Sodium Chlorite Solution Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Sodium Chlorite Solution, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer.

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Export to USA UAE Europe Africa Tanzania Kenya Egypt Turkey Jumbo Packing; Exports to USA UAE Europe Africa Tanzania Kenya Uganda Egypt Turkey Brazil Chile Argentina Dubai etc. Packing Palletized and Shrink Wrapped; 25kg or 50kg or 55 lbs HDPE laminated bags with an extra HMHDP liner Drum Packing for better transportation Drum Packing & Palletized Liquid Chemical Export Import Air Freighting

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Sodium Chlorite Solution and Powder.

In the USA, UAE, Iran Iraq, Kuwait, Saudi Arabia and other oil producing areas, several hundred chemical compounds are used in hydraulic fracturing also called fracking, fracing or frac. In some areas like UK only 'Non-Hazardous' chemicals are permitted for fracturing fluids by the Environment Agency. All chemicals have to be declared publicly and increasingly, food additive based chemicals are available to allow fracking to take place safely.

Mubychem is an internationally preferred source for Stimulation Chemicals and Hydraulic Fracturing Chemicals. We serve various oil and shale gas producing countries like USA UAE, Kuwait, Iran, Iraq, Saudi Arabia, UK, Europe India etc. We are never too far from your well-site with multiple 24/7 company owned or rented warehouses in the India, USA and across the globe. With customers in several countries, we sell almost all the fracturing chemicals.

FRB-1 Liquid FR Breaker
Sodium Chlorite 7.5%
CAS No: 7758-19-2
Molecular Formula: NaClO2
Molecular Weight: 90.44

Specifications
Appearance: Clear Liquid
Assay as NaClO2: 7.5% min
Sodium Chlorate: 0.25% max.
Sodium Chloride: 1% max
Heavy Metals: 5 ppm max
FRB-1 is used as an oxidative breaker for Friction Reducers to clean residual polymer from proppant pack.

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

Exporters to USA Canada UAE Europe South Africa Tanzania Kenya Uganda Egypt Nigeria Turkey Mexico Brazil Argentina Chile Dubai etc.

Global or International Suppliers, Exporters, Importers, Manufacturers

I shall pass through this world, but once. If therefore, there is any good that I can do, or if there is any favor that I can show to a fellow human being, let me do it now. Let me not defer or neglect it. For I shall not tread this way again

Sodium Chlorite 2% to 15% Solution SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet17-Nov-20

Product Name/Synonyms: Stabilized chlorine dioxide solution.
CAS No.: 7758-19-2
Molecular Weight: 90.44
Chemical Formula: NaClO2 in water
Intended Use: Oil & Gas Wells fracturing and Industrial Manufacturing.
Recommended uses and uses advised against (if any): Precursor for generation of chlorine dioxide gas used in water treatment.
SUPPLIER: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Corrosive to Metals Category 1, H290
Health, Acute toxicity, 3 Oral, H302
Health, Acute toxicity, 3 Dermal, H311
Health, Serious eye damage/eye irritation Category 1, H318
Health, Specific target organ toxicity - Single exposure, Category 2, H373
Environmental, Hazards to the aquatic environment - acute hazard, 1, H400

Hazard Statements:
H290: May be corrosive to metals.
H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H318: Causes serious eye damage.
H373: May cause damage to organs through prolonged or repeated exposure.
H400: Very toxic to aquatic life.
EUH032: Contact with acids liberates very toxic gas.
This is a dilute product. However, it may be handled carefully. It may intensify fire: oxidizer.

Precautionary Statements
P234: Keep only in original container.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get Medical advice/attention if you feel unwell.
P330: If swallowed, rinse mouth.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P361: Call a POISON CENTER or doctor/physician if you feel unwell.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P363 : Wash contaminated clothing before reuse.
P390: Absorb spillage to prevent material damage.
P391: Collect spillage.
P404: Store in a closed container.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn Harmful
Xi Irritant
C Corrosive
N Dangerous for the environment.
Risk Phrases:
R8- Contact with combustible material may cause fire.
R22 Harmful if swallowed.
R24 Toxic in contact with skin.
R31 Contact with acids liberates toxic gas.
R41 Risk of serious damage to eyes.
R48 Danger of serious damage to health by prolonged exposure.
R50 Very toxic to aquatic organisms.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used. Wash clothing & shoes before reuse. Get medical attention.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.

