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Calcium Acetate USP BP Pure AR LR ACS Analytical Reagent FCC Food Grade Manufacturers, SDS MSDS Sheet

Calcium Acetate CAS Number 62-54-4 anhydrous & 5743-26-0 monohydrate, EINECS EC Number 200-540-9, HS Code ---**; Molecular Weight 158.17 anhydrous & 176.19 monohydrate, Molecular Formula: C4H6CaO4 anhydrous & C4H6CaO4.H2O monohydrate

For MSDS Sheet Click
MSDS Sheet of Calcium Acetate Manufacturers

Calcium Acetate
Commercial USP BP IP Pure LR AR ACS Analytical Reagent Grade
Calcium Acetate

The chemical compound calcium acetate is the salt of  calcium and acetic acid. It has the formula Ca(C2H3O2)2. Its standard name is calcium acetate, while calcium ethanoate is the systematic IUPAC name. An older name is acetate of lime. The anhydrous form is very hygroscopic; therefore the monohydrate (Ca(CH3COO)2•H2O, CAS [5743-26-0]) is the common form. It is used as a food additive, as a stabilizer, buffer and sequestrant, mainly in candy products. Calcium Acetate, (CH3COO)2Ca is used in food industry as a growth inhibitor for certain bacteria. It is used in bread and other baked foods to prevent rope formation and to extend the shelf life.

Specifications of Commercial Pure Calcium Acetate:
Calcium Acetate is a fine, white, bulky powder, freely soluble in water and slightly soluble in alcohol.
Assay: Not less than 99.0% and not more than 100.5% of Ca(C2H3O2)2, calculated on the anhydrous basis.
Chloride: Not more than 0.05%.
Fluoride: Not more than 0.005%.
Lead: Not more than 2 mg/kg.
Sulfate: Not more than 0.1%.

Calcium Acetate BP, Ph Eur Grade

C4H6CaO4 --- 158.2 --- 62-54-4

Calcium diacetate.
Content: 98.0 per cent to 102.0 per cent (anhydrous substance).

Appearance: White or almost white, hygroscopic powder.
Solubility: Freely soluble in water, slightly soluble in ethanol (96 per cent).

A. It gives reaction of calcium.
B. It gives reaction of acetates.

pH: 7.2 to 8.2.
Readily oxidisable substances: Dissolve 2.0 g in boiling water and dilute to 100 ml with boiling water, add a few glass beads, 6 ml of 5 M sulphuric acid and 0.3 ml of 0.02 M potassium permanganate , mix, boil gently for 5 min and allow the precipitate to settle. The pink colour in the supernatant is not completely discharged.
Chlorides: Maximum 330 ppm.
Nitrates: Dissolve 1.0 g in water and dilute to 10 ml with the same solvent. Add 5 mg of sodium chloride, 0.05 ml of indigo carmine solution and add with stirring, 10 ml of nitrogen-free
sulphuric acid. The blue colour remains for at least 10 min.
Sulphates: Maximum 600 ppm.
Aluminium: Maximum 1 ppm.
Arsenic: Maximum 2 ppm.
Barium: Maximum 50.0 ppm.
Magnesium: Maximum 5.00 × 102 ppm.
Potassium: Maximum 0.10 per cent.
Sodium: Maximum 0.50 per cent.
Strontium: Maximum 5.00 × 102 ppm.
Heavy metals: Maximum 20 ppm.
Water: Maximum 7.0 per cent.

Calcium Acetate USP Grade

C4H6CaO4 158.17
Acetic acid, calcium salt.

Calcium Acetate contains not less than 99.0 percent and not more than 100.5 percent of C4H6CaO4, calculated on the anhydrous basis.

