Carbomer 934, 934P, 940, 941, 974, 980, Carbomer Copolymer, Carbomer Homopolymer, Carbomer Interpolymer or Polyacrylic acid Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Carbomer 934, 934P, 940, 941, 974, 980, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Carbomer 934, 934P, 940, 941, 974, 980, Carbomer Copolymer, Carbomer Homopolymer, Carbomer Interpolymer: CAS Number: 9003-01-4, EINECS EC Number: 618-347-7 or 202-415-4, Molecular Formula: (C3H4O2)n, Molecular Weight: Variable, HS Code ---**

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Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Carbomer 934, 934P, 940, 941, 974, 980, Carbomer Copolymer, Carbomer Homopolymer, Carbomer Interpolymer or Polyacrylic acid .

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SDS MSDS Sheet of Carbomer 934, 934P, 940, 941, 974, 980, Carbomer Copolymer, Carbomer Homopolymer, Carbomer Interpolymer Manufacturers

Carbomer 934, 934P, 940, 941, 974, 980
Polyacrylic acid or Carbomer Copolymer, Carbomer Homopolymer, Carbomer Interpolymer Pure Suppliers
Carbomer 934, 934P, 940, 941, 974, 980

Polyacrylic acid (PAA; trade name Carbomer) is a synthetic high-molecular weight polymer of acrylic acid. The IUPAC name is poly(1-carboxyethylene). Dry Carbomers are sold as white, fluffy powders that are frequently used as gels in cosmetic and personal care products. Their role in cosmetics is to suspend solid in liquids, prevent emulsions from separating. Carbomer codes  like 910, 934, 940, 941, 934P, etc. are an indication of molecular weight and the specific components of the polymer. Carbomers can be found in a wide variety of product types including skin, hair, nail, and makeup products, as well as dentifrices.

Specifications of Carbomer 934 USP NF grade:

DEFINITION
Carbomer 934 is a high molecular weight polymer of acrylic acid cross-linked with allyl ethers of sucrose. Carbomer 934, previously dried under vacuum at 80C for 1 h, contains NLT 56.0% and NMT 68.0% of carboxylic acid (–COOH) groups. The viscosity of a neutralized 0.5% aqueous dispersion of Carbomer 934 is between 30,500 and 39,400 mPa·s.

IDENTIFICATION
A.
Sample dispersion:  10 mg/mL
Analysis 1: To one portion of the Sample dispersion add thymol blue.
Acceptance criteria 1: An orange color is produced.
Analysis 2: To another portion of the Sample dispersion add cresol red.
Acceptance criteria 2: A yellow color is produced.
B.
Sample dispersion: 10 mg/mL
Analysis: Adjust the Sample dispersion with 1 N sodium hydroxide to a pH of 7.5.
Acceptance criteria: A very viscous gel is produced.

ASSAY
Carboxylic Acid Content:
To pass the test.
Acceptance criteria: 56.0%–68.0% on the dried basis

Limit of Benzene:
To pass the test.
Acceptance criteria: NMT 0.5%
Loss on Drying:
Analysis: Dry a sample under vacuum at 80° for 1 h.
Acceptance criteria: NMT 2.0%
Viscosity—Rotational Methods:
To pass the test.
Acceptance criteria: 30,500–39,400 mPa·s
Packaging and Storage: Preserve in tight containers. No storage requirements specified.
Labeling: Label it to indicate that it is not intended for internal use. A carbomer homopolymer manufactured using benzene and complying with the unique requirements of this monograph will be officially titled Carbomer 934 and will not be referred to as Carbomer Homopolymer.


Specifications of Carbomer 934P Grade:

DEFINITION
Carbomer 934P is a high molecular weight polymer of acrylic acid, cross-linked with allyl ethers of sucrose or pentaerythritol. Carbomer 934P, previously dried under vacuum at 80C for 1 h, contains NLT 56.0% and NMT 68.0% of carboxylic acid (–COOH) groups. The viscosity of a neutralized 0.5% aqueous dispersion of Carbomer 934P is between 29,400 and 39,400 mPa·s.

