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Calcium Sulfate Calcium Sulphate Dihydrate SDS MSDS Sheet
Calcium Sulphate BP Grade
Calcium Sulfate USP Grade
Calcium Sulfate ACS AR Analytical Reagent Grade
Calcium Sulfate FCC; Calcium Sulphate Food Grade
MSDS Sheet of Calcium Sulfate Sulphate Dihydrate Manufacturers
MSDS Sheet of Calcium Sulfate Sulphate Hemihydrate Anhydrous Manufacturers
Calcium Sulfate Sulphate USP ACS BP IP Analytical Reagent FCC Food grade Manufacturers Specifications
Calcium Sulfate Dihydrate SDS MSDS Sheet, Material Safety Data Sheet
Section 1: Chemical Product and Company Identification
Product Name: Calcium sulfate dihydrate
Synonym: Calcium (II) sulfate, dihydrate; precipitated calcium sulfate; Sulfuric acid, calcium (2+) salt, dihydrate
Chemical Name: Calcium Sulfate, Dihydrate
Chemical Formula: CaSO4.2H2O
CAS #: 10101-41-4 for dihydrate (10034-76-1 for hemihydrate or 7778-18-9 for anhydrous)
EINECS EC: 231-900-3
Relevant Uses: Industrial use only.
Supplier: As per letterhead.
Section 2: Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Word: None
Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
OSHA Hazards: No known OSHA hazards.
Section 3: Composition and Information on Ingredients
Name: Calcium sulfate dihydrate or Calcium sulphate anhydrous
CAS #: 10101-41-4 for hemihydrate (10034-76-1 for hemihydrate or 7778-18-9 for anhydrous)
EINECS EC: 231-900-3
% by Weight: 100
Section 4: First Aid Measures
Always seek medical advice after the first aid treatment.
FIRST AID: CALL A PHYSICIAN. SKIN: Wash exposed area with soap and water.
EYES: Wash eyes with plenty of water for at least 15 minutes, lifting lids occasionally. Seek Medical Aid.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
INGESTION: If swallowed, induce vomiting immediately after giving two glasses of water. Never give anything by mouth to an unconscious person.
Section 5: Fire and Explosion Data
Flammability of the Product: Neon-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
Slightly explosive in presence of heat.
Fire Fighting Media and Instructions: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Remarks on Fire Hazards: Calcium Sulphate mixed with phosphorus will ignite at high temperatures.
When primed at high temperature with potassium nitrate-calcium silicide mixture, calcium sulfate mixed with excess red phosphorus will burn.
When heated to decomposition it emits toxic fumes of oxides of sulfur and calcium.
Special Remarks on Explosion Hazards: Contact with diazomethane causes an exothermic reaction which may lead to detonation.
Many metal oxo-compounds (nitrates, oxides, and particularly sulfates) and sulfides are reduced violently or explosively (undergo a thermite reaction) on heating an intimate mixture with aluminum powder to a suitably high temperature to initiate the reaction. A violent or explosive reaction can occur upon heating when calcium sulfate is mixed with aluminum powder.
Containers of Calcium sulfate or Calcium Sulphate may explode when heated.
Section 6: Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of Calcium sulfate according to legal requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
Section 7: Handling and Storage
Precautions: Do not breathe dust of Calcium sulfate. Keep away from incompatibles such as oxidizing agents, acids.
Storage: Keep container of Calcium Sulphate tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic.
Section 8: Exposure Controls/Personal Protection
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
TWA: 15 (mg/m3) from OSHA (PEL) [United States] Inhalation Total.
TWA: 5 (mg/m3) from OSHA (PEL) [United States] Inhalation Respirable.
TWA: 10 (mg/m3) from ACGIH (TLV) [United States]
TWA: 10 (mg/m3) [United Kingdom (UK)] Inhalation Total.
TWA: 4 (mg/m3) [United Kingdom (UK)] Inhalation Respirable.3
Consult local authorities for acceptable exposure limits.
Section 9: Physical and Chemical Properties
Physical state and appearance: Calcium Sulphate is solid. (hygroscopic crystals; lumps; powder)
Taste: Not available.
Molecular Weight: 172.17 g/mole
Color: Colorless. White.
pH (1% soln/water): Not available.
Boiling Point: Not available.
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: 2.32 (Water = 1)
Very slightly soluble in cold water.
Solubility in water: 0.21 g/100 g water @ 20 deg. C; 0.24 g/100 g water @ 25 deg. C.
Section 10: Stability and Reactivity Data
Stability: Calcium sulfate is stable.
Conditions of Instability: Incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents, acids.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Hygroscopic; keep container tightly closed.
Loses 1/2 water at 128 C and 2 waters at 163 C.
Incompatible with Diazomethane, aluminum, magnesium, phosphorous.
The dihydrate form cannot set with water. Hygroscopic; keep container tightly closed.
Polymerization: Will not occur.
Section 11: Toxicological Information
Toxicity to Animals:
LD50 (Oral) Rat 3,920 mg/kg
Special Remarks on Toxicity to Animals: The probable lethal oral human dose has been estimated to be 0.5 to 5 g/kg
Section 12: Ecological Information
Calcium sulphate, dihydrate EC50 >79 mg/l Algae 72 hours
EC50 >79 mg/l Daphnia 48 hours
EC50 >790 mg/l Micro-organism 3 hours
Acute LC50 >1970 mg/l Fish 96 hours
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
DOT (US): Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
Section 15: Other Regulatory Information
OSHA Hazards: No known OSHA hazards
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: No SARA Hazards
Massachusetts Right To Know Components: Calcium sulfate, CAS-No. 10101-41-4
Pennsylvania Right To Know Components: Calcium sulfate, CAS-No. 10101-41-4
New Jersey Right To Know Components: Calcium sulfate, CAS-No. 10101-41-4
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Illinois toxic substances disclosure to employee act: Calcium sulfate dihydrate
Canada WHMIS: Not controlled under WHMIS (Canada).
EINECS EC: 231-900-3
Section 16 - Additional Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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Last 21 August, 2017
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