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Iodoform USP Grade Manufacturers, SDS GHS MSDS Sheet

Iodoform: CAS Number: 75-47-8, EINECS EC Number: 200-874-5, Molecular Formula: CHI3, Molecular Weight: 393.73, HS Code ---**

For SDS MSDS Sheet Click
SDS MSDS Sheet of Iodoform Manufacturers

Iodoform
Pure USP Grade
Iodoform

Iodoform is the organoiodine compound with the formula CHI3. A pale yellow, crystalline, volatile substance, it has a penetrating and distinctive odor sometimes referred to as the smell of hospitals, sweetish taste. It is occasionally used as a disinfectant.

Iodoform USP Grade
or Triiodomethane
CHI3 393.73 [75-47-8].

Iodoform, previously dried over silica gel for 24 hours, contains not less than 99.0 percent and not more than 100.5 percent of CHI3.
Packaging and storage: Preserve in tight, light-resistant containers, store at controlled room temperature, and prevent exposure to excessive heat.

Identification: Heat 0.1 g: a purple gas is evolved.
Loss on drying: Dry it over silica gel for 24 hours: it loses not more than 0.5% of its weight.
Residue on ignition: not more than 0.1%.
Coloring matter, acids, and alkalies: Shake about 2 g of it with 5 mL of water for 1 minute, and filter: the filtrate is colorless and is neutral to litmus.
Chloride: Shake 3.0 g of powdered Iodoform with 75 mL of water for 1 minute, allow to stand, and filter the supernatant. To 25 mL of the filtrate add 6 mL of 3 N nitric acid, and dilute with water to 40 mL. This solution shows no more chloride than corresponds to 0.15 mL of 0.020 N hydrochloric acid (0.011%).
Sulfate: To 25 mL of the filtrate obtained in the test for Chloride add 1 mL of 3 N hydrochloric acid, and dilute with water to 40 mL. This solution shows no more sulfate than corresponds to 0.17 mL of 0.020 N sulfuric acid (0.017%).
Assay: Transfer about 200 mg of Iodoform, previously dried over silica gel for 24 hours and accurately weighed, to a 500-mL glass-stoppered conical flask. Add 20 mL of alcohol, and swirl to dissolve. Add 30.0 mL of 0.1 N silver nitrate and 10 mL of nitric acid, insert the stopper, and allow it to stand in a dark place for 16 hours. Add 150 mL of water and 5 mL of ferric ammonium sulfate and titrate the excess silver nitrate with 0.1 N ammonium thiocyanate. Perform a blank determination. Each mL of 0.1 N silver nitrate is equivalent to 13.124 mg of CHI3.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) 91-22-23770100, 23726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA & Canadian Customers may
e-mail: usa@mubychem.com
Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

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Last 19 September, 2017

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Iodoform Oil SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Product name: Iodoform
CAS No.: 75-47-8
EINECS EC Number: 200-874-5
Molecular Formula: CHI3
Molecular Weight: 393.73
Intended use: Laboratory and Industrial Use.
Supplier: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity,oral Category 4
Acute toxicity, dermal Category 4
Acute toxicity, inhalation Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Hazardous to the aquatic environment, long-term hazard Category 2

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
irritant.png
Irritant

GHS Label Elements
marinepollutant.png
Aquatic Toxicity

Signal Words: Danger

Hazard Statements:
H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H411: Toxic to aquatic life with long lasting effects.

Precautionary Statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P310: IF SWALLOWED: Immediately call a POSION CENTER or doctor/physician.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P403+233+235: Store in a well ventilated place. Keep container tightly closed. Keep cool.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xn Harmful, N Dangerous for the environment.
R20/22 Harmful by inhalation and if swallowed
R36/37/38, Risk Phrase: Irritating to eyes, respiratory system and skin
R51/53            Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrases:
S2 Keep out of the reach of children
S24/25 - Avoid contact with skin and eyes.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection
S29/35 Do not empty into drains; dispose of this material and its container in a safe way

3. Composition/Information on Ingredients

Product name: Iodoform
CAS No.: 75-47-8
EINECS EC Number: 200-874-5

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention.
Ingestion: Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Use a mild soap if available. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. For minor skin contact, avoid spreading material on unaffected skin.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Products of Combustion: Carbon oxides, hydrogen iodide and fumes.
Fire Extinguishing Media: Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Do not use a solid water stream as it may scatter and spread fire. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Special Information: Fire may produce irritating, corrosive and/or toxic gases. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

Personal precautions: Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering. Keep out of low areas.
Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Methods for containment: Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable.
Dike the spilled material, where this is possible. Prevent entry into waterways, sewers, basements or confined areas.
Methods  for  cleaning  up: Clean up in accordance with all applicable regulations. Should not be released into the environment.
Small Spill: Avoid dust/mist formation. Avoid breathing dust/mist. Ensure adequate ventilation. Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly.
Large Spill: Dike far ahead of liquid spill for later disposal. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal.

7. Handling and Storage

Handling: Do not handle or store near an open flame, heat or other sources of ignition. All equipment used when handling the product must be grounded. Use only with adequate ventilation. Wash thoroughly after handling. Avoid prolonged exposure. Do not empty into drains. Avoid release to the environment.
Storage: Keep away from heat and sources of ignition (spark or flame). Keep containers tightly closed in a cool, well-ventilated place. Store in a closed container away from incompatible materials. Use care in handling/storage. Store in accordance with local/regional/national/international regulation.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:

Components Type Value
75-47-8

USA ACGIH TWA

0.6 ppm or 10 mg/m3

Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Physical state: Solid.
Color: Light Yellow.
Odor: Unpleasant.
pH: NA
Boiling  point: Not available.
Melting  point/Freezing  point: 118 to 121C
Solubility  (water): Practically insoluble.
Specific gravity: 4.08

10. Stability and Reactivity

Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents, strong bases and alkali metals.
Conditions to Avoid: Avoid heat, sparks, open flames and other ignition sources. Contact with incompatible materials..

11. Toxicological Information

Eyes: Causes serious  eye irritation.
Skin: Harmful in contact with skin.
Ingestion: Toxic if swallowed. Causes digestive tract burns.
Inhalation: Toxic if inhaled. Inhalation.
Toxicity data:
LD50 Oral - Rat - 355 mg/kg
Carcinogenicity: Not expected to be hazardous by OSHA criteria.
Sensitization: May cause sensitization by skin contact.
Local  effects: Harmful if swallowed. Harmful if inhaled or absorbed through the skin. Irritating to eyes, respiratory system and skin. Causes serious eye irritation.

12. Ecological Information

Toxicity to fish: LC50 - Pimephales promelas (fathead minnow) - 2.92 mg/l - 96 h
Ecotoxicity: Components of this product have been identified as having potential environmental concerns.
Environmental effects: Hazardous to the aquatic environment, long-term hazard.
Aquatic toxicity: May cause long-term adverse effects in the aquatic environment.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Department of Transportation (DOT) Requirements Bulk:
Not dangerous goods.

15. Regulatory Information

USA:
SARA 302 Components
: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: Acute Health Hazard
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Section 16 - Additional Information

European/International Regulations European Labeling in Accordance with EC Directives
H226: Flammable liquid and vapor.
H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H411: Toxic to aquatic life with long lasting effects.

Xn Harmful, N Dangerous for the environment.
R20/22 Harmful by inhalation and if swallowed
R36/37/38, Risk Phrase: Irritating to eyes, respiratory system and skin
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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