Triethyl Citrate Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Triethyl Citrate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Triethyl Citrate: CAS Number: 77-93-0, EINECS EC Number: 201-070-7, Molecular Formula: C12H20O7 or HOC(COOC2H5)(CH2COOC2H5)2, Molecular Weight: 276.28, FEMA Number: 3083, HS Code 2918 1500

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For SDS MSDS Sheet Click
SDS MSDS Sheet of Triethyl Citrate Manufacturers

Triethyl Citrate
Pure Suppliers
Triethyl Citrate

Triethyl citrate is used in foods as a flavoring agent, solvent, and surface-active agent Triethyl citrate is an ester of citric acid. It is a colorless, odorless liquid used as a food additive (E number E1505) to stabilize foams, especially as whipping aid for egg white. In pharmaceutical coatings and plastics. Triethyl citrate may also be used in cosmetics, personal care products, pharmaceutical coatings, and plastics.

General Properties and Specifications of Triethyl Citrate:
Appearance: Clear colorless or almost colorless oily liquid.
Assay: 99% minimum.
Melting point: -55C
Boiling point: 294C
Relative density: 1.14
Solubility: Soluble in water, miscible with ethanol (96 per cent).


Specifications of Triethyl Citrate USP NF Grade:
C12H20O7 --- 276.28

DEFINITION
Triethyl Citrate contains NLT 99.0% and NMT 100.5% of C12H20O7, calculated on the anhydrous basis.

IDENTIFICATION
A.
Infrared Absorption
B. The retention time of the major peak of the Sample solution corresponds to that of a similar preparation of USP Triethyl Citrate RS, as obtained in the Assay.
ASSAY
To pass the test by Chromatography.
Acceptance criteria: 99.0%–100.5% on the anhydrous basis
Specific Gravity: 1.135–1.139
Refractive Index: 1.439–1.441
Acidity:
Neutralized isopropyl alcohol: To a suitable quantity of isopropyl alcohol add 2–3 drops of bromothymol blue and just sufficient 0.10 N sodium hydroxide dropwise to produce a faint blue color. [Note— Prepare Neutralized isopropyl alcohol just prior to use.]
Sample solution: 32.0 g of Triethyl Citrate in 30 mL of Neutralized isopropyl alcohol
Analysis: Add bromothymol blue. Titrate with 0.10 N sodium hydroxide to a faint blue endpoint.
Acceptance criteria: NMT 1.0 mL of 0.10 N sodium hydroxide is required.
Water Determination: NMT 0.25%
Packaging and Storage: Preserve in tight containers.


Specifications of Triethyl Citrate BP Ph Eur Grade:
C12H20O7 --- 276.3 --- CAS 77-93-0
Action and use: Excipient.

DEFINITION
Triethyl 2-hydroxypropane-1,2,3-tricarboxylate.
Content: 98.5 per cent to 101.0 per cent (anhydrous substance).

CHARACTERS
Appearance: Clear, viscous, colourless or almost colourless, hygroscopic liquid.
Solubility: Soluble in water, miscible with ethanol (96 per cent), slightly soluble in fatty oils.

IDENTIFICATION
First identification: A, B
Second identification: A, C, D
A. Refractive index.
B. Infrared absorption spectrophotometry.
Comparison Ph. Eur. reference spectrum of triethyl citrate.
C. It gives the reaction of esters.
D. To 0.5 mL add 5 mL of ethanol (96 per cent) and 4 mL of dilute sodium hydroxide solution. Boil under reflux for about 10 min. 2 mL of the solution gives the reaction of citrates.

TESTS
Appearance: The substance to be examined is clear and not more intensely coloured than reference solution
Acidity: Dilute 10 g with 10 mL of previously neutralised ethanol (96 per cent), add 0.5 mL of bromothymol blue solution. Not more than 0.3 mL of 0.1 M sodium hydroxide is required to change the colour of the indicator to blue.
Refractive index: 1.440 to 1.446.
Related substances: To pass the test by Gas chromatography.
Limits:
-any impurity: for each impurity, maximum 0.2 per cent;
-total: maximum 0.5 per cent;
-disregard limit: 0.04 per cent.
Water: Maximum 0.25 per cent, determined on 1.000 g.
Sulfated ash: Maximum 0.1 per cent, determined on 1.0 g.

STORAGE
In an airtight container.

IMPURITIES
A. triethyl propene-1,2,3-tricarboxylate (triethyl aconitate).


Specifications of Triethyl Citrate FCC Food Grade:
Ethyl Citrate
C12H20O7 Formula weight 276.29
INS: 1519 CAS 77-93-0

DESCRIPTION
Triethyl Citrate occurs as a practically colorless, oily liquid. It is slightly soluble in water but is miscible with alcohol and with ether.
Function: Solvent.

