Pyridinium Chlorochromate Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Pyridinium Chlorochromate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Pyridinium Chlorochromate: CAS Number: 26299-14-9, EINECS EC Number: 247-595-5, Molecular Formula: [C5H5NH]-[CrO3Cl] or C5H6ClCrNO3, Molecular Weight: 215.56, HS Code ---**

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SDS MSDS Sheet of Pyridinium Chlorochromate Manufacturers

Pyridinium Chlorochromate
Pure Suppliers
Pyridinium Chlorochromate

Pyridinium chlorochromate is a yellow orange solid reagent used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. Pyridinium chlorochromate, or PCC, will not fully oxidize a primary alcohol to the carboxylic acid. PCC offers the advantage of the selective oxidation of alcohols to aldehydes or ketones, whereas many other reagents are less selective.

Specifications of Pyridinium Chlorochromate:
CAS number: 26299-14-9
Molecular formula: [C5H5NH]-[CrO3Cl] or C5H6ClCrNO3
Molecular weight: 215.56
Solubility: Soluble in acetone, acetonitrile, THF.
Melting range:            Between 196C and 205C.
Appearance: Yellow orange powder.
Loss on drying: maximum 0.50%
Assay: Between 98 and 102%.

We also manufacture and supply Pyridinium Dichromate --- Pyridinium Chlorochromate --- 5-Ethyl-Pyridine-2-Ethanol --- Pyridine.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

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Copyright and Usual Disclaimer is Applicable.
Last 4 October, 2023

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Pyridinium Chlorochromate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
15-Nov-20

Section 1. Product Information

Product Name & Other Names: Pyridinium Chlorochromate.
CAS No.: 26299-14-9
EINECS EC Number: 247-595-5
Chemical Formula: [C5H5NH]-[CrO3Cl] or C5H6ClCrNO3
Molecular Weight: 215.56
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Oxidizing liquids; Oxidizing solids Category 3, H272
Sensitization, Skin Category 1, H317
Carcinogenicity Inhalation Category 1B, H350i
Chronic aquatic toxicity Category 1, H410

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

GHS Label Elements
Health Hazard
Health Hazard

GHS Label Elements
irritant.png
Irritant

GHS Label Elements
oxidizingsolid.png
Oxidizer

Signal Words: Danger

Hazard statements:
H272 May intensify fire; oxidizer
H317 May cause an allergic skin reaction.
H350i May cause cancer by inhalation.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P220: Keep/Store away from clothing/…/combustible materials.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get medical advice/attention if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P302+352: IF ON SKIN: Wash with soap and water.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
O = Oxidizing.
T = Toxic
N = Dangerous to environment.
Risk Phrases:
R 8: Contact with combustible material may cause fire.
R43: May cause sensitization by skin contact.
R49: May cause cancer by inhalation.
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Section 3: Composition and Information on Ingredients

Product Name & Other Names: Pyridinium Chlorochromate.
CAS No.: 26299-14-9
EINECS EC Number: 247-595-5

Section 4. First Aid & Procedure

Always get medical attention after the first aid is over.

Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and shoes before reuse. Get medical attention if irritation develops.
Eyes:
Immediately flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower eyelids. Hold eyelids apart during irrigation. Get medical attention.
Inhalation:
Remove person to fresh air. If breathing is difficult, give oxygen. If not breathing administer artificial respiration. Get medical attention.

Section 5. Fire Fighting Measures

Fire/Explosion: The product is an oxidizer.
Extinguishing Medium:
Water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture: Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas, Chromium oxides.
Fire Fighting Instructions: Use suitable protective equipment for surrounding fire. Use water spray to cool unopened containers.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Section 6. Spills and Disposals

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law. Keep combustibles (wood, paper, oil, etc) away from spilled material.

Section 7. Handling and Storage

Hazardous material. Avoid prolonged or repeated exposure.
Precautions for safe handling
: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, organic materials, powdered metals, strong reducing agents, metals, strong acids, alcohols, Methanol, Acetone. Isolate from all combustibles.

Section 8. Exposure Controls & Personal Protection

Exposure Limits: 0.1 mg/m3 USA Occupational Exposure Limits (OSHA)
Engineering Controls: Use adequate exhaust ventilation to keep airborne concentrations below the allowable exposure limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9. Physical & Chemical Data

Appearance: Yellow orange powder.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting range: Between 196C and 205C.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in acetone, acetonitrile, THF.
Viscosity: Not available.
Chemical Formula: [C5H5NH]-[CrO3Cl] or C5H6ClCrNO3
Molecular Weight: 215.56.
Oxidizing properties: The substance or mixture is classified as oxidizing with the category 2.

Section 10. Stability and Reactivity

Chemical Stability: Stable under recommended temperatures and pressures. Dust when whirled up a dust explosion potential may generally be assumed.
Incompatibility (Materials to Avoid):
Organic materials, Powdered metals, Strong reducing agents. Violent reactions possible with: Metals, Strong acids, strong reducing agents, Alcohols, Methanol, Acetone.
Conditions to Avoid: Incompatible materials, exposure to moist air or water, excessive heat.
Hazardous Decomposition Products: Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas, Chromium oxides.
Hazardous Polymerization:
Will not occur.

Section 11. Toxicological Information

Toxicity to Animals: LD50 Oral - Rat - Not available.
Carcinogenicity: Presumed to have carcinogenic potential for humans May cause cancer by inhalation.
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Germ cell mutagenicity: Not available.
Reproductive toxicity: Not available.
Developmental Effects: Not available.
Teratogenicity: Not available.

Section 12. Ecological Information

Ecotoxicity: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Toxicity to fish: Not available.
Toxicity to daphnia and other aquatic invertebrates: Not available.
Persistence and Degradability: Not available. May persist.
Mobility in soil: Not available.
Environmental Precautions: DO NOT DISCHARGE into drains and rivers.
Results of PBT and vPvB assessment: Not available.

Section 13. Disposal Suggestions

Dispose of in accordance with all applicable local, state, and federal regulations at an approved waste disposal facility.

Section 14. Transport and Label Information

DOT USA, TDG Canada & ADR/RID Europe:
UN number: 1479 Class: 5.1 Packing group: II
Proper shipping name: OXIDIZING SOLID, N.O.S. (Pyridinium chlorochromate)
IMDG/IMO
UN number: 1479 Class: 5.1 Packing group: II
Proper shipping name: OXIDIZING SOLID, N.O.S. (Pyridinium chlorochromate)
IATA:
UN number: 1479 Class: 5.1 Packing group: II
Proper shipping name: OXIDIZING SOLID, N.O.S. (Pyridinium chlorochromate).

Section 15. Regulatory Information

USA:
SARA 311/312
: Hazardous Categorization: Acute Health Hazard; Chronic Health Hazard.
California Prop.65: WARNING! This product contains a chemical known to the State of California to cause birth defects or other reproductive harm.

Section 16. Other Information

European Labeling in Accordance with EC Directives:
H272 May intensify fire; oxidizer
H317 May cause an allergic skin reaction.
H350i May cause cancer by inhalation.
H410 Very toxic to aquatic life with long lasting effects.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
O = Oxidizing.
T = Toxic
N = Dangerous to environment.
Risk Phrases:
R 8: Contact with combustible material may cause fire.
R43: May cause sensitization by skin contact.
R49: May cause cancer by inhalation.
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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