Phosphorus Oxychloride or Phosphoryl Chloride Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Phosphorus Oxychloride, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Phosphorus Oxychloride or Phosphoryl Chloride: CAS Number: 10025-87-3, EINECS EC Number: 233-046-7, Molecular Formula: Cl3OP or POCl3, Molecular Weight: 153.33, HS Code 28121030 or 28121200 or 28129000

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Phosphoryl Chloride or Phosphorus Oxychloride.

Phosphorus oxychloride appears as a colorless fuming liquid with a pungent odor. Phosphoryl chloride or Phosphorus oxychloride is a colourless liquid with the formula POCl3. Phosphoryl chloride is used in the manufacture of phosphate esters. It is also used in producing pharmaceuticals.

General Properties and Specifications of Phosphorus Oxychloride or Phosphoryl Chloride:
Appearance: Colorless fuming liquid.
Assay: 99%
PCl3: 0.2% maximum.
Odor: Pungent odor.
Boiling point: 106C.
Melting point: around 1C.
Relative density: around 1.65
Solubility: Reacts with water.

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Phosphorus Oxychloride or Phosphoryl Chloride SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 31-Aug-21

Product Name & Other Names: Phosphorus Oxychloride or Phosphoryl Chloride.
CAS No.: 10025-87-3
EINECS EC Number: 233-046-7
Chemical Formula: Cl3OP or POCl3.
Molecular Weight: 153.33
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 4), H302
Skin corrosion (Category 1A), H314
Acute toxicity, Inhalation (Category 2), H330
Specific target organ toxicity - repeated exposure Category 1, H372

Hazard statements:
H302 Harmful if swallowed.
H330 Fatal if inhaled.
H314 Causes severe skin burns and eye damage.
H372: Causes damage to organs through prolonged or repeated exposure.
EUH014 Reacts violently with water.
EUH029 Contact with water liberates toxic gas.

Precautionary statements:
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink, or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P284: Wear respiratory protection.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P405: Store locked up.
P403+233: Store in a well-ventilated place. Keep container tightly closed.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T+ Very Toxic
C Corrosive.
Risk Phrases:
R22 Harmful if swallowed.
R26 Very toxic by inhalation.
R48 Danger of serious damage to health by prolonged exposure.
R34 Causes burns.
R41 Risk of serious damage to eyes.

Product Name & Other Names: Phosphorus Oxychloride or Phosphoryl Chloride.
CAS No.: 10025-87-3
EINECS EC Number: 233-046-7

Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin: Immediately flush skin with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and shoes before reuse. Get medical attention if irritation develops.
Eyes: Immediately flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower eyelids. Hold eyelids apart during irrigation. Get medical attention.
Inhalation: Remove person to fresh air. If breathing is difficult, give oxygen. If not breathing administer artificial respiration. Get medical attention.

Flash Point: Not flammable.
Fire/Explosion: Not considered to be a fire and explosion hazard.
Extinguishing Medium: Dry chemical or Carbon dioxide or Dry powder Dry sand.
Unsuitable extinguishing media: Water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.
Special hazards arising from the substance or mixture: Fumes of hydrogen fluoride.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Don't touch or walk through this product. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid prolonged or repeated exposure. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from moisture, heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials. Take care to eliminate static discharge.

Exposure Limits:
USA ACGIH TLV: 0.1 ppm
OSHA PEL: 0.1 ppm
Engineering Controls: Use adequate exhaust ventilation to keep airborne concentrations below the allowable exposure limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Colorless fuming liquid.
Odor: Pungent odor.
Odor threshold: Not available.
pH: Not available.
Relative density: around 1.65
Melting Point: 1C literature.
Initial boiling point and boiling range: 106C.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Reacts with water.
Viscosity: Not available.
Chemical Formula: Cl3OP or POCl3.
Molecular Weight: 153.33

Chemical Stability: Stable under normal temperatures and pressures. Reacts violently with water. Contact with water liberates toxic gas. Sensitive to moisture. Highly reactive material.
Incompatibility (Materials to Avoid): Highly reactive material. Reacts with water. Avoid Strong bases, Alcohols, Amines, Metals, Acids, Reducing Agent, Water, Oxidizing agent.
Conditions to Avoid: Incompatible materials, excessive heat, moisture.
Hazardous Decomposition Products: Fumes of hydrogen fluoride and fluorine may evolve.
Hazardous Polymerization: Hazardous polymerization does not occur.

Toxicity to Animals:
LC50 Inhalation Rat: 308 mg/m3 for 4 h.
LD50 Oral Rat: 380 mg/kg.
LD50 Dermal Rabbit: > 250 mg/kg.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible, or confirmed human carcinogen by IARC, NTP ACGIH or OSHA.
Mutagenic Effects: No information found.
Reproductive Effects: No information found.
Developmental Toxicity: No information found.

Toxicity to daphnia: static test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h.
Persistence and Degradability: Unlikely to persist.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Dispose of in accordance with all applicable local, state, and federal regulations at an approved waste disposal facility.

DOT USA, TDG Canada & ADR/RID Europe:
UN-No UN 1810, Proper Shipping Name: Phosphorus oxychloride.
Hazard Class 6.1 (8), Packing Group I.
IMDG/IMO
UN-No UN 1810, Proper Shipping Name: Phosphorus oxychloride.
Hazard Class 6.1 (8), Packing Group I.
IATA:
UN-No UN 1810, Proper Shipping Name: Phosphorus oxychloride.
Hazard Class 6.1 (8), Packing Group I.

USA:
SARA 311/312: Acute Health Hazard; Chronic Health Hazard, as per section 2.
California Prop.65: This product contains no chemical known to the State of California to cause birth defects or other reproductive harm.

European Labeling in Accordance with EC Directives:
H302 Harmful if swallowed.
H330 Fatal if inhaled.
H314 Causes severe skin burns and eye damage.
H372: Causes damage to organs through prolonged or repeated exposure.
EUH014 Reacts violently with water.
EUH029 Contact with water liberates toxic gas.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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