Cetylpyridinium Chloride monohydrate or Cetylpyridinium chloride monohydrate or Hexadecylpyridinium chloride monohydrate Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Cetylpyridinium Chloride, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Cetylpyridinium Chloride monohydrate or Hexadecylpyridinium chloride monohydrate: CAS Number: 123-03-5 and 6004-24-6 for monohydrate, EINECS EC Number: 204-593-9, Molecular Formula: C21H38ClN-H2O monohydrate, Molecular Weight: 358.00 monohydrate, HS Code ---**

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Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Cetylpyridinium Chloride monohydrate or Cetylpyridinium chloride monohydrate or Hexadecylpyridinium chloride monohydrate.

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SDS MSDS Sheet of Cetylpyridinium Chloride monohydrate or Cetylpyridinium chloride monohydrate or Hexadecylpyridinium chloride monohydrate Manufacturers

Cetylpyridinium Chloride monohydrate
Cetylpyridinium chloride monohydrate or Hexadecylpyridinium chloride monohydrate Pure Suppliers
Cetylpyridinium Chloride

Cetylpyridinium chloride is used to study the mechanisms of bacterial and virus inactivation. Generally, its monohydrate is used. A new safe & cost-effective preservative. An antiseptic used as active ingredient in over the counter, oral & personal care products. Cetylpyridinium chloride (CPC) is used in some types of mouthwashes, toothpastes, lozenges, throat sprays, breath sprays, and nasal sprays. It is an antiseptic that kills bacteria and other microorganisms. It has been shown to be effective in preventing dental plaque and reducing gingivitis. It has also been used as an ingredient in certain pesticides and for industrial purpose.

Properties and General Specifications of Cetylpyridinium Chloride monohydrate or Cetylpyridinium chloride monohydrate or Hexadecylpyridinium chloride monohydrate:
Appearance: White powder.
Assay: 99% minimum.
Water (KF): 4.5% to 5.5%
Residue on ignition (Ash): < 0.2%
Melting point: about 80C.
Solubility: Very soluble in water, chloroform.


Specifications of Cetylpyridinium Chloride USP NF Grade:
C21H38ClN-H2O --- 358.00
Pyridinium, 1-hexadecyl-, chloride, monohydrate.
1-Hexadecylpyridinium chloride monohydrate --- CAS 6004-24-6.
Anhydrous --- 339.99 [123-03-5].

Cetylpyridinium Chloride contains not less than 99.0 percent and not more than 102.0 percent of C21H38ClN, calculated on the anhydrous basis.
Packaging and storage: Preserve in well-closed containers.

Identification:
A: Infrared Absorption.
B: Ultraviolet Absorption.
C: Dissolve 100 mg in 50 mL of water: a 10-mL portion of the solution responds to the tests for Chloride, except that a turbidity is produced, rather than a curdy white precipitate, when the silver nitrate is added.
Melting range: between 80 and 84, the preliminary drying treatment being omitted.
Acidity: Dissolve 500 mg, accurately weighed, in 50 mL of water, add phenolphthalein and titrate with 0.020 N sodium hydroxide: not more than 2.5 mL is required for neutralization.
Water: between 4.5% and 5.5%.
Residue on ignition: not more than 0.2%, calculated on the anhydrous basis.
Heavy metals: 0.002%.
Pyridine: Dissolve 1 g in 10 mL of sodium hydroxide solution (1 in 10) without heating: the odor of pyridine is not immediately perceptible.
Assay: Transfer about 200 mg of Cetylpyridinium Chloride, accurately weighed, to a glass-stoppered, 250-mL graduated cylinder containing 75 mL of water. Add 10 mL of chloroform, 0.4 mL of bromophenol blue solution (1 in 2000), and 5 mL of a freshly prepared solution of sodium bicarbonate (4.2 in 1000) and titrate with 0.02 M sodium tetraphenylboron until the blue color disappears from the chloroform layer. Add the last portions of the sodium tetraphenylboron solution dropwise, agitating vigorously after each addition. Each mL of 0.02 M sodium tetraphenylboron is equivalent to 6.800 mg of C21H38ClN.


Specifications of Cetylpyridinium Chloride BP Ph Eur Grade:

C21H38ClN-H2O --- 358.0 --- CAS 6004-24-6 
Action and use: Antiseptic.

DEFINITION
Cetylpyridinium chloride contains not less than 96.0 per cent and not more than the equivalent of 101.0 per cent of 1-hexadecylpyridinium chloride, calculated with reference to the anhydrous substance.

CHARACTERS
A white or almost white powder, slightly soapy to the touch, soluble in water and in alcohol. An aqueous solution froths copiously when shaken.