Fire: Sodium Chlorite solution is not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents. Heating will release chlorine dioxide or hydrochloric acid.
Explosion: An explosion hazard when mixed with finely powdered organic matter, metal powder or reducing agents.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Sealed containers may rupture when heated.
Hazardous Combustible Products: If product is dry, heat or friction can easily ignite this product. Do not allow this product to dry on cloth or clothing. Oxidation can cause a fire hazard. Hydrogen chloride and Chlorine dioxide will evolve.

Personal precautions, protective equipment, environmental precautions and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material. Keep away from drains, surface and groundwater and soil.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Contain spilled material. It is an oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Do not touch spilled material. Prevent entry into sewers. Eliminate all ignition sources.
Evacuation procedures must be placed into effect. Evacuate all non-essential personnel. Hazardous concentrations in air may be found in local spill area and immediately downwind. Utilize emergency response personal protective equipment prior to the start of any response. This product may represent an explosion hazard, in the form of explosive chlorine dioxide gas if it contacts acid or chlorine. Remove all sources of ignition, such as flames, hot glowing surfaces, or electric arcs. Stop source of spill as soon as possible and notify appropriate personnel. Notify all downstream water users of possible contamination. Spill materials may be absorbed using clay, soil, or non-flammable commercial absorbents. Flush spill area with large amounts of water. If allowed to dry, dried material can ignite in contact with combustible materials so do not allow spills to dry up.
Deactivating Materials: Small spills that have been diluted with water can be neutralized with sodium sulfite or sodium bisulfite solutions.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices with proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces. Containers of this material may be hazardous when empty since they retain product residues.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like reducing agents, organic material and powdered metals, heat, sulfur containing compounds, acids. Isolate from heat and sun. Separate from combustibles, organic or other readily oxidizable materials. Avoid storage on wood floors. Containers of this material may be hazardous when empty since they retain product residues (dust, solids).

Airborne Exposure Limits: Not established. Use under good ventilation only.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Clear to yellow solution.
Odor: Chlorine odor.
Odor threshold: Not available.
pH: 7 to 13.
Relative density: 1.05 to 1.23.
Boiling Point: 106C
Melting Point: 0C
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Viscosity: Not available.
Molecular Weight: 90.44 for dry material.
Chemical Formula: NaClO2 in water.

Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Decomposed by heat, sunlight, and organic substances. Burning may produce chlorine and its oxide and hydrochloric acid.
Hazardous Polymerization: Will not occur.
Incompatibilities: Reducing agents, organic material and powdered metals, heat, sulfur containing compounds, acids.
Conditions to Avoid: Heat, combustible materials and incompatibles.

Oral rat LD50: 165 mg/kg on 100% basis.
Carcinogenic Effects: Sodium chlorite is not listed by NTP, IARC, OSHA, or any other authority as a carcinogen.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Fish Toxicity: TL50 (48 hours, Daphnia Magna): 0.29mg/L
Biodegradability: Sodium chlorite in water will eventually degrade to sodium chloride. Sodium chlorite in contact with acidic soil could produce chlorine dioxide.
Environmental Toxicity: This product is toxic to fish and aquatic organisms.

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.

DOT USA, TDG Canada & ADR/RID Europe
Proper Shipping Name: CHLORITE SOLUTION
UN/NA: UN 1908; Hazard Class: 8; Packing Group: II
International Water IMO/IMDG & AIR IATA
Proper Shipping Name: CHLORITE SOLUTION
UN/NA: UN 1908; Hazard Class: 8; Packing Group: II

SARA Section 302 Extremely Hazardous Substances: Does not have a TPQ.
Section 313: No chemicals are reportable under Section 313.
California Prop 65: No Significant Risk Level: None of the chemicals in this product are listed.

European Labeling in Accordance with EC Directives:
H290: May be corrosive to metals.
H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H318: Causes serious eye damage.
H373: May cause damage to organs through prolonged or repeated exposure.
H400: Very toxic to aquatic life.
EUH032: Contact with acids liberates very toxic gas.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Sodium Chlorite 16% to 31% Solution SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet17-Nov-20

Product/Synonyms: Sodium Chlorite or Stabilized chlorine dioxide in water
CAS No.: 7758-19-2 for dry material.
Molecular Weight: 90.44 for dry material.
Chemical Formula: NaClO2 for dry material.
Intended Use: Oil & Gas Wells fracturing and Industrial Manufacturing.
Recommended uses and uses advised against (if any): Precursor for generation of chlorine dioxide gas used in water treatment.
SUPPLIER: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Hazard Statements:
H290: May be corrosive to metals.
H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H318: Causes serious eye damage.
H373: May cause damage to organs through prolonged or repeated exposure.
H400: Very toxic to aquatic life.
EUH032: Contact with acids liberates very toxic gas.
This is a dilute product. However, it must be handled carefully. It may intensify fire, oxidizer.

