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Sodium propionate SDS MSDS Sheet
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Sodium Propionate MSDS Sheet, Material Safety Data Sheet
Propionic Acid, Sodium Salt Sodium Propionate
Sodium Propionate SDS MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Synonyms: Sodium Propionate, Propionic Acid Sodium Salt.
CAS No.: 137-40-6
EINECS EC Number: 205-290-4
Molecular Weight: 96.06
Chemical Formula: CH3CH2COONa
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2B
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3
Labeling according Regulation (EC) No 1272/2008
GHS Label Elements
Signal Word: Warning
H315: Causes skin irritation.
H320: Causes eye irritation.
H335: May cause respiratory irritation.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
According to European Directive 67/548/EEC as amended:
Hazard symbol(s): Xi: Irritant
R-phrase(s): R21 Harmful in contact with skin.
S-phrase(s): S36/37 Wear suitable protective clothing and gloves.
3. Composition/Information on Ingredients
Ingredient: Propionic Acid, Sodium Salt or Sodium Propionate
CAS Number: 137-40-6
EINECS EC Number: 205-290-4
Percent: 90 - 100%
4. First Aid Measures
Inhalation: If a person breathes in large amounts of Sodium Propionate, move the exposed person to fresh air.
Ingestion: If large amounts were swallowed, give water to drink and get medical advice.
Skin Contact: In case of contact with Sodium Propionate, immediately wash skin with plenty of soap and water for at least 15 minutes.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.
5. Fire Fighting Measures
Fire: Sodium Propionate is not expected to be a fire hazard.
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Information: Firefighters should wear proper protective equipment and self-contained breathing apparatus with full face piece operated in positive pressure mode.
6. Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system.
7. Handling and Storage
Keep Sodium Propionate container tightly closed. Suitable for any general chemical storage area. Containers of Sodium Propionate may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: In general, dilution ventilation is a satisfactory health hazard control for this substance. However, if conditions of use create discomfort to the worker, a local exhaust system should be considered.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to Sodium Propionate is apparent and engineering controls are not feasible, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance: Sodium Propionate is white powder.
Odor: No information found.
Solubility: Appreciable (> 10%)
Boiling Point: No information found.
Melting Point: 285C (545F)
10. Stability and Reactivity
Stability: Sodium Propionate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents.
11. Toxicological Information
LD50 Oral - mouse - 6.332 mg/kg
LD50 Dermal - rabbit - 1.640 mg/kg
Carcinogenic Effects: Not a reported carcinogen by IARC NTP ACGIH OSHA.
12. Ecological Information
Toxicity to fish: LC50 - Pimephales promelas (fathead minnow) - 4.740 mg/l - 96 h
Environmental Fate: No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Waste must be disposed of in accordance with federal, state and local environmental control regulations.
14. Transport Information
DOT & ADR/RID: Not regulated
TDG: Not regulated
IATA: Not regulated
IMDG/IMO: Not regulated
15. Regulatory Information
TSCA 8(b) inventory: Sodium propionate
TSCA: Propionic Acid, Sodium Salt (137-40-6) Yes
SARA 302: Propionic Acid, Sodium Salt (137-40-6) No
SARA 313: Propionic Acid, Sodium Salt (137-40-6) No
SARA 311/312: Acute: No; Chronic: No; Fire: No; Pressure: No; Reactivity: No (Pure / Solid) Chemical Weapons Convention: No; TSCA 12(b): No; CDTA: No
Canada WHMIS: Not controlled under WHMIS (Canada).
Canada DSL: Propionic Acid, Sodium Salt (137-40-6): Yes
Section 16 - Additional Information
EINECS EC Number: 205-290-4
H315 = Causes skin irritation.
H320 = Causes eye irritation.
H335 = May cause respiratory irritation.
Xi = Irritant
R21 = Harmful in contact with skin.
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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Last 21 August, 2017
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