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Iron III, Ferric Sulfate USP Pure AR LR ACS Analytical Reagent FCC Food Grade Manufacturers, SDS MSDS Sheet
Ferric Sulfate CAS Number 10028-22-5, 15244-10-7 (monohydrate), EINECS EC Number 233-72-9, HS Code ---**; Molecular Weight 399.88 g/mol (anhydrous), 489.96 g/mol (pentahydrate), 562.00 g/mol (nonahydrate), Molecular Formula: Fe2(SO4)3 (anhydrous)
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MSDS Sheet of Ferric Sulfate Manufacturers
Iron (III) sulfate (or ferric sulfate), is the chemical compound with the formula Fe2(SO4)3, the sulfate of trivalent iron. Usually yellow, it is a rhombic crystalline salt and soluble in water at room temperature. It is used in dyeing as a mordant, and as a coagulant for industrial wastes.
Ferric Sulfate USP
Fe2(SO4)3xH2O (anhydrous) 399.88
Ferric tersulfate [10028-22-5].
Ferric Sulfate is hydrated Fe2(SO4)3. It contains not less than 73.0 percent and not more than 80.0 percent of Fe2(SO4)3.
Identification: Dissolve 0.5 g in a mixture of 50 mL of water and 3 mL of hydrochloric acid: this solution meets the requirements for the Ferric Salts test under Iron.
Limit of insoluble matter: Transfer 10 g in a covered beaker, and dissolve in a mixture of 100 mL of water and 5 mL of sulfuric acid. Heat to boiling, and warm on a steam bath for 1 hour. Filter the hot solution through a tared sintered-glass crucible of fine porosity. Wash the beaker and the filter with hot water, dry the crucible at 105 , cool in a desiccator, and weigh: not more than 2 mg of insoluble matter is found (0.02%).
Limit of chloride: 0.002%.
Limit of ferrous iron: Dissolve 4 g by warming with 50 mL of dilute sulfuric acid (1 in 10), cool, and titrate with 0.1 N potassium permanganate: not more than 0.16 mL is required to produce a permanent pink color (0.02% as Fe++).
Limit of copper: 0.005%.
Limit of zinc: 0.01%.
Limit of nitrate: 0.01%.
Substances not precipitated by ammonia: 0.1%.
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Last 22 March, 2017
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Ferric Sulphate SDS MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Synonyms: Iron(III) Sulphate
CAS No.: 10028-22-5 (anhydrous), 15244-10-7 (monohydrate)
EINECS: EC Number: 233-72-9
Molecular Weight: 399.88 g/mol (anhydrous), 489.96 g/mol (pentahydrate), 562.00 g/mol (nonahydrate)
Chemical Formula: Fe2(SO4)3 (anhydrous)
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Corrosive to Metals Category 1
Acute toxicity, oral Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Labeling according Regulation (EC) No 1272/2008
GHS Label Elements
GHS Label Elements
Signal Words: Danger
H290: May be corrosive to metals.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H401: Toxic to aquatic life.
P234: Keep only in original container.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P362: Take off contaminated clothing and wash before reuse.
P390: Absorb spillage to prevent material damage.
P404: Store in a closed container.
P501: Dispose of contents/container to authorized agents only.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
R22: Harmful if swallowed.
R38: Irritating to skin.
R41: Risk of serious damage to eyes.
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.
3. Composition/Information on Ingredients
Ingredient: Ferric Sulphate
CAS No.: 10028-22-5 (anhydrous), 15244-10-7 (monohydrate)
EINECS: EC Number: 233-72-9
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Treat symptomatically.
5. Fire Fighting Measures
Flammability of the Product: The product is not flammable.
Products of Combustion: It forms oxides of iron, sulphuric acid and toxic fumes when heated to decomposition.
Fire: Non flammable.
Explosion: not known.
Fire Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide.
Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.
6. Accidental Release Measures
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water and swab.
7. Handling and Storage
Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Ferric Sulphate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage or contact with oxidizing material and combustible substances. Avoid moisture and store away from water sources. It is to be stored in corrosive area.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established. Assure it as below 2mg/m3.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Ferric Sulphate is yellowish to grayish solid.
pH: Not available.
Density: 3.1 gm/cc
Molecular Weight: 162.2
Chemical Formula: Fe2(SO4)3
% Volatile by volume @ 21C (70F): 0
Melting Point: Decomposes at 480C
10. Stability and Reactivity
Stability: Ferric Sulphate is stable under ordinary conditions of use and storage. It must be kept in air tight containers.
Hazardous Decomposition Products: It produces oxides of iron along with sulphuric acid when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, Forms shock-sensitive mixtures with certain other materials., Sodium/sodium oxides, Potassium. Exothermic in contact with water.
Conditions to Avoid: Moisture, Heat, Sun light, Incompatibles.
11. Toxicological Information
Toxicity to Animals:
LD50 Oral - Rat - 500 to 2000 mg/kg
Carcinogenic Effects: Not a reported carcinogen by IARC NTP ACGIH OSHA.
12. Ecological Information
Toxicity to fish: Not available
Biodegradability: Not available.
BOD5 and COD: Not available.
Environmental Fate: No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Ferric Sulphate in accordance with federal, state and local requirements.
14. Transport Information
DOT (US) & ADR/RID: Not listed
IMDG: Not listed
IATA: Not listed
15. Regulatory Information
SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard
Canada WHMIS Classification: Not a controlled product.
CAS# 10028-22-5 is listed on Canada's DSL List
16. Other Information
EINECS EC Number: 231-729-4
Xn = Harmful
R22 = Harmful if swallowed.
R38 = Irritating to skin.
R41 = Risk of serious damage to eyes.
H290 = May be corrosive to metals.
H302 = Harmful if swallowed.
H315 = Causes skin irritation.
H318 = Causes serious eye damage.
H401 = Toxic to aquatic life.
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.