IDENTIFICATION
A.
Sample dispersion:  10 mg/mL
Analysis 1: To one portion of the Sample dispersion add thymol blue.
Acceptance criteria 1: An orange color is produced.
Analysis 2: To another portion of the Sample dispersion add cresol red.
Acceptance criteria 2: A yellow color is produced.
B.
Sample dispersion: 10 mg/mL
Analysis: Adjust the Sample dispersion with 1 N sodium hydroxide to a pH of 7.5.
Acceptance criteria: A very viscous gel is produced.

ASSAY
Carboxylic Acid Content:
To pass the test.
Acceptance criteria: 56.0%–68.0% on the dried basis

Limit of Benzene:
To pass the test.
Acceptance criteria: NMT 0.01%
Loss on Drying:
Analysis: Dry a sample under vacuum at 80° for 1 h.
Acceptance criteria: NMT 2.0%
Viscosity—Rotational Methods:
To pass the test.
Acceptance criteria: 29,400–39,400 mPa·s
Packaging and Storage: Preserve in tight containers. No storage requirements specified.
Labeling: A carbomer homopolymer manufactured using benzene and complying with the unique requirements of this monograph will be officially titled Carbomer 934P and will not be referred to as Carbomer Homopolymer.


Specifications of Carbomer 940 USP NF Grade:

DEFINITION
Carbomer 940 is a high molecular weight polymer of acrylic acid cross-linked with allyl ethers of pentaerythritol. Carbomer 940, previously dried under vacuum at 80C for 1 h, contains NLT 56.0% and NMT 68.0% of carboxylic acid (–COOH) groups. The viscosity of a neutralized 0.5% aqueous dispersion of Carbomer 940 is between 40,000 and 60,000 mPa·s.

IDENTIFICATION
A.
Sample dispersion: 10 mg/mL
Analysis 1: To one portion of the Sample dispersion add thymol blue.
Acceptance criteria 1: An orange color is produced.
Analysis 2: To another portion of the Sample dispersion add cresol red.
Acceptance criteria 2: A yellow color is produced.
B.
Sample dispersion: 10 mg/mL
Analysis: Adjust the Sample dispersion with 1 N sodium hydroxide to a pH of 7.5.
Acceptance criteria: A very viscous gel is produced.

ASSAY
Carboxylic Acid Content:
To pass the test.
Acceptance criteria: 56.0%–68.0% on the dried basis

Limit of Benzene:
To pass the test.
Acceptance criteria: NMT 0.5%
Loss on Drying:
Analysis: Dry a sample under vacuum at 80° for 1 h.
Acceptance criteria: NMT 2.0%
Viscosity—Rotational Methods:
To pass the test.
Acceptance criteria: 40,000–60,000 mPa·s
Packaging and Storage: Preserve in tight containers. No storage requirements specified.
Labeling: Label to indicate that it is not intended for internal use. A carbomer homopolymer manufactured using benzene and complying with the unique requirements of this monograph will be officially titled Carbomer 940 and will not be referred to as Carbomer Homopolymer.


Specifications of Carbomer 941 USP NF Grade:

DEFINITION
Carbomer 941 is a high molecular weight polymer of acrylic acid cross-linked with allyl ethers of pentaerythritol. Carbomer 941, previously dried under vacuum at 80C for 1 h, contains NLT 56.0% and NMT 68.0% of carboxylic acid (–COOH) groups. The viscosity of a neutralized 0.5% aqueous dispersion of Carbomer 941 is between 4000 and 11,000 mPa·s.

IDENTIFICATION
A.
Sample dispersion: 10 mg/mL
Analysis 1: To one portion of the Sample dispersion add thymol blue.
Acceptance criteria 1: An orange color is produced.
Analysis 2: To another portion of the Sample dispersion add cresol red.
Acceptance criteria 2: A yellow color is produced.
B.
Sample dispersion: 10 mg/mL
Analysis: Adjust the Sample dispersion with 1 N sodium hydroxide to a pH of 7.5.
Acceptance criteria: A very viscous gel is produced.

