek immediate medical attention.
Ingestion: DO NOT INDUCE VOMITING. Seek medical attention.

Section 5: Fire Fighting Measures

Extinguishing Media: Dry chemical, carbon dioxide, foam, water.
Flash point: Not Available
Upper Flammable Limit: Not Available
Lower Flammable Limit: Not Available
Auto ignition Temperature: Not Applicable
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Section 6: Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating as per law.

Section 7: Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, lime, and acids.

Section 8: Exposure Controls, Personal Protection

Exposure Limits: Not Determined.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9: Physical and Chemical Properties

Appearance: Solid. White free flowing powder.
Odor: Odorless.
Odor threshold: Not available.
pH: 11 to 13
Relative density: around 2.43
Melting Point: 891C
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Not available.
Viscosity: Not available.
Molecular Formula: K2CO3
Molecular Weight: 138.21

Section 10: Stability and Reactivity

Chemical Stability: Stable.
Hazardous Polymerization: Will not occur.
Conditions of Chemical Instability: Incompatible Substances: Avoid simultaneous presence of this product and Lime dust. The combination of these chemicals in presence of water or perspiration can cause the formation of caustic potash.

Section 11: Toxicological Information

LD50 Oral - rat - 1.870 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Section 12: Ecological Information

Toxicity to fish: LC50 - Pimephales promelas (fathead minnow) - < 510 mg/l - 96 h
Persistence and Degradability: unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Section 13: Disposal Considerations

Waste Disposal: All waste should be disposed of according to Federal, Provincial, and local regulations. Containers should NOT be reused. Containers Potassium carbonate should be disposed of in accordance with government regulations.

Section 14: Transport Information

DOT USA, TDG Canada & ADR/RID Europe: Not Regulated.
IMDG/IMO: Not dangerous goods.
IATA/ICAO: Not dangerous goods.

Section 15: Regulatory Information

USA:
SARA 302
: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: Not regulated.
SARA 311/312 Hazards: Acute Health Hazard. See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Section 16: Additional Information

European Labeling in Accordance with EC Directives:
H302 = Harmful if swallowed.
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
H335 = May cause respiratory irritation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn = Harmful
Xi = Irritant
Risk Phrases:
R22 = Harmful if swallowed.
R36/37/38 = Irritating to eyes, respiratory system, and skin.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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Last 5 October, 2023

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