CAS Number, 101-86-0, Hexyl Cinnamic Aldehyde α Hexyl cinnamaldehyde Manufacturers with SDS, MSDS Sheet

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Hexyl Cinnamic Aldehyde
CAS No.101-86-0; EINECS No. 202-983-3; FEMA No. 2569
Hexyl Cinnamaldehyde, Molecular Weight 216.32, Molecular Formula C15H20O

Hexyl Cinnamic Aldehyde

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Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail prices, Uses etc available on these pages for Hexyl Cinnamic Aldehyde or α Hexyl cinnamaldehyde.

Hexyl Cinnamaldehyde

CAS: 101-86-0
Synonyms: α-n Hexyl Cinnamic Aldehyde, α-Hexyl cinnamaidehyde; α-n-Hexyl-β-Phenylacrolein; AHCA; HCA
Octanal, 2-(phenylmethylene)
EINECS Number: 202-983-3
HS Number: 2912290000
Molecular Weight: 216.32
Molecular Formula: C15H20O

Odor Profile: Floral, Jasmin, Waxy
Olfactory Description: Similar to alpha amyl cinnamic aldehyde but with a finer, more floral and delicate character.
Visual Description: Clear yellow liquid
GC Analysis ------------- Min --- Max
trans isomer ------------ 90% --- 95%
cis isomer -------------- 3% ---- 8.5%
cis + trans isomers ----- 95%
Acid Value (mg KOH/gm) -- 0 ----- 0.5
Fla shpoint (closed cup)- > 100C

USES: Very extensively used in perfumes where it produces a jasmine-like floral when accompanied by more volatile chemicals of floral character. Blends easily and assists in fixation of the fragrance. It is also used in Soap, Acid Cleaner Liquid, Detergent, Alcoholic Lotion, Fabric Softener, Anti Perspirant, Foam Bath, Hard Surface Cleaner, Deo Stick, Shampoo, Bleach.

Hexyl Cinnamic Aldehyde, α Hexyl Cinnamaidehyde SDS MSDS Sheet
Material Safety Data Sheet

1 - Product Identification

Product Name & Other Names: Hexyl Cinnamic Aldehyde or alpha-hexylcinnamaldehyde.
CAS Number 101-86-0
EINECS EC Number: 202-983-3
Molecular Formula: C6H5CH=C[(CH2)5CH3]CHO
Molecular Weight: 216.32
Relevant uses and uses advised against (if any): Laboratory and Industrial Manufacturing.
SUPPLIER: As per letterhead.

2 - Hazards identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Dermal (Category 5), H313
Skin irritation (Category 3), H317
Eye irritation (Category 2A), H319

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements

Signal Words: Warning

Hazard statements:
H313: May be harmful in contact with skin.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P363: Wash contaminated clothing before reuse.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P302+ P352 - IF ON SKIN: Wash with plenty of soap and water.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xi Irritant.
Xn Harmful.
R Phrases:
R36 Irritating to eyes.
R21 Harmful in contact with skin.
R43 May cause sensitization by skin contact.

3 - Composition / information on ingredients

Product Name & Other Names: Hexyl Cinnamic Aldehyde or alpha-hexylcinnamaldehyde.
CAS Number 101-86-0
EINECS EC Number: 202-983-3
4 - First aid measures
Always seek medical attention after first aid measures are provided.
Eye contact: Immediately flush eyes with plenty of clean water for an extended time, not less than five (5) minutes. Flush longer if there is any indication of residual chemical in the eye. Ensure adequate flushing of the eyes by separating the eyelids with fingers and roll eyes in a circular motion.
Skin contact: Immediately remove contaminated clothing and shoes. Wash the affected area with plenty of soap and water until no evidence of the chemical remains. Launder clothing before reuse. If irritation develops, call a physician.
Inhalation: If affected, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.
Ingestion: Do not induce vomiting. Rinse out the mouth with water. Never give anything by mouth to an unconscious person. Get medical attention immediately.

