1,3 Dibromopropane or Trimethylene dibromide or Trimethylenebromide Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of 1,3 Dibromopropane or Trimethylene dibromide, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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1,3 Dibromopropane or Trimethylene dibromide or Trimethylenebromide: CAS Number: 109-64-8, EINECS EC Number: 203-690-3, Molecular Formula: Br-CH2CH2CH2-Br or (CH2)3Br2, Molecular Weight: 201.89, HS Code ---**

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SDS MSDS Sheet of 1,3 Dibromopropane or Trimethylene dibromide or Trimethylenebromide Manufacturers

1,3 Dibromopropane
Trimethylene dibromide or Trimethylenebromide Pure Suppliers
1,3 Dibromopropane

1,3-Dibromopropane is an organobromine compound with the formula (CH2)3Br2. It is a colorless liquid with sweet odor. It is used in organic synthesis to form C3-bridged compounds such as through C-N coupling reactions. 1,3 Dibromopropane is used as intermediate for synthesis of Pharmaceutical and Organic compounds.

Specifications of 1,3 Dibromopropane, Dibromopropane:
Formula: Br-CH2CH2CH2-Br
Appearance: Clear colorless to light yellow liquid.
Odor: Sweet.
Relative density: 1.99
Melting point: -34 to -35C literature.
Flash point: 54C literature.
Boiling point: 167C literature.
Solubility: Miscible with Alcohol & ether
Moisture: 0.2 % maximum
Other impurities: 1% maximum
Assay: 99% minimum.

We manufacture and supply the entire range of bromine based organic chemicals and inorganic bromide chemicals:

Allyl Bromide

Acetyl Bromide

Benzyl Bromide

Bromobenzene

4-Bromobiphenyl

2 Bromobutane

Isobutyl Bromide

N-Butyl Bromide

1 Bromo 3 chloropropane

4-bromo-1,2-diaminobenzene

5-Bromo-2-Chlorobenzoic Acid

4-Bromo-2, 2-Diphenylbutyronitrile

4-Bromoiodobenzene

N-Bromosuccinimide

Cis Bromo Benzoate

1,4-Dibromobutane

1,3 Dibromopropane

1,3 Dibromo 5,5 Dimethylhydantoin

1,3-Dichloro-5,5-Dimethylhydantoin

Diphenylmethane

Diphenylacetonitrile

1,6 Dibromohexane

Ethyl Bromide

Ethyl Bromoacetate

Ethyl Triphenyl Phosphonium Bromide

Isopropyl Bromide

Isopropyl Iodide or 2-Iodopropane

Methyl Triphenyl Phosphonium Bromide

Para Bromophenol

Para Bromotoluene

Phosphorus Tribromide

N Pentyl Bromide

N-Propyl Bromide

Propionyl Bromide

Tetrabutylammonium bromide

Trimethylolpropane

We also supply several inorganic bromides and bromates.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

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Last 20 October, 2023

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1,3 Dibromopropane or Trimethylene dibromide SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 26-Nov-20

1. Product Identification

Product Name & Other Names: 1,3 Dibromopropane or Trimethylene dibromide or Trimethylenebromide.
CAS No.: 109-64-8
EINECS EC Number: 203-690-3
Molecular Formula: Br-CH2CH2CH2-Br or (CH2)3Br2
Molecular Weight: 201.89
Relevant uses and uses advised against (if any): Laboratory and Industrial Use.
Supplier: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable liquids Category 3, H226
Acute toxicity, oral Category 4, H302
Skin corrosion/irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Hazardous to the aquatic environment, long-term hazard Category 2, H411

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
flammable.png
Flammable

GHS Label Elements
irritant.png
Irritant

GHS Label Elements
marinepollutant.png
Aquatic Toxicity

Signal Words: Danger

Hazard Statements:
H226: Flammable liquid and vapor.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H411: Toxic to aquatic life with long lasting effects.