ASSAY
Carboxylic Acid Content:
To pass the test.
Acceptance criteria: 56.0%–68.0% on the dried basis

Limit of Benzene:
To pass the test.
Acceptance criteria: NMT 0.5%
Loss on Drying:
Analysis: Dry a sample under vacuum at 80C for 1 h.
Acceptance criteria: NMT 2.0%
Viscosity—Rotational Methods:
To pass the test.
Acceptance criteria: 4,000–11,000 mPa·s
Packaging and Storage: Preserve in tight containers. No storage requirements specified.
Labeling: Label it to indicate that it is not intended for internal use. A carbomer homopolymer manufactured using benzene and complying with the unique requirements of this monograph will be officially titled Carbomer 941 and will not be referred to as Carbomer Homopolymer.


Specifications of Carbomer 1342 USP NF Grade:

DEFINITION
Carbomer 1342 is a high molecular weight copolymer of acrylic acid and a long-chain alkyl methacrylate cross-linked with allyl ethers of pentaerythritol. Carbomer 1342, previously dried under vacuum at 80° for 1 h, contains NLT 52.0% and NMT 62.0% of carboxylic acid (–COOH) groups. The viscosity of a neutralized 1.0% aqueous dispersion of Carbomer 1342 is between 9500 and 26,500 centipoises.

IDENTIFICATION
A.
Sample dispersion: 10 mg/mL
Analysis 1: To one portion of the Sample dispersion add thymol blue.
Acceptance criteria 1: An orange color is produced.
Analysis 2: To another portion of the Sample dispersion add cresol red.
Acceptance criteria 2: A yellow color is produced.
B.
Sample dispersion: 10 mg/mL
Analysis: Adjust the Sample dispersion with 1 N sodium hydroxide to a pH of 7.5.
Acceptance criteria: A very viscous gel is produced.

ASSAY
Carboxylic Acid Content:
To pass the test.
Acceptance criteria: 52.0%–62.0% on the dried basis

Limit of Benzene:
To pass the test.
Acceptance criteria: NMT 0.2%
Loss on Drying:
Analysis: Dry a sample under vacuum at 80C for 1 h.
Acceptance criteria: NMT 2.0%
Viscosity—Rotational Methods:
To pass the test.
Acceptance criteria: 9500–26,500 centipoises
Packaging and Storage: Preserve in tight containers.
Labeling: Label to indicate that it is not intended for internal use. A carbomer copolymer manufactured using benzene and complying with the unique requirements of this monograph will be officially titled Carbomer 1342 and will not be referred to as Carbomer Copolymer.


Specifications of Carbomer Copolymer USP NF Grade:

DEFINITION
Carbomer Copolymer is a high molecular weight copolymer of acrylic acid and a long-chain alkyl methacrylate cross-linked with allyl ethers of polyalcohols.
[Note— The heading of this monograph does not constitute the official title for a Carbomer Copolymer manufactured with the use of benzene. When benzene is used in the manufacturing process, the name will be Carbomer 1342, provided it complies with the existing requirements in the Carbomer 1342 monograph. ]

IDENTIFICATION
A.
Infrared Absorption: Exhibits main bands at or near (±5) wavenumbers (/cm) 1710, 1454, 1414, 1245, 1172, 1115, and 801, with the strongest band at 1710.
B.
Sample: 5 g
Analysis: Add the Sample to 500 mL of water, and stir.
Acceptance criteria: A dispersion is formed, with a foam layer that persists after the dispersion is allowed to stand at room temperature for 1 h.

ASSAY
Content of Carboxylic Acid:
To pass the test.
Acceptance criteria: 52.0%–62.0%

Limit of Ethyl Acetate and Cyclohexane:
To pass the test.
Acceptance criteria
Ethyl acetate: NMT 0.5%
Cyclohexane: NMT 0.3%
Limit of Benzene:
To pass the test.
Acceptance criteria: The benzene peak response from the Sample solution is NMT half of that from the Standard solution, corresponding to NMT 2 microg/g.
Limit of Acrylic Acid:
To pass the test.
Acceptance criteria: NMT 0.25%
Loss on Drying:
Analysis: Dry under vacuum at 80° for 1 h.
Acceptance criteria: NMT 2.0%
Viscosity—Rotational Methods:
To pass the test.
Acceptance criteria:
Carbomer Copolymer A: 4,500–13,500 1% Viscosity Specification (mPa·s)
Carbomer Copolymer B: 10,000–29,000 1% Viscosity Specification (mPa·s)
Carbomer Copolymer C: 25,000–45,000 1% Viscosity Specification (mPa·s)
Packaging and Storage: Preserve in tight containers, at a temperature not exceeding 45C.
Labeling: If benzene has been used in the manufacturing process, the name of the article will be Carbomer 1342, provided it complies with and is labeled in accordance with the requirements set forth in that monograph. If benzene is not used in the manufacturing process, label it to indicate whether it is Type A, B, or C; and label it to state the measured viscosity, giving the viscosity measurement parameters, the concentration of the solution, and the type of equipment used; the solvent or solvents used in the polymerization process; and the nominal and residual solvent levels for each solvent.