Fire: Sodium Chlorite solution is not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents. Heating will release chlorine dioxide or hydrochloric acid.
Explosion: An explosion hazard when mixed with finely powdered organic matter, metal powder or reducing agents.
Fire Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Sealed containers may rupture when heated.
Hazardous Combustible Products: If product dry, heat or friction can easily ignite this product. Do not allow this product to dry on cloth or clothing. Oxidation can cause a fire hazard. Hydrogen chloride and Chlorine dioxide will evolve.

Airborne Exposure Limits: - Not established. Maintain Shower, Eye Wash and use under good ventilation only.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice.

Appearance: Clear to yellow solution.
Odor: Chlorine odor.
Odor threshold: Not available.
pH: 7 to 13.
Relative density: 1.05 to 1.23
Boiling Point: 106C
Melting Point: 0C
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Viscosity: Not available.
Molecular Weight: 90.44 for dry material.
Chemical Formula: NaClO2 in water.

Oral rat LD50: 165 mg/kg on 100% basis.
Carcinogenic Effects: Not listed by NTP, IARC, OSHA, or any other authority as a carcinogen.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Environmental Fate: Fish Toxicity TL50 (48 hours, Daphnia Magna): 0.29mg/L
Biodegradability: Sodium chlorite in water will eventually degrade to sodium chloride. Sodium chlorite in contact with acidic soil could produce chlorine dioxide.
Environmental Toxicity: This product is toxic to fish and aquatic organisms. Do not discharge effluent containing this product into bodies of water unless in accordance with law.

Chemical Name and CAS Number	% Range
Sodium Chlorite --- 7758-19-2	2%-15%
Sodium Chloride --- 7647-14-5	0%-5%
Sodium Chlorate --- 7775-09-9	0%-3%
Water --- 7732-18-5	77%-98%

Shale Gas Hydraulic Fracturing Chemicals
Acetic Acid Solution	Ammonium Persulfate or Persulphate
Acid Viscosifier	Acid Emulsifier
ATMP Phosphonate, Amino tris (methylene phosphonic acid)	Ammonium Bifluoride
Barium Sulfate Remover	BHMT or BHMTPMPA Biocide Solution
Boron & Zirconium based Guar Cross Linker	BME Iron Reducer or Dissolver
Calcium Chloride Anhydrous & Solution	Cement Defoamer
Citric Acid Solution	Clay Stabilizer
Corrosion Inhibitors	DETA Phosphonate or DTPMP Phosphonate
Didecyl Dimethyl Ammonium Chloride Solution	Diverting Agent
Encapsulated Citric Acid	Encapsulated Gel Breaker
Fe46 Liquid Iron Control Blend	Friction Reducer
Flow Back Aid, Water Recovery Surfactant	Foam or Finofoam 810
Foam 418 Heavy Crude Foamer	Gel Sweep
Glycerin Solution	Glutaraldehyde Solution
HP HT Lube	Hydroxy ethylidene diphosphonic acid, HEDP phosphonate
Hydrogen Sulfide Scavenger	Potassium Chloride
KI (Stabilised) & Initiator	KCl Substitute or Potassium Chloride Substitute
Non Emulsifier	Paraffin Dispersant
Potassium Hydroxy Ethylidene,1-Diphosphonic Acid, HEDP-Kx	Phthalic Acid, EDTA, BPA based Diverting Agents
Scale Inhibitor Chemicals	Sodium Chlorite Solution
Sodium Glutaraldehyde Bisulfite Bisulphite	Extended Release Solids - Scale Paraffin Asphaltene Inhibitor
Tetrakis Hydroxymethyl Phosphonium Sulfate THPS	Xanthan Gum Slurry
Zinc Chloride

Chemical Name & CAS Number	% Range
Sodium Chlorite -- 7758-19-2 EINECS EC code number: 231-836-6	2%-15%
Sodium Chloride - 7647-14-5	0%-5%
Sodium Chlorate - 7775-09-9	0%-3%
Water --------------- 7732-18-5	77%-98%

Chemical Name & CAS Number	% Range
Sodium Chlorite -- 7758-19-2 EINECS EC code number: 231-836-6	2%-31%
Sodium Chloride - 7647-14-5	0%-5%
Sodium Chlorate - 7775-09-9	0%-3%
Water --------------- 7732-18-5	77%-98%