Precautionary Statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P310: IF SWALLOWED: Immediately call a POSION CENTER or doctor/physician.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P370+378: In case of fire: Use Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2).  Do not use a solid water stream as it may scatter and spread fire.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
F Flammable
Xi Irritant
Xn Harmful
N Dangerous for the environment.
Risk Phrases:
R10 Flammable
R22 Harmful if swallowed
R36/38, Irritating to eyes and skin
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

3. Composition/Information on Ingredients

Product Name & Other Names: 1,3 Dibromopropane or Trimethylene dibromide or Trimethylenebromide.
CAS No.: 109-64-8
EINECS EC Number: 203-690-3

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention.
Ingestion: Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Use a mild soap if available. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. For minor skin contact, avoid spreading material on unaffected skin.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Flammable. Containers may explode when heated.
Products of Combustion: Carbon oxides, hydrogen bromide and toxic fumes.
Fire Extinguishing Media: Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Avoid a solid water stream as it may scatter and spread fire. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Special Information: Fire may produce irritating, corrosive and/or toxic gases. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
Keep away from heat and sources of ignition. Flash back possible over considerable distance. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6. Accidental Release Measures

Personal precautions: Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering. Keep out of low areas.
Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Methods for containment: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Vapors can accumulate in low areas. Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust). Dike the spilled material, where this is possible. Prevent entry into waterways, sewers, basements or confined areas.
Methods for cleaning up: Clean up in accordance with all applicable regulations. Should not be released into the environment.
Small Spill: Avoid dust/mist formation. Avoid breathing dust/mist. Ensure adequate ventilation. Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly.
Large Spill: Dike far ahead of liquid spill for later disposal. Use a non-combustible material like vermiculite, sand, or earth to soak up the product and place into a container for later disposal.

7. Handling and Storage

Precautions for safe handling: Do not handle or store near an open flame, heat or other sources of ignition. All equipment used when handling the product must be grounded. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wear suitable protective equipment. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Avoid prolonged exposure. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents, bases. Keep away from heat and sources of ignition (spark or flame). Keep containers tightly closed in a cool, well-ventilated place.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Exposure guidelines have not been established for this product. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Physical state: Liquid.
Color: Clear colorless to light yellow liquid.
Odor: Sweet..
Odor threshold: Not available.
pH: Not available.
Relative density: 1.99
Flash Point: 54C literature.
Boiling  point: 167C literature.
Melting  point/Freezing  point: -34 to -35C literature.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Miscible with Alcohol & ether.
Viscosity: Not available.
Molecular Formula: Br-CH2CH2CH2-Br or (CH2)3Br2
Molecular Weight: 201.89

10. Stability and Reactivity

Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits carbon oxides, hydrogen bromide and toxic fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents, bases.
Conditions to Avoid: Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

11. Toxicological Information

Toxicity data:
LD50 Oral - Rat - 315 mg/kg
Carcinogenicity: Not expected to be hazardous by IARC, ACGIH, NTP & OSHA criteria.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. Ecological Information

Toxicity to fish: LC50 - Pimephales promelas (fathead minnow) - 1,79 mg/l - 96,0 h.
Aquatic toxicity: May cause long-term adverse effects in the aquatic environment.
Bioaccumulative potential: Not available.
Mobility in soil: Not available.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe:
Proper shipping name: FLAMMABLE LIQUID, N.O.S. (1,3-Dibromopropane).
UN number: 1993; Class: 3; Packing group: III
IMDG/IATA & IATA/ICAO:
Proper shipping name: FLAMMABLE LIQUID, N.O.S. (1,3-Dibromopropane).
UN number: 1993; Class: 3; Packing group: III

15. Regulatory Information

USA:
SARA 302 Components
: Not subject to the reporting requirements.
SARA 313 Components: Not listed.
SARA 311/312 Hazards: Fire Hazard, Acute Health Hazard. See section 2.
California Prop. 65 Components: Not listed.

Section 16 - Additional Information

European Labeling in Accordance with EC Directives:
H226: Flammable liquid and vapor.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H411: Toxic to aquatic life with long lasting effects.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
F Flammable
Xi Irritant
Xn Harmful
N Dangerous for the environment.
Risk Phrases:
R10 Flammable
R22 Harmful if swallowed
R36/38, Irritating to eyes and skin
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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