IDENTIFICATION
First identification: B, D
Second identification: A, C, D
A. Dissolve 0.10 g in water and dilute to 100.0 mL with the same solvent. Dilute 5.0 mL of this solution to 100.0 mL with water. Examined between 240 nm and 300 nm, the solution shows an absorption maximum at 259 nm and 2 shoulders at about 254 nm and at about 265 nm. The specific absorbance at the maximum is 126 to 134, calculated with reference to the anhydrous substance.
B. Examine by infrared absorption spectrophotometry, comparing with the spectrum obtained with cetylpyridinium chlorideCRS. Examine the substances in the solid state.
C. To 5 mL of dilute sodium hydroxide solution add 0.1 mL of bromophenol blue solution and 5 mL of chloroform and shake. The chloroform layer is colourless. Add 0.1 mL of solution S (see Tests) and shake. The chloroform layer becomes blue.
D. Solution S gives reaction of chlorides.

TESTS
Solution S: Dissolve 1.0 g in carbon dioxide-free water and dilute to 100 mL with the same solvent.
Appearance of solution: Solution S is not more opalescent than reference suspension II and is colourless.
Acidity: To 50 mL of solution S add 0.1 mL of phenolphthalein solution. Not more than 2.5 mL of 0.02 M sodium hydroxide is required to change the colour of the indicator.
Amines and amine salts: Dissolve 5.0 g with heating in 20 mL of a mixture of 3 volumes of 1 M hydrochloric acid and 97 volumes of methanol and add 100 mL of 2-propanol. Pass a stream of nitrogen slowly through the solution. Gradually add 12.0 mL of 0.1 M tetrabutylammonium hydroxide and record the potentiometric titration curve. If the curve shows 2 points of inflexion, the volume of titrant added between the two points is not greater than 5.0 mL. If the curve shows no point of inflexion, the substance to be examined does not comply with the test. If the curve shows one point of inflexion, repeat the test but add 3.0 mL of a 25.0 g/L solution of dimethyldecylamine in 2-propanol before the titration. If the titration curve after the addition of 12.0 mL of the titrant shows only one point of inflexion, the substance to be examined does not comply with the test.
Water: 4.5 per cent to 5.5 per cent, determined on 0.300 g by the semi-micro determination of water.
Sulfated ash: Not more than 0.2 per cent, determined on 1.0 g.

ASSAY
Dissolve 2.00 g in water and dilute to 100.0 mL with the same solvent. Transfer 25.0 mL of the solution to a separating funnel, add 25 mL of chloroform, 10 mL of 0.1 M sodium hydroxide and 10.0 mL of a freshly prepared 50 g/L solution of potassium iodide. Shake well, allow to separate and discard the chloroform layer. Shake the aqueous layer with three quantities, each of 10 mL, of chloroform and discard the chloroform layers. To the aqueous layer add 40 mL of hydrochloric acid, allow to cool and titrate with 0.05 M potassium iodate until the deep brown colour is almost discharged. Add 2 mL of chloroform and continue the titration, shaking vigorously, until the chloroform layer no longer changes colour. Carry out a blank titration on a mixture of 10.0 mL of the freshly prepared 50 g/L solution of potassium iodide, 20 mL of water and 40 mL of hydrochloric acid.
1 mL of 0.05 M potassium iodate is equivalent to 34.0 mg of C21H38ClN.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

We also manufacture and supply as under:

Cetyl Alcohol or 1-Hexadecanol

Cetyl Palmitate or Hexadecyl Palmitate or Palmityl Palmitate or Palmitic Acid Palmityl Ester

Cetyltrimethylammonium Chloride or Cetrimonium Chloride

PAN Indicator or or (1(2-Pyridylazo)-2- Naphthol)

Cetylpyridinium Chloride

5-Ethyl-Pyridine-2-Ethanol

Pyridine.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

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Last 21 October, 2024

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Cetylpyridinium Chloride monohydrate or Hexadecylpyridinium chloride monohydrate SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
08-Oct-20

Section 1. Product Information

Product Name & Other Names: Cetylpyridinium Chloride monohydrate or Hexadecylpyridinium chloride monohydrate.
CAS No.: 123-03-5 anhydrous and 6004-24-6 for monohydrate
EINECS EC Number: 204-593-9
Chemical Formula: C21H38ClN-H2O monohydrate
Molecular Weight: 358.00 monohydrate
Relevant uses and uses advised against (if any)
: Industrial Manufacturing.
Suppliers: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 4, H302
Acute toxicity, Dermal Category 4, H312
Skin irritation Category 2, H315
Serious eye damage Category 1, H318
Acute toxicity, inhalation Category 2, H330
Specific target organ toxicity - single exposure Category 3, Respiratory system, H335
Short-term (acute) aquatic hazard Category 1, H400

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

GHS Label Elements
Corrosive
Corrosive

GHS Label Elements
toxic.png
Toxic

Signal Words: Danger

Hazard statements:
H302 + H312 Harmful if swallowed or in contact with skin.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.

