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Manganese Chloride Tetrahydrate SDS MSDS Sheet

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MSDS of Manganese Chloride Manufacturers

Manganese Chloride Commercial Pure Specifications

Manganese Chloride ACS Analytical Reagent FCC Food Grade Manufacturers

Manganese Chloride SDS MSDS Sheet, Material Safety Data Sheet

Section 1: Chemical Product and Company Identification

Product Name: Manganese Chloride Tetrahydrate
CAS#: 13446-34-9
EINECS EC Number: 231-869-6
TSCA: TSCA 8(b) inventory: Manganese chloride tetrahydrate
Molecular Formula: MnCl2.4H2O
Molecular Weight: 197.92
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)

Acute toxicity, oral Category 4
Hazardous to the aquatic environment, acute hazard Category 3

Labeling Regulation EC 1272/2008 (CLP) & GHS

GHS Label Elements
Irritant
Irritant

Signal Words: Warning

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xn Harmful R22, R52
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

Hazard statements:
H302: Harmful if swallowed.
H402: Harmful to aquatic life.

Hazards not otherwise classified (HNOC):
May be slightly  harmful in contact with skin
May causes mild eye irritation

Precautionary statements:
P264: Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P330: Rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P501: Dispose of contents/ container to an approved waste disposal plant.

Section 3: Composition and Information on Ingredients

Composition: Manganese chloride tetrahydrate
CAS #: 13446-34-9
EINECS EC Number: 231-869-6
% by Weight: 100%

Section 4: First Aid Measures

Always seek medical attention after first aid measures are provided.

Eye Contact: Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention.
Skin Contact: After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used. Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Ingestion: Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.

Section 6: Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions: Do not ingest. Do not breathe dust. Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes.
Storage: No specific storage is required. Use shelves or cabinets sturdy enough to bear the weight of the chemicals. Be sure that it is not necessary to strain to reach materials, and that shelves are not overloaded.

Section 8: Exposure Controls/Personal Protection

Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection: Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling. Exposure Limits: TWA: 1 STEL: 3 (mg/m3) from ACGIH.

Section 9: Physical and Chemical Properties

Physical State: Solid crystals or powder
Appearance: pink-red
Odor: none reported
pH: 5.5
Boiling Point: 1190 deg C; 2174 deg F
Melting Point: 58 deg C
Decomposition Temperature: > 100 deg C
Solubility: 72%
Specific Gravity/Density:2.977 @ 25C
Molecular Formula: MnCl2.4H2O
Molecular Weight: 197.92

Section 10: Stability and Reactivity Data

Stability: Manganese Chloride  is stable.
Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Polymerization: No.

Section 11: Toxicological Information

Toxicity to Animals: Acute oral toxicity (LD50): 1454 mg/kg [Rat].
Chronic Effects on Humans: The substance is toxic to lungs, the nervous system, mucous membranes.
Carcinogenicity: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.

Section 12: Ecological Information

Toxicity to fish: LC50 - Carassius auratus (goldfish) - 18,8 mg/l - 7 d
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - > 11 mg/l - 48 h
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Section 13: Disposal Considerations

Waste Disposal: To be done as per legal requirement.
Section 14: Transport Information
DOT & ADR/RID: Not regulated.
IMDG: Not regulated.
IATA: Not regulated.

Section 15: Other Regulatory Information

USA Regulations:
Pennsylvania RTK: Manganese chloride tetrahydrate
Massachusetts RTK: Manganese chloride tetrahydrate
TSCA 8(b) inventory: Manganese chloride tetrahydrate
SARA 313 toxic chemical notification and release reporting: Manganese chloride tetrahydrate
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
HMIS (Perceived): Health Hazard: 2, Fire Hazard: 0, Reactivity: 0, Personal Protection: E
NFPA (Perceived): Health: 2, Flammability: 0, Reactivity: 0, Specific hazard:

Canada WHMIS: CLASS D-2A: Material causing other toxic effects (VERY TOXIC).

Section 16: Other Information

EINECS EC Number: 231-869-6
H302 = Harmful if swallowed.
H402 = Harmful to aquatic life.
Xn = Harmful
R22 = Harmful if swallowed.
R52 = Harmful to aquatic organisms.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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e-mail: info@mubychem.com

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Last 20 May, 2017

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