Specifications of Carbomer Homopolymer USP NF Grade:

DEFINITION
Carbomer Homopolymer is a high molecular weight polymer of acrylic acid cross-linked with allyl ethers of polyalcohols. Carbomer Homopolymer, previously dried, contains NLT 56.0% and NMT 68.0% of carboxylic acid (–COOH) groups.
[Note— This monograph applies to, but is not limited to, Carbomer 934, Carbomer 934P, Carbomer 940, and Carbomer 941 manufactured without benzene. The heading of this monograph does not constitute the official title for a Carbomer Homopolymer manufactured with the use of benzene. When benzene is used in the manufacturing process, the name of the article will be Carbomer 934, Carbomer 934P, Carbomer 940, or Carbomer 941, whichever is appropriate. ]

IDENTIFICATION
A.
Infrared Absorption: Exhibits main bands at or near (±5) wavenumbers (/cm) 1710, 1454, 1414, 1245, 1172, 1115, and 801, with the strongest band at 1710.
B.
Sample dispersion: 10 mg/mL
Analysis: Adjust the Sample dispersion with 1 N sodium hydroxide to a pH of 7.5.
Acceptance criteria: A viscous gel is produced.
C.
Analysis: Add 2 mL of calcium chloride solution (100 mg/mL), while stirring, to 10 mL of the gel obtained from Identification test B.
Acceptance criteria: A white precipitate is produced immediately.
D.
Sample dispersion: 10 mg/mL
Analysis 1: Add 0.5 mL of thymol blue to 10 mL of the Sample dispersion.
Acceptance criteria 1:  An orange color is produced.
Analysis 2: To another 10 mL of the Sample dispersion add 0.5 mL of cresol red.
Acceptance criteria 2: A yellow color is produced.

ASSAY
Content of Carboxylic Acid:
To pass the test.
Acceptance criteria: 56.0%–68.0%

Residue on Ignition:
Sample: 1.0 g
Acceptance criteria: NMT 4.0%
Limit of Ethyl Acetate and Cyclohexane:
To pass the test.
Acceptance criteria:
Ethyl acetate: NMT 0.5%
Cyclohexane: NMT 0.3%
[Note— This test is required only for those Carbomer Homopolymers where ethyl acetate or a mixture of ethyl acetate and cyclohexane was used in the polymerization process. ]
Limit of Benzene:
To pass the test.
Acceptance criteria: NMT 2 microg/g; the benzene peak response from the Sample solution is NMT half of that from the Standard solution.
Limit of Acrylic Acid:
To pass the test.
Acceptance criteria: NMT 0.25%
Loss on Drying:
Analysis: Dry under vacuum at 80° for 1 h.
Acceptance criteria: NMT 2.0%
Viscosity—Rotational Methods:
To pass the test.
Carbomer Homopolymer A: 4,000–11,000 Viscosity Specified (mPa·s)
Carbomer Homopolymer B: 25,000–45,000 Viscosity Specified (mPa·s)
Carbomer Homopolymer C: 40,000–60,000 Viscosity Specified (mPa·s)
Packaging and Storage: Preserve in tight containers, at a temperature not exceeding 45V.
Labeling: Label it to indicate whether it is Type A, B, or C; and label it to state the measured viscosity, giving the viscosity measurement parameters, the concentration of the solution, and the type of equipment used; the solvent or solvents used in the polymerization process; and the nominal and residual solvent levels for each solvent.


Specifications of Carbomer Interpolymer USP NF Grade:

DEFINITION
Carbomer Interpolymer is a carbomer homopolymer or copolymer that contains a block copolymer of polyethylene glycol and a long-chain alkyl acid ester.

