Thiophenol or PhSH or Phenyl mercaptan or Mercaptobenzene Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Thiophenol or PhSH or Phenyl mercaptan, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Thiophenol or PhSH or Phenyl mercaptan or Mercaptobenzene: CAS Number: 108-98-5, EINECS EC Number: 203-635-3, Molecular Formula: C6H6S, Molecular Weight: 110.18, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Thiophenol or PhSH or Phenyl mercaptan or Mercaptobenzene.

Thiophenol or PhSH has the formula C6H5SH. It is a foul-smelling colorless liquid. Thiophenols are used in the production of pharmaceuticals including of sulfonamides.

Specifications of Thiophenol:
Appearance: Colorless liquid.
Assay: 99.5% minimum.
Relative Density: 1.077
Melting point: −15C
Boiling point: 169C.

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) 91-22-23770100, 23726950
Current Date Time in India GMT+5:30

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Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

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Thiophenol or Phenyl mercaptan or Mercaptobenzene SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

Product Name/Synonyms: Thiophenol or PhSH or Phenyl mercaptan or Mercaptobenzene.
CAS No.: 108-98-5
EINECS EC No.: 203-635-3
Molecular Formula: C6H6S
Molecular Weight: 110.18
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910

Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP):
Flammable liquids (Category 3) H226
Acute toxicity, Oral (Category 2), H300
Acute toxicity, Inhalation (Category 2), H330
Acute toxicity, Dermal (Category 1), H310
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319
Reproductive toxicity (Category 2), H361
Specific target organ toxicity - single exposure (Category 2), Nervous system, H371
Specific target organ toxicity - single exposure Respiratory system (Category 3), H335
Specific target organ toxicity - repeated exposure Kidney, (Category 1), H372

Hazard statements:
H226: Flammable liquid and vapor.
H300: Fatal if swallowed.
H310: Fatal in contact with skin.
H330: Fatal if inhaled.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H361 Suspected of damaging fertility or the unborn child.
H371 May cause damage to organs (Nervous system) if swallowed.
H372 Causes damage to organs (Kidney) through prolonged or repeated exposure if swallowed.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352 + P310 IF ON SKIN: Wash with plenty of water. Immediately call a POISON CENTER/doctor.
P304+340+310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P370+378: In case of fire: Use dry chemical, foam, water spray, carbon dioxide for extinction.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbols:
T+ Very toxic
F Extremely Flammable
Xi Irritant.
R-phrases:
R 10 Flammable.
R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed.
R36/37/38 Irritating to eyes, respiratory system, and skin.
R48 Danger of serious damage to health by prolonged exposure.
R60 May impair fertility..
R61 May cause harm to the unborn child.

Product Name/Synonyms: Thiophenol or PhSH or Phenyl mercaptan or Mercaptobenzene.
CAS No.: 108-98-5
EINECS EC No.: 203-635-3
Molecular Formula: C6H6S

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Flammable.
Flash Points: -
Products of Combustion: Carbon dioxide, Carbon monoxide, Sulfur oxides and fumes.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Use dry powder or dry sand should be preferred. Do not use solid water stream. Flammable liquid and vapor. For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Never direct a water jet in the container in order to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water jet in order to prevent pressure build-up, auto-ignition or explosion.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid mist formation. Avoid breathing mist/vapors. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Remove all sources of ignition. Provide proper ventilation. Keep people away from and upwind of spill/leak. Entry to non-involved personnel should be controlled around the leakage area by roping off. Absorb the material on a porous, inert material such as earth, sand or vermiculite. Carefully sweep up the material without causing dust. Dispose of in accordance with local regulations.
Large liquid spillages should be contained by use of sand or another inert material. The spillage should be transferred to a suitable container and recovered or disposed of in accordance with local regulations. Because of the danger of spontaneous combustion, any combustible material, such as cloth, used for cleaning spillages, should be saturated with water and disposed of promptly, preferably by incineration.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Keep away from heat/sparks/open flame/hot surfaces. -No smoking. Take measures to prevent the buildup of electrostatic charge. Use explosion-proof equipment. Wash hands and face thoroughly after handling.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from light, heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents, acids, bases, reducing agents. Store locked up. Keep away from sources of ignition - No smoking. Take measures to prevent the build-up of electrostatic charge.

Airborne Exposure Limits: Not Established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Colorless liquid.
Odor: Unpleasant.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.077
Boiling Point: 169C literature.
Melting Point: -15C
Flash Point: 50C
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Not available.
Viscosity: Not available.
Molecular Formula: C6H6S
Molecular Weight: 110.18

Stability: Stable under ordinary conditions of use and storage. Vapour/air-mixtures are explosive at high temperature.
Hazardous Decomposition Products: It emits Carbon oxides, Sulfur oxides & Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, Acids, Bases, Reducing agents.
Conditions to Avoid: Incompatibles, oxidizing agents, heat flame & light.

Fatal if inhaled, swallowed and in skin contact.
LD50 Oral - Rat – 46.2 mg/kg.
LC50 Inhalation - Rat - 4 h - 33 ppm.
LD50 Dermal - Rabbit - 134 mg/kg.
Carcinogenicity: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found

Environmental Toxicity:
Toxicity to fish: LC50 - Oryzias latipes (Japanese medaka) - 0,009 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 0,0044 mg/l - 48 h.
Environmental Fate: Not available.
Mobility: Not available.
Persistence and Degradability: Not available.
Toxicity of the Products of Biodegradation: Not available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

DOT USA, TDG Canada & ADR/RID Europe:
Shipping Name: Phenyl Mercaptan.
Hazard Class: 6.1(3), Packing Group: I
UN Number: UN2377
UN Number: UN2377
IATA & IMDG/IMO:
Shipping Name: Phenyl Mercaptan.
Hazard Class: 6.1(3), Packing Group: I
UN Number: UN2377

USA:
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Fire Hazard, Chronic Health Hazard.
California prop. 65: Contains no chemical subject to California Prop 65.

European Labeling in Accordance with EC Directives:
H226: Flammable liquid and vapor.
H300: Fatal if swallowed.
H310: Fatal in contact with skin.
H330: Fatal if inhaled.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H361 Suspected of damaging fertility or the unborn child.
H371 May cause damage to organs (Nervous system) if swallowed.
H372 Causes damage to organs (Kidney) through prolonged or repeated exposure if swallowed.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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