Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance & Flavor chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc. The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer.
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Methyl salicylate BP Wintergreen oil FCC Food Grade Manufacturers, SDS GHS MSDS Sheet

Methyl salicylate BP Wintergreen oil: CAS Number: 119-36-8, EINECS EC Number: 204-317-7, FEMA Number: 2745, Molecular Formula: C8H8O3, Molecular Weight: 152.15, HS Code ---**

For MSDS Sheet Click
SDS MSDS Sheet of Methyl salicylate BP Wintergreen oil Manufacturers

Methyl salicylate
Pure BP Wintergreen oil FCC Food Grade
Methyl salicylate Oil of wintergreen Wwintergreen oil

Methyl salicylate, oil of wintergreen or wintergreen oil is an ester naturally produced by many species of plants, particularly wintergreens. It is also synthetically produced, used as a fragrance, in foods and beverages, and in liniments. This compound is probably produced as an anti-herbivore defense. If the plant is infected with herbivorous insects, the release of methyl salicylate may function as an aid in the recruitment of beneficial insects to kill the herbivorous insects.
Uses: Analgesic and antiseptic, flavoring agent in chewing gum and mints, fragrance, bait for attracting male orchid bees, to lower the freezing point of glacial acetic acid for transport etc.

Methyl Salicylate BP Grade
Ph Eur
C8H8O3 -- 152.1 -- 119-36-860-7
Action and use: Counter-irritant.

DEFINITION
Methyl 2-hydroxybenzoate.
Content: 99.0 per cent m/m to 100.5 per cent m/m.

CHARACTERS
Appearance: Colourless or slightly yellow liquid.
Solubility: Very slightly soluble in water, miscible with ethanol (96 per cent) and with fatty and essential oils.

IDENTIFICATION
A. Heat 0.25 ml with 2 ml of dilute sodium hydroxide solution on a water-bath for 5 min. Add 3 ml of dilute sulphuric acid. A crystalline precipitate is formed. Filter. The precipitate washed with water and dried at 100C-105C, melts at 156C to 161C.
B. To 10 ml of a saturated solution add 0.05 ml of ferric chloride solution. A violet colour develops.

TESTS
Appearance of solution: The solution is clear and not more intensely coloured than reference solution.
To 2 ml add 10 ml of ethanol (96 per cent).
Acidity: Dissolve 5.0 g in a mixture of 0.2 ml of bromocresol green solution and 50 ml of ethanol (96 per cent) previously neutralised to a blue colour by addition of 0.1 M sodium hydroxide. Not more than 0.4 ml of 0.1 M sodium hydroxide is required to restore the blue colour.
Relative density: 1.180 to 1.186.
Refractive index: 1.535 to 1.538.

ASSAY
Dissolve 0.500 g in 25 ml of ethanol (96 per cent). Add 0.05 ml of phenol red solution and neutralise with 0.1 M sodium hydroxide. To the neutralised solution add 50.0 ml of 0.1 M sodium hydroxide and heat under a reflux condenser on a water-bath for 30 min. Cool and titrate with 0.1 M hydrochloric acid . Calculate the volume of 0.1 M sodium hydroxide used in the saponification. Carry out a blank titration.
1 ml of 0.1 M sodium hydroxide is equivalent to 15.21 mg of C8H8O3.

Wintergreen Oil FCC Food and Flavoring Grade
Gaultheria Oil
CAS: [68917-75-9]

DESCRIPTION
Wintergreen Oil occurs as a colorless to yellow liquid withthe characteristic odor and taste of wintergreen. It is obtained by maceration and subsequent distillation with steam from the leaves of Gualtheria procumbens L. (Fam. Ericaceae) or from the bark of Betula lenta L. (Fam. Betulaceae). It boils, with decomposition, between 219C and 224C. It is soluble in alcohol and in glacial acetic acid, and it is very slightly soluble in water.
Function: Flavoring agent.

REQUIREMENTS
Identification:-
A. Shake 1 drop of sample with about 5 mL of water, and add 1 drop of ferric chloride. A deep violet color appears.
B. The infrared absorption spectrum of the sample exhibits relative maxima at the same wavelengths as those of a typical spectrum as shown in the section on Infrared Spectra, using the same test conditions as specified therein.
Assay: Not less than 98.0% and not more than 100.5% of methyl salicylate (C8H8O3).
Acid Value: Not more than 1.0.
Angular Rotation: Slightly levorotatory, exhibiting a rotation of not more than −1.5°.
Refractive Index: Between 1.535 and 1.538 at 20°.
Solubility in Alcohol: Passes test.
Specific Gravity: Between 1.176 and 1.182.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
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Last 17 May, 2017

