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Lithium Citrate BP USP Grade Manufacturers, SDS GHS MSDS Sheet
Lithium Citrate: CAS Number: 6080-58-6 (919-16-4), EINECS EC Number: 213-045-8, Molecular Formula: LiO2CCH2C(OH)(CO2Li)CH2CO2Li, Molecular Weight: 209.92, HS Code ---**
For SDS MSDS Sheet Click
SDS MSDS Sheet of Lithium Citrate Manufacturers
Pure BP USP Grade
Lithium Citrate BP
C6H5Li3O7,4H2O --- 282.0 --- 6080-58-6
Trilithium 2-hydroxypropane-1,2,3-tricarboxylate tetrahydrate.
Content: 98.0 per cent to 102.0 per cent (anhydrous substance).
Appearance: White or almost white, fine crystalline powder.
Solubility: Freely soluble in water, slightly soluble in ethanol (96 per cent).
A. When moistened with hydrochloric acid, it gives a red colour to a non-luminous flame.
B. Dilute 3 ml of solution S (see Tests) to 10 ml with water. Add 3 ml of potassium ferriperiodate solution. A white or yellowish-white precipitate is formed.
C. To 1 ml of solution S add 4 ml of water. The solution gives the reaction of citrates.
Solution S: Dissolve 10.0 g in carbon dioxide-free water prepared from distilled water and dilute to 100 ml with the same solvent.
Appearance of solution: Solution S is clear and colourless.
Acidity or alkalinity: To 10 ml of solution S add 0.1 ml of phenolphthalein solution. Not more than 0.2 ml of 0.1 M hydrochloric acid or 0.1 M sodium hydroxide is required to change the colour of the indicator.
Readily carbonisable substances: To 0.20 g of the powdered substance to be examined add 10 ml of sulphuric acid and heat in a water-bath at 90 ± 1C for 60 min. Cool rapidly. The solution is not more intensely coloured than reference.
Chlorides: Maximum 100 ppm.
Oxalates: Maximum 300 ppm, calculated as anhydrous oxalate ion.
Sulphates: Maximum 500 ppm.
Heavy metals: Maximum 10 ppm.
Water: 24.0 per cent to 27.0 per cent, determined on 0.100 g.
ASSAY: Dissolve 80.0 mg in 50 ml of anhydrous acetic acid, heating to about 50C. Allow to cool. Titrate with 0.1 M perchloric acid, using 0.25 ml of naphtholbenzein solution as indicator, until the colour changes from yellow to green.
1 ml of 0.1 M perchloric acid is equivalent to 7.00 mg of C6H5Li3O7.
STORAGE: In an airtight container .
Lithium Citrate USPIdentification:
1,2,3-Propanetricarboxylic acid, 2-hydroxy-trilithium salt tetrahydrate.
Trilithium citrate tetrahydrate [6080-58-6].
Anhydrous 209.93 [919-16-4].
Lithium Citrate contains not less than 98.0 percent and not more than 102.0 percent of C6H5Li3O7, calculated on the anhydrous basis.
A: When moistened with hydrochloric acid, it imparts an intense crimson color to a nonluminous flame.
B: It responds to the test for Citrate.
pH: between 7.0 and 10.0, in a solution (1 in 20).
Water: Dry it at 150 for 3 hours: it loses between 24.0% and 28.0% of its weight.
Carbonate: Add about 0.5 g to 5 mL of 6 N acetic acid: not more than a slight effervescence is produced.
Heavy metals: the limit is 0.001%.
For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
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Last 14 August, 2017
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Lithium Citrate (Hydrate) SDS MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Synonyms: Citric salt of lithium
CAS No.: 6080-58-6
EINECS EC Number: 213-045-8
Molecular Weight: 209.92
Chemical Formula: LiO2CCH2C(OH)(CO2Li)CH2CO2Li (for Anhydrous)
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Serious eye damage/eye irritation Category 2A
Labeling Regulation GHS & EC 1272/2008 (CLP) & GHS
GHS Label Elements
Signal Words: Warning
H319 Causes serious eye irritation.
Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash … thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
Classification according to EU Directives 67/548/EEC or 1999/45/EC: Hazard Symbols: Xi
Risk Phrases: 36
For the full text of the H-Statements & R-phrases mentioned in this Section, see Section 16.
3. Composition/Information on Ingredients
Ingredient: Lithium Citrate (or hydrates)
CAS No.: 6080-58-6
EINECS EC Number: 213-045-8
4. First Aid Measures
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Call a physician.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician.
Eye Contact: Wash eyes with plenty of water for at least 15 minutes. Call a physician.
5. Fire Fighting Measures
Fire: It is not considered to be a fire hazard.
Explosion: It is not considered to be an explosion hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
6. Accidental Release Measures
Ventilate area of leak or spill. Wear appropriate personal protective equipment.
Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. Do not let product enter drains.
7. Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Separate from incompatibilities. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance: Lithium Citrate is white crystals.
Odor: No data available.
Solubility: No data available.
Specific Gravity: No data available.
pH: No data available.
% Volatile by volume @ 21C (70F): 0
Boiling Point: No data available.
Melting Point: 112C
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Oxides of the lithium and carbon with fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers, reducing agents and bases.
Conditions to Avoid: Incompatibles.
11. Toxicological Information
LD50 Oral - Rat No data available.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
12. Ecological Information
Toxicity to fish: No data available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
14. Transport Information
DOT (USA) & ADT/RID: Not dangerous goods
IMDG & IATA: Not dangerous goods
15. Regulatory Information
Section 302 (RQ): None of the chemicals in this material have an RQ.
Section 313: No chemicals are reportable under Section 313.
SARA 311/312: Acute health hazard.
Canadian WHMIS Classifications: Not controlled.
16. Other Information
Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.