Methyl Iodide or Iodomethane Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Methyl Iodide or Iodomethane, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Methyl Iodide or Iodomethane: CAS Number: 74-88-4, EINECS EC Number: 200-819-5, Molecular Formula: CH3I, Molecular Weight: 141.94, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Methyl Iodide or Iodomethane.

Methyl iodide is also called Iodomethane commonly abbreviated "MeI", is an Organo iodine Compound that contains one Carbon – Iodine bond. Methyl iodide is highly reactive, the Methylium cation acts as a strong electrophillic Methylating agent, while the Iodide ion is a powerful nucleophile and is a good leaving group. Methyl iodide is a dense, colorless, volatile liquid turns brown on exposure to light due to liberation of Iodine. Methyl Iodide has a boiling point of 41C to 43C and specific gravity of about 2.27. Methyl Iodide is sensitive to light and therefore needs to be stored in dark amber colored bottles to prevent its degradation by light. Iodomethane may be stabilized by copper or silver wire.

Specifications - Methyl Iodide or Iodomethane:
Molecular formula: CH3I
Molecular weight: 141.94
Description: Clear colorless liquid
Density: Between 2.270 and 2.285 g/ml.
Water: Maximum 0.10 %
Assay: Mininimum 99.0 %.

MUBY CHEMICALS
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Methyl Iodide SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 05-Nov-20

Product Name & Other Names: Methyl Iodide or Iodomethane
CAS No.: 74-88-4
EINECS EC Code: 200-819-5
Molecular Weight: 141.94
Chemical Formula: CH3I.
Intended Use: Oil & Gas Wells fracturing and Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 3) H301
Acute toxicity, Inhalation (Category 3) H331
Acute toxicity, Dermal (Category 4) H312
Skin corrosion (Category 1B) H315
Respiratory sensitization (Category 1) H335
Carcinogenicity (Category 2), H351

Hazard Statements:
H301: Toxic if swallowed
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H331: Toxic if inhaled
H335: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H351: Suspected of causing cancer.

Precautionary Statements
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P301+P310+330: IF SWALLOWED: Rinse mouth and immediately call a POISON CENTER or doctor/physician.
P302+P352: IF ON SKIN: Wash with soap and water.
P303 + P361 + P352 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304 + P341 + P311 IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P314: Get Medical advice/attention if you feel unwell.
P330: If swallowed, rinse mouth.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
T Toxic
Xi Irritant
Xn Harmful
R21 Harmful in contact with skin.
R23/25 Toxic by inhalation and if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R45 May cause cancer.
R42 May cause sensitization by inhalation.

Product Name & Other Names: Methyl Iodide or Iodomethane.
CAS No.: 74-88-4
EINECS EC Code: 200-819-5

Inhalation: Toxic if inhaled. If inhaled, it will cause irritation and damage. Remove the victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Toxic if swallowed. It will cause irritation and burns to mouth, digestive tract and stomach. Contact medical center quickly. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Harmful and irritating on contact with skin. On contact, it can cause itching, pain, swelling and redness. Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: It can cause severe damage to eyes. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.

Fire: Flash point: 270C.
Auto ignition temperature: 352C
Toxic fumes, hydrogen iodide, carbon dioxide and carbon monoxide may be formed in fire.
Explosion: No data available
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide and water spray jet.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Keep away from heat. Keep away from sources of ignition. Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Non-Combustible Toxic Liquids. Keep away from heat and source of fire preferably in a ventilated area. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong bases, oxygen, metals.

Airborne Exposure Limits: TWA: 2 ppm USA. ACGIH Threshold Limit Values (TLV)
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Colorless liquid. Turns brown on exposure to light due to liberation of Iodine.
Odor: Typical.
Odor threshold: Not available.
pH: Not available.
Relative density: 2.27 approximate.
Boiling Point: 41C to 43C
Melting Point: -65C approximate.
Decomposition Temperature: 270C
Auto-ignition Temperature: 352C
Flash point: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Slightly soluble in water.
Viscosity: Not available.
Molecular Weight: 141.94
Chemical Formula: CH3I

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Toxic fumes, hydrogen iodide, carbon dioxide and carbon monoxide may be formed in fire.
Hazardous Polymerization: Not reported.
Incompatibilities: Strong oxidizing agents, Strong bases, Oxygen, Metals.
Conditions to Avoid: Heat, flames, moisture, light, ignition sources and incompatibles.

Oral rat LD50: 76 mg/kg
Dermal Guinea pig LD50: 800 mg/kg.
Inhalation rat LC50: 4 h - 1,300 mg/m3
Carcinogenicity: This product has been reported to be possible classification. Limited evidence of carcinogenicity in animal studies.
IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans.
Reproductive Toxicity: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.

Persistence and Degradability: Persistence is unlikely based on information available.
Bioaccumulation/ Accumulation: No information available.
Mobility: Will likely be mobile in the environment due to its volatility.
Results of PBT and vPvB assessment: No information available.
Environmental Toxicity: No information available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

DOT USA, TDG Canada & ADR/RID Europe
UN Number: 2644
Proper shipping name: METHYL IODIDE
Class: 6.1, Packing group: I
IMDG/IMO & IATA
UN Number: 2644
Proper shipping name: METHYL IODIDE
Class: 6.1, Packing group: I

USA:
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: Listed.
SARA 311/312: Acute & Chronic.
California Prop 65: WARNING! This product contains a chemical known to the State of California to cause cancer.

European/International Regulations European Labeling in Accordance with EC Directives:
H301: Toxic if swallowed
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H331: Toxic if inhaled
H335: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H351: Suspected of causing cancer.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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