Glacial Acrylic Acid or Acroleic acid or Ethylenecarboxylic acid or Propenoic acid Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Glacial Acrylic Acid, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Glacial Acrylic Acid or Acroleic acid or Ethylenecarboxylic acid or Propenoic acid: CAS Number: 79-10-7, EINECS EC Number: 201-177-9, Molecular Formula: C3H4O2 or CH2=CHCOOH, Molecular Weight: 72.06, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Glacial Acrylic Acid or Acroleic acid or Ethylenecarboxylic acid or Propenoic acid.

Acrylic acid or Propenoic acid is an organic compound with the formula CH2=CHCOOH. Glacial acrylic acid is a clear, colorless liquid with a characteristic acrid odor. It is miscible with water, alcohols and ethers. This colorless liquid has a characteristic acrid or tart smell. It is miscible with water, alcohols, ethers, and chloroform. Acrylic acid is used in the production of coatings, elastomers, adhesives, thickeners, superabsorbents, acrylic esters, and fiber sizing.

Specifications of Glacial Acrylic Acid or Acroleic acid or Ethylenecarboxylic acid or Propenoic acid:
Purity GC: 99.8 % minimum
Inhibitor (MEHQ): 180 – 220 ppm MEHQ
Boiling Point: 141C
Melting Point: 13C
Water Content: 1000 ppm maximum.

MUBY CHEMICALS
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Exporters to USA Canada UAE Europe South Africa Tanzania Kenya Uganda Egypt Nigeria Turkey Mexico Brazil Argentina Chile Dubai etc.

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Acrylic acid or Propenoic acid SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 22-Oct-20

Product Name & Other Names: Glacial Acrylic Acid or Acroleic acid or Ethylenecarboxylic acid or Propenoic acid
CAS No.: 79-10-7.
EINECS EC Number: 201-177-9
Molecular Formula: C3H4O2 or CH2=CHCOOH
Molecular Weight: 72.06
Relevant uses and uses advised against (if any): Laboratory and Industrial Use.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable liquids Category 3, H226
Acute toxicity, oral Category 4, H302
Acute toxicity, dermal Category 4, H312
Acute toxicity, inhalation Category 4, H332
Skin corrosion (Category 1A), H314
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Short-term (acute) aquatic hazard (Category 1), H400

Hazard Statements:
H226: Flammable liquid and vapor.
H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled
H314: Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.

Precautionary Statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P310: IF SWALLOWED: Immediately call a POSION CENTER or doctor/physician.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P370+378: In case of fire: Use Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Do not use a solid water stream as it may scatter and spread fire.
P403+233+235: Store in a well ventilated place. Keep container tightly closed. Keep cool.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
F Flammable
Xi Harmful
C Corrosive
N Dangerous for the environment.
Risk Phrase:
R10 Flammable.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R35 Causes severe burns.
R41 Risk of serious damage to eyes.
R50 Very toxic to aquatic organisms.

Product Name & Other Names: Glacial Acrylic Acid or Acroleic acid or Ethylenecarboxylic acid or Propenoic acid
CAS No.: 79-10-7.
EINECS EC Number: 201-177-9

Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention.
Ingestion: Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Use a mild soap if available. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. For minor skin contact, avoid spreading material on unaffected skin.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Flammable. Containers may explode when heated.
Products of Combustion: Carbon oxides and fumes.
Fire Extinguishing Media: Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Do not use a solid water stream as it may scatter and spread fire. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Special Information: Fire may produce irritating, corrosive and/or toxic gases. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
Keep away from heat and sources of ignition. Flash back possible over considerable distance. Beware of vapors accumulating to form explosive concentrations .Vapors can accumulate in low areas.

Personal precautions: Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering. Keep out of low areas.
Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Methods for containment: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Vapors can accumulate in low areas.
Dike the spilled material, where this is possible. Prevent entry into waterways, sewers, basements or confined areas.
Methods for cleaning up: Clean up in accordance with all applicable regulations. Should not be released into the environment.
Small Spill: Avoid dust/mist formation. Avoid breathing dust/mist. Ensure adequate ventilation. Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly.
Large Spill: Dike far ahead of liquid spill for later disposal. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal.

Precautions for safe handling: Do not handle or store near an open flame, heat or other sources of ignition. All equipment used when handling the product must be grounded. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces. Avoid prolonged exposure.
Conditions for safe storage, including any incompatibilities: Keep away from heat and sources of ignition (spark or flame). Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents, chlorine.

Airborne Exposure Limits: Exposure guidelines have not been established for this product. Available exposure limit as per Australia Exposure Standards is shown below:
5.9 mg/m3 / 2 TWA ppm as per Australia Exposure Standards
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Clear and colorless liquid.
Odor: Characteristic acrid or tart smell.
Odor threshold: Not available.
pH: around 2.
Relative density: 1.05
Boiling point: 141C
Melting point/Freezing point: 13C
Flash Point: 46C
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Miscible with water, alcohols, ethers, and chloroform.
Viscosity: Not available.
Molecular Formula: C3H4O2 or CH2=CHCOOH
Molecular Weight: 72.06

Stability: It is stable under ordinary conditions of use and storage. Reacts violently in contact with acids, amines, driers, polymerization accelerators and easily oxidized materials., Polymerization can occur.
Hazardous Decomposition Products: It emits toxic fumes when heated to decomposition.
Hazardous Polymerization: Polymerization can occur.
Incompatibilities: Oxidizing agents, chlorine.
Conditions to Avoid: Avoid heat, sparks, open flames and other ignition sources. Avoid metals like Copper, Nickel, Mild steel, Zinc etc. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Eyes: Causes serious eye irritation.
Skin: Harmful in contact with skin. May causes skin burns. Harmful if absorbed through skin.
Ingestion: Toxic if swallowed. Causes digestive tract burns.
Inhalation: Toxic if inhaled. Inhalation.
Toxicity data:
LD50 Dermal - Rabbit - male - 1.000 mg/kg
Carcinogenicity: Not expected to be hazardous by IARC criteria.
Local effects: Harmful if swallowed. Harmful if inhaled or absorbed through the skin. Irritating to eyes, respiratory system and skin. Causes serious eye damage.

Toxicity to fish: LC50 - Oncorhynchus mykiss (rainbow trout) - 27 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates: EC5 - E.sulcatum - 20 mg/l - 72 h
Toxicity to algae: NOEC - Chlorella vulgaris (Fresh water algae) - 0,2 mg/l - 72 h
Ecotoxicity: Components of this product have been identified as having potential environmental concerns.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

Department of Transportation DOT USA, TDG Canada & ADR RID Europe:
Proper shipping name: ACRYLIC ACID, STABILIZED.
Class: 8 (3).
UN number: 2218
Packing group: II
IMDG & IATA:
Proper shipping name: ACRYLIC ACID, STABILIZED.
Class: 8 (3).
UN number: 2218
Packing group: II

USA:
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: Fire Hazard, Acute Health Hazard
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European/International Regulations European Labeling in Accordance with EC Directives
H226: Flammable liquid and vapor.
H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled
H314: Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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