5 - Firefighting measures

NFPA flammability class: IIIB
Flash point: >212 °F (>100 °C) in Tag Closed Cup
Fire and explosive properties: Combustible liquid will burn at high temperatures.
Extinguishing media: NFPA Class IIIB (Combustible liquid): Use water spray, ABC dry chemical, foam or carbon dioxide. Water or foam may cause frothing. Use water to keep fire-exposed containers cool. Water spray may be used to flush spills away from exposures.
Fire fighting instructions: Wear self-contained breathing apparatus (SCBA) equipped with a full face piece and operated in a pressure-demand mode (or other positive pressure mode) and approved protective clothing. Personnel without suitable respiratory protection must leave the area to prevent significant exposure to hazardous gases from combustion, burning or decomposition. In an enclosed or poorly ventilated area, wear SCBA during cleanup immediately after a fire as well as during the attack phase of fire fighting operations.
Unusual fire/explosion hazards: Irritating or toxic substances may be emitted upon burning, combustion or decomposition.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6 - Accidental release measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental  precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container. Avoid open flames or other sources of ignition.

7 - Handling and storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong acids, alkali, or oxidizing agents.
Fire Protection: Keep away from ignition sources and naked flame. Product can easily oxidize. It is recommended that opened containers be padded with nitrogen. Keep away from heat, sparks and open flames.

8 - Exposure controls / personal protection

Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Respiratory Protection: Avoid to breath directly on the product. Apply local ventilations when appropriate.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9 - Physical and chemical properties

Appearance: Pale yellow liquid.
: Jasmine.
Odor threshold: Not available.
pH: Not available.
Relative density: about 0.95 - 0.96 (25C).
Boiling point C: 305C (581F).
Melting point: 4C (39F).
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: <0.02 mm Hg @20C.
Vapor density: Not available.
Evaporation rate: < 0.01
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Negligible in water.
Viscosity: Not available.
Molecular Formula: C6H5CH=C[(CH2)5CH3]CHO
Molecular Weight: 216.32

10 - Stability and reactivity

Stability: This product is stable.
Hazardous polymerization: Hazardous polymerization will not occur.
Conditions to avoid: Excessive heat and ignition sources.
Incompatibility with other materials: Avoid contact with strong oxidizing agents.
Hazardous decomposition products: Carbon dioxide and carbon monoxide.

11 - Toxicological information

LD50 Oral: 3100 mg/kg Rat/ adult
LD50 Skin: >3000 mg/kg Rabbit/ adult
Carcinogenicity: No component of this product present at levels greaterthan or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12 - Ecological information

Toxicity to fish: No information available.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
No other ecological testing has been conducted on this product.

13 - Disposal information

Incinerate waste product when in liquid form (i.e., as supplied) in a properly permitted (approved) incineration facility in accordance with local regulations. Liquids cannot be disposed of in a landfill. Do not release to waterways. Wash-water should be contained and sent to a waste facility for proper handling and disposal in accordance with all applicable regulations.

14 - Transportation information

DOT USA, TDG Canada & ADR/RID Europe: Not Regulated.
IMDG/IMO: Not Regulated.
IATA/ICAO: Not Regulated.

15 - Regulatory information

USA federal:
SARA 304 Emergency release notification: Not regulated.
SARA 302 Extremely hazardous substance: Not listed.
SARA 311/312 Hazardous chemical: No
SARA 313 (TRI reporting): Not regulated.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Not listed.

16. Other Information

European Labeling in Accordance with EC Directives:
H313: May be harmful in contact with skin.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xi Irritant.
Xn Harmful.
R Phrases:
R36 Irritating to eyes.
R21 Harmful in contact with skin.
R43 May cause sensitization by skin contact.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Hexyl Cinnamaldehyde manufacturers
Hexyl Cinnamic Aldehyde manufacturers suppliers at:

Ambernath Mumbai, Ankleshwar Gujarat, India
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Last 7 October, 2023

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Hexyl Cinnamic Aldehyde α Hexyl cinnamaldehyde Manufacturers