IDENTIFICATION
A.
Infrared Absorption: Exhibits bands at or near (±5) wavenumbers (/cm) 1710, 1454, 1414, 1245, 1172, 1115, and 801, with the strongest band at 1710.
B.
Sample: 2.5 g
Analysis: Without mixing, add the Sample to 500 mL of water in an 800-mL beaker, and allow to stand.
Acceptance criteria: The powders wet out in NMT 60 min.
C.
Sample: 5 g
Analysis: Add the Sample to 500 mL of water, stir, and adjust with 1 N sodium hydroxide to a pH of 7.5.
Acceptance criteria: A viscous gel is formed.

ASSAY
Content of Carboxylic Acid:
To pass the test.
Acceptance criteria: 52.0%–62.0%

Limit of Ethyl Acetate and Cyclohexane:
Acceptance criteria:
Ethyl acetate: NMT 0.35%
Cyclohexane: NMT 0.15%
[Note— This test is required only for those Carbomer Interpolymers where the labeling indicates that ethyl acetate or a mixture of ethyl acetate and cyclohexane was used in the polymerization process. ]
Limit of Benzene:
To pass the test.
Acceptance criteria: The benzene peak response from the Sample solution is NMT half of that from the Standard solution, corresponding to NMT 2 microg/g.
Limit of Acrylic Acid:
To pass the test.
Acceptance criteria: NMT 0.25%
Loss on Drying:
Analysis:  Dry under vacuum at 80C for 1 h.
Acceptance criteria:  NMT 2.0%
Viscosity—Rotational Methods:
Carbomer Interpolymer A: 45,000–65,000 Viscosity Specifications (mPa·s)
Carbomer Interpolymer B: 47,000–77,000 Viscosity Specifications (mPa·s)
Carbomer Interpolymer C: 8,500–16,500 Viscosity Specifications (mPa·s)
Packaging and Storage: Preserve in tight containers, at a temperature not exceeding 45C.
Labeling: Label it to indicate whether it is Type A, B, or C. Also label it to state the measured viscosity, giving the viscosity measurement parameters, the concentration of the solution, and the type of equipment used; the solvent or solvents used in the polymerization process; and the nominal and measured residual solvent levels for each solvent.


Specifications of Carbomers BP Ph Eur:
Action and use: Stabilizer in pharmaceutical products.

DEFINITION
High-molecular-mass polymers of acrylic acid cross-linked with alkenyl ethers of sugars or polyalcohols.
Content: 56.0 per cent to 68.0 per cent of carboxylic acid (-CO2H) groups (dried substance).

CHARACTERS
Appearance: White or almost white, fluffy, hygroscopic powder.
Solubility: Swells in water and in other polar solvents after dispersion and neutralisation

with sodium hydroxide solution.
IDENTIFICATION
First identification: A
Second identification: B, C, D
A. Infrared absorption spectrophotometry.
Main bands At 1710 ± 5 cm-1, 1454 ± 5 cm-1, 1414 ± 5 cm-1, 1245 ± 5 cm-1, 1172 ± 5 cm-1, 1115 ± 5 cm-1 and 801 ± 5 cm-1, with the strongest band at 1710 ± 5 cm-1.
B. Adjust a 10 g/L dispersion to about pH 7.5 with 1 M sodium hydroxide. A highly viscous gel is formed.
C. Add 2 mL of a 100 g/L solution of calcium chloride, with continuous stirring, to 10 mL of the gel from identification test B. A white precipitate is immediately produced.
D. Add 0.5 mL of thymol blue solution to 10 mL of a 10 g/L dispersion. An orange colour is produced. Add 0.5 mL of cresol red solution to 10 mL of a 10 g/L dispersion. A yellow colour is produced.