REQUIREMENTS
Assay: Not less than 99.0% and not more than 100.5% of C12H20O7, calculated on the anhydrous basis.
Acidity: (as citric acid) Not more than 0.02%.
Lead: Not more than 2 mg/kg.
Refractive Index: Between 1.439 and 1.443 at 25C; or between 1.440 and 1.444 at 20C.
Specific Gravity: Between 1.135 and 1.139 at 25C.
Water: Not more than 0.25%.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

We manufacture and supply as under:

Ammonium Citrate Dibasic

Ammonium Citrate Tribasic

Bismuth Ammonium Citrate

Bismuth Citrate

Boron Citrate

Calcium Citrate

Calcium Citrate Malate

Copper Citrate

Disodium Hydrogen Citrate

Ferric Ammonium Citrate

Ferrous Calcium Citrate

Ferrous Citrate

Ferric Citrate

Iron Choline Citrate

Lithium Citrate

Magnesium Citrate

Magnesium Citrate Malate

Manganese Citrate

Monosodium Citrate

Nickel Citrate

Potassium Citrate

Sodium Citrate

Strontium Citrate

Tributyl Citrate

Tricholine Citrate

Triethyl Citrate

Zinc Citrate.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

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Last 18 May, 2024

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Triethyl Citrate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
22-Nov-20

1. PRODUCT DESCRIPTION

Product Name & Other Names: Triethyl Citrate.
CAS Number: 77-93-0
EINECS EC Number: 201-070-7
Molecular Weight: 276.28
Molecular Formula: C12H20O7 or HOC(COOC2H5)(CH2COOC2H5)2
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per letterhead.

2. HAZARD IDENTIFICATION

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling as per GHS & Regulation EC 1272/2008 (CLP) & GHS

GHS Label Elements
None

Signal Words: None

Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation, if exposed in large quantity.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Product Name & Other Names: Triethyl Citrate.
CAS Number: 77-93-0
EINECS EC Number: 201-070-7

4. FIRST AID MEASURES

Always get medical attention after the first aid is over.

Emergency and First Aid Procedures:
Eyes - Flush with water for at least 15 minutes, raising and lowering eyelids occasionally. Get medical attention if irritation persists.
Skin - Thoroughly wash exposed area for at least 15 minutes. Remove contaminated clothing. Launder contaminated clothing before reuse. Get medical attention if irritation persists.
Ingestion - If swallowed, if conscious, give plenty of water. Immediately call a physician. Never give anything by mouth to an unconscious person.
Inhalation - Remove to fresh air. Give oxygen if breathing is difficult; give artificial respiration if breathing has stopped. Get medical attention.

5. FIREFIGHTING PROCEDURES

Extinguisher Media: Use media suitable to extinguish surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Flammable Limits in Air % by Volume: N/A
Special hazards arising from the substance or mixture: Fumes, Carbon oxides.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6. SPILL OR LEAK PROCEDURES

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container.

7. SPECIAL PRECAUTIONS

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store cold to warm conditions, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing.

8. SPECIAL PROTECTION INFORMATION

Airborne Exposure Limits: None established. Ensure adequate ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants low.
Respiratory Protection (Specify Type):
None needed under normal conditions of use with adequate ventilation. NIOSH approved equipment should be worn if PELs are exceeded.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. PHYSICAL DATA

Appearance and Odor: Clear colorless or almost colorless oily liquid.
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.14
Melting point/freezing point: -55C literature.
Initial boiling point and boiling range: 294C literature.
Flash point: 151C literature.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Soluble in water, miscible with ethanol (96 per cent).
Viscosity: Not available.
Molecular Weight: 276.28
Molecular Formula: C12H20O7 or HOC(COOC2H5)(CH2COOC2H5)2

10. REACTIVITY DATA

Stability: It is stable
Conditions to Avoid: Heat, humidity, Dust generation.
Incompatibility (Materials to Avoid): Strong oxidizing.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, nitrogen oxides.
Hazardous Polymerization: Will not occur

11. TOXICITY DATA

Acute toxicity:
LD50 Oral - Rat - 5.900 mg/kg.
LD50 Dermal - Rabbit - > 5.000 mg/kg.
Carcinogenicity: This product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, NTP, ACGIH & OSHA.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. ECOLOGICAL DATA

Toxicity to fish: No information available.
Toxicity to daphnia and other aquatic invertebrates: Immobilization EC50 - Daphnia magna (Water flea) - > 100 mg/l  - 48 h.
Toxicity: Avoid release into the environment.
Persistence and Degradability: Soluble in water Persistence is unlikely based on information available.
Mobility: Will likely be mobile in the environment due to its water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

13. DISPOSAL INFORMATION

Waste Disposal Methods: Dispose in accordance with all applicable Federal, State and Local regulations.

14. TRANSPORT INFORMATION

DOT USA, TDG Canada & ADR/RID Europe: Not regulated.
IMDG/IMO: Not regulated.

IATA: Not regulated.

15. REGULATORY INFORMATION

USA:
Section 355 (extremely hazardous substances)
: Substance is not listed.
Section 313 (Specific toxic chemical listings): Substance is not listed.
SARA 311/312 Hazard Categories: None. See section 2 for more information
Proposition 65:
Chemicals known to cause cancer: Substance is not listed.
Chemicals known to cause reproductive toxicity for females: Substance is not listed.
Chemicals known to cause reproductive toxicity for males: Substance is not listed.
Chemicals known to cause developmental toxicity: Substance is not listed.

16. ADDITIONAL INFORMATION

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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