4-Hydroxyacetophenone or Piceol or 4-Hydroxyphenylethanone Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of 4-Hydroxyacetophenone or Piceol, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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4-Hydroxyacetophenone or Piceol or 4-Hydroxyphenylethanone or p-Acetophenol or p-Hydroxyphenyl methyl ketone: CAS Number: 99-93-4, EINECS EC Number: 202-802-8, Molecular Formula: C8H8O2 or HOC6H4COCH3, Molecular Weight: 136.15, FEMA Number: 4330, HS Code ---**

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SDS MSDS Sheet of 4-Hydroxyacetophenone or Piceol or 4-Hydroxyphenylethanone Manufacturers

4-Hydroxyacetophenone
Piceol or 4-Hydroxyphenylethanone Pure Suppliers
4-Hydroxyacetophenone

4-Hydroxyacetophenone or Piceol is used in the synthesis of several pharmaceutical drugs

General Properties and Specifications of 4-Hydroxyacetophenone or Piceol or 4-Hydroxyphenylethanone or p-Acetophenol or p-Hydroxyphenyl methyl ketone:
Appearance: White powder or crystalline solid. Hygroscopic.
Assay: 99% minimum.
Relative density: around 1.1
Melting point: 109C to 111C.
Boiling point: 147C to 148C.
Flash point: 166C.
Solubility: Slightly soluble in water.
Storage: Store below 30C.

We manufacture and supply as under:

Acetophenone

p-Aminoacetophenone or 4-Acetylaniline

Benzoin or Benzoylphenylcarbinol

Benzophenone

4-Hydroxyacetophenone

4-Hydroxybenzaldehyde

4-Hydroxybenzyl Alcohol

4-Hydroxycoumarin

4-Hydroxy Propiophenone.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

Manufacturers india
Copyright and Usual Disclaimer is Applicable.
Last 20 July, 2024

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4-Hydroxyacetophenone or Piceol or 4-Hydroxyphenylethanone SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
 28-Nov-20

1. Product Identification

Product Name & Other Names: 4-Hydroxyacetophenone or Piceol or 4-Hydroxyphenylethanone or p-Acetophenol or p-Hydroxyphenyl methyl ketone
CAS No.: 99-93-4
EINECS EC Number: 202-802-8
FEMA Number: 4330
Molecular Weight: 136.15
Chemical Formula: C8H8O2 or HOC6H4COCH3
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 4), H302
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
irritant.png
Irritant

Signal Words: Warning

Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P501: Dispose of contents/container to authorized agents only.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn Harmful
Xi Irritant
Risk Phrases:
R22 Harmful if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.

3. Composition/Information on Ingredients

Product Name & Other Names: 4-Hydroxyacetophenone or Piceol or 4-Hydroxyphenylethanone or p-Acetophenol or p-Hydroxyphenyl methyl ketone
CAS No.: 99-93-4
EINECS EC Number: 202-802-8
FEMA Number: 4330

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and get medical attention immediately.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing and shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Special hazards arising from the substance or mixture: Fumes and carbon oxides
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Contain spilled material. Irritating solid. Harmful solid. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Use water spray to reduce vapors.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizers, strong bases, acids, acid anhydrides, acid chlorides. Storage: Store below 30C.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: White powder or crystalline solid. Hygroscopic.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: around 1.1
Boiling Point: 147C to 148C.
Melting Point: 109C to 111C.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Slightly soluble in water.
Viscosity: Not available.
Molecular Weight: 136.15
Chemical Formula: C8H8O2 or HOC6H4COCH3

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide along with fumes may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers, strong bases, acids, acid anhydrides, acid chlorides.
Conditions to Avoid: Heat, dusting, moisture and incompatibles.

11. Toxicological Information

Oral rat LD50: 2240 mg/Kg
Dermal rabbit LD50: >2000 mg/Kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. Ecological Information

Environmental Toxicity:
Toxicity to fish: LC50: = 25 mg/L, 96h static (Oncorhynchus mykiss).
Toxicity to daphnia and other aquatic invertebrates: EC50 Daphnia magna (Water flea): 50 mg/l; 48 h.
Persistence and Degradability: Unlikely to persist due to its water solubility.
Mobility: Likely to be mobile.
Bioaccumulation/ Accumulation: Unlikely to accumulate.
Results of PBT and vPvB assessment: No data available for assessment.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused material in accordance with legal requirements.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods.
IMDG/IMO: Not dangerous goods.
IATA/ICAO: Not dangerous goods.

15. Regulatory Information

USA:
SARA 311/312: Acute health hazard and Chronic health hazard as per section 2.
SARA 313: Not applicable.
California Prop 65: Not listed.

16. Other Information

European Labeling in Accordance with EC Directives:
H302 = Harmful if swallowed.
H315 = Causes skin irritation.
H319 =Causes serious eye irritation.
H335 = May cause respiratory irritation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn Harmful
Xi Irritant
Risk Phrases:
R22 Harmful if swallowed.
R36/37/38 Irritating to eyes, respiratory system, and skin.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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