Chromium Chromic Chloride SDS, MSDS Sheet

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Chromic Chloride SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
02-Dec-20

Section 1: Product and Company Identification

Product Name & Other Names : Chromic chloride hexahydrate or Chromium chloride hexahydrate
CAS No.: 10060-12-5
EINECS, EC Number: 233-038-3
Molecular Weight: 266.45
Chemical Formula: CrCl3-6H2O
Relevant uses and uses advised against (if any): Industrial use only.
Supplier: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Corrosive to metals Category 1, H290
Acute toxicity, Oral Category 4, H302
Skin corrosion/irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3, H332
Acute toxicity, Inhalation Category 4, H335
Hazardous to the aquatic environment, acute hazard Category 3

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Corrosive
Corrosive

Signal Words: Warning

Hazard statements:
H290: May be corrosive to metals.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation
H402: Harmful to aquatic life.

Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P261: Remove/Take off immediately all contaminated clothing.
P264 Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P330 : Rinse mouth
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn Harmful
C Corrosive
Risk Phrase:
R20/22 Harmful by inhalation and if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R52 Harmful to aquatic organisms.

Section 3: Composition / Information on Ingredients

Product Name & Other Names: Chromic chloride hexahydrate or Chromium chloride hexahydrate
CAS No.: 10060-12-5
EINECS, EC Number: 233-038-3

Section 4: First Aid Measures

Always seek medical attention after first aid measures are provided.

Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally.
Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing.
Ingestion: Call Emergency Medical immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink. Induce vomiting immediately.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration.

Section 5: Fire Fighting Measures

It is non-flammable solid. When heated to decomposition, emits acrid fumes.
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.
Special hazards arising from the substance or mixture: Hydrogen chloride gas, Chromium oxides
Protective equipment and precautions for firefighters:
Use foam or dry chemical to extinguish fire. Firefighters should wear full fire fighting turn-out gear and respiratory protection. Cool container with water spray. Material is not sensitive to impact or static discharge.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Section 6: Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Section 7: Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents and lithium.

Section 8: Exposure Controls / Personal Protection

Exposure guidelines: OSHA PEL: 0.5 mg/m3, ACGIH: TLV: 0.5 mg/m3, STEL: Not Available.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9: Physical and Chemical Properties

Appearance: Solid. Green crystals or powder.
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: around 2.87
Melting Point: 1150C (2102F).
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: 1300C (2372F).
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Very slightly soluble in hot water.
Viscosity: Not available.
Molecular Formula : CrCl3 · 6H2O
Molecular Weight:
266.45 g/mole

Section 10: Stability and Reactivity

Avoid heat and ignition sources.
Stability: Stable under normal conditions of use and storage.
Incompatibility: Lithium and nitrogen.
Shelf life: Indefinite if stored properly.

Section 11: Toxicology Information

Chromium Chloride:
LD50 [oral, rat]; 1790 mg/kg; LC50 [rat]; N/A; LD50 Dermal [rabbit]; N/A
Carcinogenicity: 3 - Group 3: Not classifiable as to its carcinogenicity to humans by IARC.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Section 12: Ecological Information

Ecotoxicity (aquatic and terrestrial): Contains a heavy metal – toxic to terrestrial and aquatic plants and animals. Do not release to environment.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Section 13: Disposal Considerations

Check with all applicable local, regional, and national laws and regulations.

Section 14: Transport Information

DOT USA, TDG Canada & ADR/RID Europe:
UN-No UN3260
Proper Shipping Name Corrosive solid, acidic, inorganic, n.o.s. Chromic chloride.
Hazard Class 8 Packing Group III.
IMDG/IMO & IATA/ICAO:
UN-No UN3260
Proper Shipping Name Corrosive solid, acidic, inorganic, n.o.s. Chromic chloride.
Hazard Class 8 Packing Group III.

Section 15: Regulatory Information

USA:
California Proposition 65
: Not listed.

Section 16: Other Information

European Labeling in Accordance with EC Directives:
H290: May be corrosive to metals.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation
H402: Harmful to aquatic life.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn Harmful
C Corrosive
Risk Phrase:
R20/22 Harmful by inhalation and if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R52 Harmful to aquatic organisms.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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Last 5 October, 2023

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