TESTS
Free acrylic acid: To pass the test.
Limit: — acrylic acid: not more than the area of the corresponding peak in the chromatogram obtained with the reference solution (0.25 per cent).
Benzene: To pass the test.
Limit: — benzene: the mean area of the peak due to benzene in the chromatograms obtained with the test solution is not greater than 0.5 times the mean area of the peak due to benzene in the chromatograms obtained with the reference solution (2 ppm).
Loss on drying: Maximum 3.0 per cent, determined on 1.000 g by drying in vacuo at 80C for 60 min.
Sulfated ash: Maximum 4.0 per cent, determined on 1.0 g.
Apparent viscosity: The nominal apparent viscosity is typically between 300 mPas and 115 000 mPas. For a product with a nominal apparent viscosity of 20 000 mPas or greater, the apparent viscosity is typically 70.0 per cent to 130.0 per cent of the nominal value; for a product with a nominal apparent viscosity of less than 20 000 mPas, the apparent viscosity is typically 50.0 per cent to 150.0 per cent of the nominal value.

ASSAY
Slowly add 50 mL of water to 0.120 g whilst stirring and heating at 60 °C for 15 min. Stop heating, add 150 mL of water and continue stirring for 30 min. Add 2 g of potassium chloride and titrate with 0.2 M sodium hydroxide, determining the end-point potentiometrically.
1 mL of 0.2 M sodium hydroxide is equivalent to 9.0 mg of carboxylic acid (-CO2H) groups.

STORAGE
In an airtight container.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

Manufacturers:

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Carbomer or Polyacrylic acid SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 07-Oct-20

Section 1: Chemical Product and Company Identification

Product Name & Other Names: Carbomer or Polyacrylic acid.
CAS Number: 9003-01-4, 9007-16-3, 9007-17-4, 9062-04-8, 76050-42-5.
EINECS EC Code: 618-347-7 or 202-415-4
Molecular Formula: (C3H4O2)n
Molecular Weight: Variable
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling Regulation EC 1272/2008 (CLP) & GHS

GHS Label Elements
NONE

Signal Word: None

Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Section 3: Composition and Information on Ingredients

Product Name & Other Names: Carbomer or Polyacrylic acid.
CAS Number: 9003-01-4, 9007-16-3, 9007-17-4, 9062-04-8, 76050-42-5
EINECS EC Code: 618-347-7 or 202-415-4

Section 4: First Aid Measures

Always seek medical advice after the first aid treatment.

Skin: Rinse with water. Soap may be used. Seek Medical Aid.
Eyes: Wash eyes with plenty of water for at least 15 minutes, lifting lids occasionally. Seek Medical Aid.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Ingestion: If swallowed, induce vomiting immediately after giving two glasses of water. Never give anything by mouth to an unconscious person.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.
Products of Combustion: Fumes and Oxides of Carbon.
Fire Fighting Media and Instructions: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Section 6: Accidental Release Measures

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Do not inhale vapors, mist, or gas. Avoid dust formation. Finish cleaning by spreading water on the contaminated surface and allow as per law.

Section 7: Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents.

Section 8: Exposure Controls/Personal Protection

Exposure Limits: Not established.
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume, or mist, use ventilation to keep exposure to airborne contaminants low.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid white, fluffy powder.
Odor: odorless.
Odor threshold: Not available.
pH (5% soln/water): Acidic.
Relative density: around 1.4
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Viscosity: Not available.
Molecular Formula: (C3H4O2)n
Molecular Weight: Variable.

Section 10: Stability and Reactivity Data

Stability: It is stable in room temperature in closed containers under normal storage & handling.
Conditions of instability: Incompatible materials, Moisture
Incompatibility with various substances: Avoid high temperatures, sparks, open flames and moisture. Avoid contact with strong oxidizing agents.
Polymerization: Will not occur.

Section 11: Toxicological Information

LD50 Oral - Rat - > 1500 mg/kg
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH, OSHA.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Section 12: Ecological Information

Toxicity to fish: Not available.
BOD5 and COD: Not available.
Products of Biodegradation: The product itself and its products of degradation are not toxic.
Persistence and Degradability: It is degradable.
Mobility: Mobile due to degradability.
Bioaccumulation/ Accumulation: Unlikely to accumulate.
Results of PBT and vPvB assessment: No data available for assessment.

Section 13: Disposal Considerations

Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT USA: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
ADR/RID Europe: Not dangerous goods.

Section 15: Other Regulatory Information

USA Regulations:
OSHA: None of the chemicals in this product are considered highly hazardous by OSHA.
California Prop 65: California No Significant Risk Level: None of the chemicals in this product are listed.

Section 16 - Additional Information

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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