Ammonium Fluoride Pure n Analytical Reagent Pure & Analytical Reagent Grade Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Ammonium Fluoride, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.
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Ammonium Fluoride: CAS Number: 12125-01-8, EINECS EC Number: 235-185-9, Molecular Formula: NH4F, Molecular Weight: 37.04, HS Code ---**

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SDS MSDS Sheet of Ammonium Fluoride Manufacturers

Ammonium Fluoride
Pure & Reagent Suppliers
Ammonium Fluoride

Ammonium fluoride is the inorganic compound with the formula NH4F. It has a sharp saline taste, and is soluble in water. It is used for preserving wood, as a mothproofing agent, in printing and dying textiles, and as an antiseptic in breweries and glass industry.

Specifications of Commercial Pure Ammonium Fluoride:
Melting Point: 100C (decomposes)
Solubility in water: 45.3 g/100 ml (25C)
Solubility: slightly soluble in alcohol, insoluble in liquid ammonia
Assay: 98.0% minimum
Appearance: White crystalline solid hygroscopic
pH: 6.8 to 8.0
Cd: 0.0005% maximum
Cl: 0.0005% maximum
Cu: 0.0005% maximum
Fe: 0.0005% maximum
K: 0.002% maximum
Na: 0.002% maximum
Pb: 0.0005% maximum
SO4: 0.005% maximum
Zn: 0.0005% maximum.


Ammonium Fluoride Analytical Reagent Grade:
NH4F --- Formula Wt 37.04 --- CAS Number 12125-01-8

REQUIREMENTS
Assay: 98% NH4F minimum.

MAXIMUM ALLOWABLE
Insoluble matter: 0.005%
Residue after ignition: 0.01%
Chloride (Cl): 0.001%
Sulfate (SO4): 0.005%
Heavy metals (as Pb): 5 ppm
Iron (Fe): 5 ppm.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade Reagent Grade product, please check with the respective web-pages or books.

We manufacture and supply Fluoride products as under:

Ammonium Bifluoride

Ammonium Fluoride

Ammonium Silicofluoride

Calcium Fluoride

Chromium Fluoride

Potassium Fluoride

Sodium Fluoride

Sodium Silico Fluoride

Sodium, Potassium, Lithium Cryolite

Stannous Fluoride

Strontium Acetate Carbonate Fluoride Nitrate Sulfate.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

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Last 1 October, 2023

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Ammonium Fluoride SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet
30-Sep-20

1. Product Identification

Product Name & Other Names: Ammonium Fluoride.
CAS No.: 12125-01-8
EINECS Number: 235-185-9
Molecular Weight: 37.04
Chemical Formula: NH4F
Relevant uses and uses advised against (if any): Laboratory Chemicals and Industrial Manufacturing Use.
Supplier: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute oral toxicity Category 3 H301
Acute toxicity, Dermal (Category 3) H311
Skin irritation Category 2 H315
Eye irritation Category 2A H319
Acute toxicity, Inhalation (Category 3) H331

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

GHS Label Elements
toxic.png
Toxic

Signal Word: Danger

Hazard statements:
H301+H311+H331: Toxic if swallowed, if inhaled or in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Precautionary statements:
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink, or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+313: If skin irritation occurs: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T = Toxic
Xi = Irritant
Risk Phrases:
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R36/38 Irritating to eyes and skin.

3. Composition/Information on Ingredients

Product Name & Other Names: Ammonium Fluoride.
CAS No.: 12125-01-8
EINECS Number: 235-185-9

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used. Wash clothing & Shoes before reuse. Get medical attention.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.
Notes to Physician: Treat symptomatically.

5. Fire Fighting Measures

Flash Point: Not applicable
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Decomposition Products: Fumes along with Nitrogen oxides (NOx) Ammonia Gaseous Hydrogen fluoride.
Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.
Large Spill: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, acid, and bases. Cannot be stored in ceramic and glass bottles.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
USA-OSHA PEL: (Vacated) TWA 2.5 mg/m3
USA-NIOSH: TWA 2.5 mg/m3
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: White to off-white powder.
Odor: Practically odorless; slight ammoniacal.
Odor threshold: Not available.
pH: 6 to 8.
Relative density: around 1
Melting Point: 100C decomposes.
Initial boiling point and boiling range
: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Viscosity: Not available.
Molecular Weight: 37.04
Chemical Formula: NH4F

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Fumes along with Nitrogen oxides (NOx) Ammonia Gaseous Hydrogen fluoride may be released.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidants, acid and bases. Cannot be stored in ceramic and glass bottles.
Conditions to Avoid: Hygroscopic. Heat, Direct sunlight, Moisture, and Incompatibles.

11. Toxicological Information

Acute toxicity: Toxic in contact with skin. Toxic if inhaled. Toxic if swallowed.
LD50 Oral - Rat: > 200 - < 2,000 mg/kg mg/kg.
LD50 Intraperitoneal - Rat: 31 mg/kg
Carcinogenicity: IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans.
Reproductive toxicity: No information found.
Developmental Effects: No information found.
Teratogenicity: No information found.
The toxicological properties have not been fully investigated.

12. Ecological Information

Toxicity to fish: LC50: = 364.0 mg/L, 96h static (Pimephales promelas).
Environmental Toxicity: Toxic to aquatic organisms.
Persistence and Degradability: Soluble in water Persistence is unlikely based on information available.
Bioaccumulation/ Accumulation: No information available.
Mobility: Will likely be mobile in the environment due to its water solubility.
Results of PBT and vPvB assessment: Not available.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

14. Transport Information

DOT USA:
UN number: 2505, Class: 6.1, Packing group: III
Proper shipping name: AMMONIUM FLUORIDE
IMDG & IATA:
UN number: 2505, Class: 6.1, Packing group: III
Proper shipping name: AMMONIUM FLUORIDE
ADT/RID Europe:
UN number: 2505, Class: 6.1, Packing group: III
Proper shipping name: AMMONIUM FLUORIDE

15. Regulatory Information

USA:
Section 313
: Listed.
SARA 311/312 Hazard Categories: Acute & Chronic Health Hazard. See section 2.
California Proposition 65: This product does not contain Proposition 65 chemicals.

Section 16 - Additional Information

European Labeling in Accordance with EC Directives:
H301+H311+H331: Toxic if swallowed, if inhaled or in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T = Toxic
Xi = Irritant
Risk Phrases:
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R36/38 Irritating to eyes and skin.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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