Soda Lime SDS, MSDS Sheet

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Soda Lime USP BP IP Analytical Reagent FCC Food grade Manufacturers Specifications

Soda Lime SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
05-Dec-20

1. Product Identification

Product Name & Other Names: Soda Lime.
CAS No.: Not applicable to mixtures
Molecular Weight: Not applicable to mixtures
Chemical Formula: Not applicable to mixtures
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin corrosion/irritation Category (H315)
Serious eye damage/eye irritation Category 1 (H318)
Acute toxicity, inhalation Category 4 (H332)
Specific target organ toxicity - single exposure, respiratory (Category 3) (H335)
Hazardous to the aquatic environment, acute hazard Category 3 (H402)

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Corrosive
Corrosive

Signal Words: Danger

Hazard Statements:
H315: Causes skin irritation.
H318: Causes serious eye damage.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H402: Harmful to aquatic life.

Precautionary Statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P262: Do not get in eyes, on skin, or on clothing.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P362: Take off contaminated clothing and wash before reuse.
P302+352: IF ON SKIN: Wash with soap and water.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P332+313: If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P501: Dispose of contents/ container to an approved waste disposal plant.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
X1: Irritant.
C: Corrosive.
Risk Phrases:
R37/38: Irritating to respiratory system and skin.
R20 Harmful by inhalation.
R41: Risk of serious damage to eyes.
R52 Harmful to aquatic organisms.

3. Composition/Information on Ingredients

Ingredients:
Item1: Sodium Hydroxide
CAS Number: 1310-73-2
Percent: < 5%
Item2: Potassium Hydroxide
CAS Number: 1310-58-3
Percent: < 3%
Item3: Calcium Hydroxide
CAS Number: 1305-62-0
Percent: > 80%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion: Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Notes to physicians: Treat symptomatically.

5. Fire Fighting Measures

Fire: Not considered to be a fire hazard.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue with a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Corrosive solid. Stop leak if without risk. Cover with an inert, non-combustible absorbent material, sweep up, and remove to an approved disposal container. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements, or confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated surface and dispose as per legal requirement.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like acids, maleic anhydride, nitro ethane, nitro methane, nitro paraffin, nitro propane, phosphorus.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
-OSHA Permissible Exposure Limit (PEL):
Calcium Hydroxide: 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction), (TWA);
Sodium Hydroxide: 2 mg/m3 (Ceiling)
-ACGIH Threshold Limit Value (TLV):
Calcium Hydroxide: 5 mg/m3 (TWA);
Sodium Hydroxide: 2 mg/m3 (Ceiling);
Potassium Hydroxide: 2 mg/m3 (Ceiling)
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a full face piece particulate respirator (NIOSH type N100 filters) may be worn for up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face-piece positive-pressure, air-supplied respirator.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: White to grayish deliquescent pellets.
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Slightly soluble in water.
Viscosity: Not available.

10. Stability and Reactivity

Stability: Soda Lime readily absorbs carbon dioxide from air to form calcium carbonate.
Hazardous Decomposition Products: Caustic fumes of calcium oxide form when heated to decomposition (580C; 1076F).
Hazardous Polymerization: Will not occur.
Incompatibilities: Violent reactions with maleic anhydride, nitro ethane, nitro methane, nitro paraffin, nitro propane, phosphorus. As a strongly alkaline material, it is incompatible with acids. Forms phosgene upon reaction with trichloroethylene or chloroform.
Conditions to Avoid: Air, incompatibles.

11. Toxicological Information

For Calcium Hydroxide and Sodium Hydroxide: No LD50/LC50 information found relating to normal routes of occupational exposure. Investigated as a mutagen.
For potassium hydroxide: Oral rat LD50: 273 mg/kg.
Carcinogenic Effects: Not a reported carcinogen by IARC NTP ACGIH OSHA.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. Ecological Information

Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.
Environmental Fate:
Soda Lime is not expected to significantly bio accumulate.
Environmental Toxicity: No information found.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with legal requirements.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe:
Proper Shipping Name: SODA LIME
Hazard Class: 8
UN/NA: UN1907
Packing Group: III
IMDG/IMO:
Proper Shipping Name: SODA LIME
Hazard Class: 8
UN/NA: UN1907
Packing Group: III
IATA/ICAO:
Proper Shipping Name: SODA LIME
Hazard Class: 8
UN/NA: UN1907
Packing Group: III

15. Regulatory Information

USA:
SARA 311/312: Acute and chronic hazard. See section2.

16. Other Information

European Labeling in Accordance with EC Directives:
H315: Causes skin irritation.
H318: Causes serious eye damage.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H402: Harmful to aquatic life.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
X1: Irritant.
C: Corrosive.
Risk Phrases:
R37/38: Irritating to respiratory system and skin.
R20 Harmful by inhalation.
R41 Risk of serious damage to eyes.
R52 Harmful to aquatic organisms.

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Contact

MUBY CHEMICALS
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TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

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neighbouring buyers may
e-mail: us@mubychem.com
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Last 26 May, 2024

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