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Chromium picolinate USP & Pure Grade Manufacturers, SDS GHS MSDS Sheet
Chromium Picolinate: CAS Number: 14639-25-9, EINECS EC Number: ---, Molecular Formula: Cr(C6H4NO2)3, Molecular Weight: 418.33 HS Code ---**
For MSDS Sheet Click
SDS MSDS Sheet of Chromium Picolinate Manufacturers
Pure & USP Grade
Chromium (III) picolinate (CrPic3) is a pinkish-red compound sold as a nutritional supplement to treat type 2 diabetes and promote weight loss. Small quantities of chromium are needed for glucose utilization by insulin in normal health, but deficiency is extremely rare and has only been observed in hospital patients on long-term defined diets.
Chromium Picolinate USP Grade
C18H12N3O6Cr -- 418.31
Chromium Picolinate contains not less than 98.0 percent and not more than 102.0 percent of C18H12N3O6Cr, calculated on the dried basis.
Packaging and storage: Preserve in tight containers.
A: Infrared Absorption.
B: To 5 mL of a solution (1 in 250) in a test tube add 1 mL of 5 N sodium hydroxide and 10 drops of 30% hydrogen peroxide, and heat gently for about 2 minutes: a yellow color develops.
Loss on drying: Dry it at 105C for 4 hours: it loses not more than 4.0% of its weight.
Chloride: Dissolve 30 mg of Chromium Picolinate in 30 to 40 mL of water, and heat to 70C. Cool overnight, and filter to remove the precipitate. Add 1 mL each of nitric acid and silver nitrate TS, and add sufficient water to make 50 mL. Mix, and allow to stand for 5 minutes, protected from direct sunlight: any turbidity formed is not greater than that produced in a similarly treated control solution containing 0.25 mL of 0.002 N hydrochloric acid (0.06%).
Sulfate: Dissolve 100 mg of Chromium Picolinate in 30 to 40 mL of water, and heat to 90C. Cool overnight, and filter to remove the precipitate. Add 1 mL of 3 N hydrochloric acid, 3 mL of barium chloride, and sufficient water to make 50 mL. Mix, and allow to stand for 10 minutes: any turbidity formed is not greater than that produced in a similarly treated control solution containing 0.2 mL of 0.02 N sulfuric acid (0.2%).
Standard stock solution: Transfer about 0.283 g of potassium dichromate, previously dried at 120C for 4 hours and accurately weighed, to a 1000-mL volumetric flask, dissolve in and dilute with water to volume to obtain a solution having a known concentration of about 100 µg of chromium per mL, and mix. Store in a polyethylene bottle.
Standard preparations: Separately transfer 1.0 mL and 2.0 mL of the Standard stock solution to 100-mL volumetric flasks, and transfer 1.5 mL and 2.0 mL of the Standard stock solution to separate 50-mL volumetric flasks. Add 1.0 mL of nitric acid to each flask, dilute the contents of each flask with water to volume, and mix. These Standard preparations contain 1.0, 2.0, 3.0, and 4.0 µg of chromium per mL, respectively.
Assay preparation: Transfer about 200 mg of Chromium Picolinate, accurately weighed, to a 500-mL volumetric flask, and add 25 mL of water. Slowly add 10 mL of nitric acid, and boil for 10 minutes with constant swirling. Cool the solution, dilute with water to volume, and mix. Filter a portion of the solution, and transfer 5 mL of the filtrate to a 100-mL volumetric flask. Add 1 mL of nitric acid, dilute with water to volume, and mix.
Procedure: Concomitantly determine the absorbances of the Standard preparations and the Assay preparation at the chromium emission wavelength of 357.9 nm, with a suitable atomic absorption spectrophotometer equipped with a chromium hollow-cathode lamp and an air–acetylene flame, using diluted nitric acid as the blank. Plot the absorbances of the Standard preparations versus chromium concentration, in µg per mL, and draw the straight line best fitting the four plotted points. From the graph so obtained, determine the chromium concentration, in µg per mL, in the Assay preparation. Calculate the quantity, in mg, of C18H12N3O6Cr in the portion of Chromium Picolinate taken by the formula:
(418.31 / 51.996)(10C)
in which C is the concentration, in µg per mL, of chromium in the Assay preparation; 418.31 is the molecular weight of chromium picolinate; and 51.996 is the atomic weight of chromium.
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Last : 22 March, 2017
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Chromium Picolinate GHS SDS, MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Synonyms: Chromium Tripicolinate
CAS No.: 14639-25-9
EINICS EC-No.: --
Molecular Weight: 418.33
Chemical Formula: Cr(C6H4NO2)3
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3
Labelling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Words: Warning
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P362: Take off contaminated clothing and wash before reuse.
P302+ P352 - IF ON SKIN: Wash with plenty of soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P501: Dispose of contents/container to authorised agents only.
Labelling in accordance with Directive 67/548/EEC:
Symbols: Xi Irritant
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.
HMIS (Perceived): Health hazard: 2, Flammability: 0, Physical hazards: 0
NFPA (Perceived): Health hazard: 2, Fire: 0, Reactivity Hazard: 0
3. Composition/Information on Ingredients
Ingredient: Chromium Picolinate
CAS No.: 14639-25-9
4. First Aid Measures
Always get medical attention after the first aid is over.
Inhalation: If Chromium Picolinate is inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and get medical attention immediately.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing and shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Fire: Not a fire hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
6. Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Corrosive solid. Stop leak if without risk. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources.
7. Handling and Storage
Keep Chromium Picolinate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of Chromium Picolinate may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. Avoid dust formation.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance: Chromium Picolinate is dark violet crystals or powder.
Solubility: Very slightly soluble in water.
Melting point/freezing point: > 300C literature
% Volatile by volume @ 21C (70F): 0
Molecular Weight: 418.33
Chemical Formula: Cr(C6H4NO2)3
10. Stability and Reactivity
Stability: Chromium Picolinate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide and monoxide, Nitrogen oxides, Chromium oxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Excessive heat, strong oxidizers & reducing agents, acids and bases.
Conditions to Avoid: Heat, dusting and incompatibles.
11. Toxicological Information
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH, OSHA.
12. Ecological Information
Toxicity to fish and daphnia and other aquatic invertebrates: NA
Mobility in soil: No data available.
PBT & vPvB: No data available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Chromium Picolinate in accordance with legal requirements.
14. Transport Information
DOT: Not regulated
TDG: Not regulated
IATA: Not regulated
IMDG/IMO: Not regulated
ADR/RID: Not regulated
15. Regulatory Information
SARA 313: Not applicable
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
CERCLA: Not applicable
California Proposition 65: This product does not contain any Proposition 65 chemicals
Canada WHMIS Hazard: CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
16. Other Information
EINICS EC-No.: 230-022-8
Xi = Irritant
R36/37/38 = Irritating to eyes, respiratory system and skin.
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
H335 =May cause respiratory irritation.
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.