List of All the IP BP USP FCC ACS Grades of Chemicals
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Calcium Gluconate Calcium Hydroxide
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Chromic Chloride Citric Acid
Calcium Citrate Copper Gluconate
Copper Sulfate, Cupric Sulphate Cupric Chloride
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Fumaric Acid Ferrous Sulphate
Ferric Sulfate Ferric Ammonium Citrate
Ferric Chloride  
Gentian Violet Mannitol
Magnesium Chloride Magnesium Gluconate
Magnesium Lactate Dihydrate Magnesium Sulfate
Magnesium Trisilicate Maleic Acid
Malic Acid BP USP Manganese Gluconate
Manganese Sulfate Manganese Chloride
Methylene Blue Potassium Bromide
Potassium Chloride Potassium Gluconate
Potassium Bitartrate, Cream of Tartar Potassium Hydroxide
Potassium Iodide Potassium Iodate
Potassium Sorbate Sodium Acetate
Sodium Bicarbonate Sodium Butyrate
Sodium Caprylate Sodium Fluoride
Sodium Gluconate Sodium Hydroxide Pellets
Sodium Iodide Sodium Lactate
Sodium Perborate Sodium Propionate
Sodium Thiosulfate Sodium Sulfate
Stannous Chloride Dihydrate Zinc Carbonate
Zinc Chloride Zinc Gluconate
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Methyl Salicylate SDS MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: 2-Hydroxybenzoic acid Methyl ester, Methyl 2-hydroxybenzoate, Oil of wintergreen, Methoxybenzoic Acid.
CAS No.: 119-36-8
EINECS EC Number: 204-317-7
Molecular Weight: 152.15
Chemical Formula: 2-(HO)C6H4CO2CH3
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3

Labeling according Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

Signal Words: Warning

Hazard statements:
H302: Harmful if swallowed.
H319: Causes serious eye irritation.

Precautionary statements:P337+P313P
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xn Harmful R22, R36
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Ingredient: Methyl Salicylate
CAS No.: 119-36-8
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Combustible at high temperature. Vapors can travel to a source of ignition and flash back.
Auto-Ignition Temperature: 454C.
Flash Points: 96C Closed Cup.
Flammable Limits: Not available.
Products of Combustion: Fumes, Carbon dioxide & Carbon Monoxide.
Fire: Methyl Salicylate is flammable on heating.
Explosion: Expslosive on heating.
Fire Extinguishing Media: Use means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. On decomposition it may emit carbon monoxide. Containers may explode on heating

6. Accidental Release Measures

Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Large Spill: Avoid touching the spilled material. Do not let the product enter drains. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Do not contaminate water sources or sewer. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Do not use combustible materials such as sawdust. Provide ventilation.

7. Handling and Storage

Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Methyl Salicylate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Keep away from heat, sun light and oxidizing agents.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Not Specified.
Ventilation System
: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Methyl Salicylate is colorless to yellowish red liquid.
Odor: Strong typical wintergreen.
Solubility: It is slightly soluble in water.
pH: NA
Specific Gravity: NA
Molecular Weight:
152.15
Molecular Formula: 2-(HO)C6H4CO2CH3
% Volatiles by volume @ 21C (70F): -
Boiling Point: 223C
Melting Point: -8.6C

10. Stability and Reactivity

Stability: Methyl Salicylate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits carbon monoxide & fumes when heated to decomposition. It may form harmful gases.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, acids, strong bases.
Conditions to Avoid: Incompatible materials, light, dust generation, excess heat, exposure to moist air or water.

11. Toxicological Information

Acute toxicity
Harmful if swallowed. Harmful if inhaled. Irritating to skin.
Toxicity data
ORAL-RAT LD50 887 mg kg-1
ORAL-Mouse LD50 1110 mg kg-1
Dermal-Rabbit LD50 > 5.000 mg/kg
Special Remarks on Toxicity to Animals: Not available.
Carcinogenicity: Not listed as a suspected/confirmed carcinogen by ACGIH, IARC, NTP, OSHA.
Developmental Toxicity: Adverse reproductive effects have occurred in experimental animals.

12. Ecological Information

Toxicity to fish: static test LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h
Toxicity to algae: static test EC50 - Desmodesmus subspicatus (green algae) - 27 mg/l - 72 h
Environmental Fate: This substance is expected to have a high biological oxygen demand. It is readily biodegradable and has low bioconcentration potential.
Environmental Toxicity: NA
BOD5 and COD: Not available. This substance is expected to have a high biological oxygen demand.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

US DOT Classification:
Not regulated.
Canada TDG Classification:
Not regulated.
IATA
Not regulated.
ADR/RID
Not regulated.

15. Regulatory Information

USA:
OSHA Hazards
: Not classed as Highly Hazardous as per OSHA
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: No chemicals in this material are subject to the reporting requirements
SARA 311/312 Hazards: Acute Health Hazard
Pennsylvania Right To Know Components: Methyl salicylate
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
CERCLA Hazardous Substances and corresponding RQs: Not Listed

EINECS EC Number: 204-317-7
Hazard Symbols: XN
Risk Phrases: R-22 Harmful if swallowed. R-36/38 Irritating to eyes and skin.
Safety Phrases:
S-26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Canada - DSL/NDSL: CAS# 119-36-8 is listed on Canada's DSL List.
Canada - WHMIS: This product has a WHMIS classification of D2A.
Canadian Ingredient Disclosure List: CAS# 119-36-8 is listed.

HMIS (Perceived): Health hazard: 1, Flammability: 1, Reactivity Hazard: 0, Physical hazards: H
NFPA (Perceived) : Health hazard: 1, Fire: 1, Reactivity Hazard: 0.

16. Other Information

H302 = Harmful if swallowed.
H319 = Causes serious eye irritation.
Xn Harmful
R22 Harmful if swallowed.
R36 Irritating to eyes.
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.