Precautionary statements:
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P284: Wear respiratory protection.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P391: Collect spillage.
P405: Store locked up.
P403+233: Store in a well-ventilated place. Keep container tightly closed.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T Toxic
Xn Harmful
Xi Irritant.
N Dangerous for the environment
Risk Phrases:
R21/22 Harmful in contact with skin and if swallowed.
R23 Toxic by inhalation.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R50 Very toxic to aquatic organisms

Section 3: Composition and Information on Ingredients

Product Name & Other Names: Cetylpyridinium Chloride monohydrate or Hexadecylpyridinium chloride monohydrate.
CAS No.: 123-03-5 anhydrous and 6004-24-6 for monohydrate
EINECS EC Number: 204-593-9

Section 4. First Aid & Procedure

Always get medical attention after the first aid is over.

Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and shoes before reuse. Get medical attention if irritation develops.
Eyes:
Immediately flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower eyelids. Hold eyelids apart during irrigation. Get medical attention.
Inhalation:
Remove person to fresh air. If breathing is difficult, give oxygen. If not breathing administer artificial respiration. Get medical attention.

Section 5. Fire Fighting Measures

Flash Point: N/A
Fire/Explosion:
Not considered to be a fire and explosion hazard.
Extinguishing Medium:
Water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture: Fumes may evolve along with nitrogen oxide, carbon oxides and hydrogen chloride.
Fire Fighting Instructions: Use suitable protective equipment for surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Section 6. Spills and Disposals

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Don't touch or walk through this product. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container.

Section 7. Handling and Storage

Toxic hazardous material. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid prolonged or repeated exposure. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents.

Section 8. Exposure Controls & Personal Protection

Exposure Limits: Contains no components with established occupational exposure limits.
Engineering Controls: Use adequate exhaust ventilation to keep airborne concentrations below the allowable exposure limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9. Physical & Chemical Data

Appearance: White powder.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available
Melting Point: 80C.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Very soluble in water, chloroform.
Viscosity: Not available.
Chemical Formula: C21H38ClN-H2O monohydrate
Molecular Weight: 358.00 monohydrate.

Section 10. Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Incompatibility (Materials to Avoid):
Oxidizing agents, Acids.
Conditions to Avoid: Incompatible materials, excessive heat.
Hazardous Decomposition Products: Fumes may evolve along with nitrogen oxide, carbon oxides and hydrogen chloride.
Hazardous Polymerization:
Will not occur.

Section 11. Toxicological Information

Toxicity to Animals:
LC50 Inhalation - Rat - 4 h – 0.054 to 0.51 mg/l
LD50 Oral - Rat - 560 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, NTP ACGIH or OSHA.
Mutagenic Effects: No information found.
Reproductive Effects: No information found.
Developmental Toxicity: No information found.

Section 12. Ecological Information

Ecotoxicity: Very toxic to aquatic organisms.
Toxicity to fish: static test LC50 - Oncorhynchus mykiss (rainbow trout) – 0.16 mg/l  - 96 h.
Toxicity to daphnia and other aquatic invertebrates: semi-static test  - Daphnia magna (Water flea) – 0.0041 mg/l - 48 h.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Section 13. Disposal Suggestions

Dispose of in accordance with all applicable local, state and federal regulations at an approved waste disposal facility.

Section 14. Transport and Label Information

DOT (USA) & ADR/RID Europe:
UN-No UN 2811
Proper Shipping Name: Toxic solid, organic, n.o.s. (Cetylpyridinium chloride)
Hazard Class 6.1, Packing Group II
IMDG/IMO
UN-No UN 2811
Proper Shipping Name: Toxic solid, organic, n.o.s. (Cetylpyridinium chloride)
Hazard Class 6.1, Packing Group II
IATA:
UN-No UN 2811
Proper Shipping Name: Toxic solid, organic, n.o.s. (Cetylpyridinium chloride)
Hazard Class 6.1, Packing Group II

Section 15. Regulatory Information

USA:
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 311/312: Acute Health Hazard; Chronic Health Hazard, as per section 2.
California Prop.65: This product contains no chemical known to the State of California to cause birth defects or other reproductive harm.

Section 16. Other Information

European Labeling in Accordance with EC Directives:
H302 + H312 Harmful if swallowed or in contact with skin.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T Toxic
Xn Harmful
Xi Irritant.
N Dangerous for the environment
Risk Phrases:
R21/22 Harmful in contact with skin and if swallowed.
R23 Toxic by inhalation.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R50 Very toxic to aquatic organisms.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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