Identification: A solution (1 in 20) responds to the tests for Calcium and for Acetate.
pH: 6.3 to 9.6, in a solution (1 in 20).
Water: not more than 7.0%, determined in a 0.7-g specimen.
Limit of fluoride:  the limit is 0.005%.
Arsenic: 3 ppm.
Heavy metals: the limit is 0.0025%.
Lead: 0.001%.
Chloride: 0.05%.
Sulfate: 0.06%.
Limit of nitrate: To pass the test.
Limit of aluminum (where it is labeled as intended for parenteral use or for use in hemodialysis or peritoneal dialysis)—
Barium (where it is labeled as intended for use in hemodialysis or peritoneal dialysis): the limit is 0.05%.
Limit of potassium (where it is labeled as intended for use in hemodialysis or peritoneal dialysis): the limit is 0.05%.
Limit of sodium (where it is labeled as intended for use in hemodialysis or peritoneal dialysis): the limit is 0.5%.
Limit of strontium (where it is labeled as intended for use in hemodialysis or peritoneal dialysis): the limit is 0.05%.
Readily oxidizable substances: Dissolve 2.0 g of it in 100 mL of boiling water, add a few glass beads, 6 mL of 10 N sulfuric acid, and 0.3 mL of 1 N potassium permanganate, mix, boil gently for 5 minutes, and allow the precipitate to settle: the pink color in the supernatant is not completely discharged.

Calcium Acetate FCC Food Grade
Ca(C2H3O2)2 Formula wt 158.17
INS: 263 CAS: [62-54-4]

Calcium Acetate occurs as a fine, white, bulky powder. It is freely soluble in water and slightly soluble in alcohol.

Function: Buffer; stabilizer; firming agent.

Identification: A 1:10 aqueous solution gives positive tests for Calcium and for Acetate.
Assay: Not less than 99.0% and not more than 100.5% of Ca(C2H3O2)2, calculated on the anhydrous basis.
Chloride: Not more than 0.05%.
Fluoride: Not more than 0.005%.
Lead: Not more than 2 mg/kg.
Sulfate: Not more than 0.1%.
Water: Not more than 7.0%.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.


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Calcium Acetate SDS MSDS Sheet, Material Safety Data Sheet

Section 1: Chemical Product and Company Identification

Product Name: Calcium Acetate
Calcium diacetate, Acetic acid, calcium salt.
CAS Number: 62-54-4 anhydrous & 5743-26-0 monohydrate
Molecular Weight: 158.17 anhydrous & 176.19 monohydrate
EINECS EC Number: 200-540-9
Chemical Formula: C4H6CaO4·xH2O
Intended use: Laboratory Chemicals and Industrial Manufacturing Use.
Supplier: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements

Signal Word: None

Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

OSHA Hazards: No known OSHA hazards.

Section 3: Composition and Information on Ingredients

Product Name: Calcium Acetate
CAS Number
: 62-54-4 anhydrous & 5743-26-0 monohydrate
Molecular Weight: 158.17 anhydrous & 176.19 monohydrate
EINECS EC Number: 200-540-9

Section 4: First Aid Measures

Always seek medical advice after the first aid treatment.

Skin: Wash exposed area with soap and water.
Eyes: Wash eyes with plenty of water for at least 15 minutes, lifting lids occasionally. Seek Medical Aid.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Ingestion: If swallowed, induce vomiting immediately after giving two glasses of water. Never give anything by mouth to an unconscious person.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.
Products of Combustion: Oxides of carbon and calcium.
Fire Fighting Media and Instructions: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use the media as per surrounding area.

Section 6: Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of Calcium Acetate according to legal requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Do not let product enter drains. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions: Do not breathe dust of Calcium Acetate. Keep away from incompatibles such as oxidizing agents, acids.
Storage: Keep container of Calcium Acetate tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic.

Section 8: Exposure Controls/Personal Protection

Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent Gloves. Handle in accordance with good industrial hygiene and safety practice.
Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.

Section 9: Physical and Chemical Properties

Physical state and appearance: Calcium Acetate is solid. (hygroscopic crystals; lumps; powder)
Odor: Odorless.
Molecular Weight: 158.17 anhydrous & 176.19 monohydrate
Chemical Formula: C4H6CaO4·xH2O
Color: White.
pH (1% soln/water): 6-9.
Boiling Point: Not available.
Melting Point: 160C.
Specific Gravity: 2.32 (Water = 1)
Solubility: Soluble in cold water. 100 g/l at 25 °C - soluble.

Section 10: Stability and Reactivity Data

Stability: Calcium Acetate is stable.
Conditions of Instability: Incompatible materials, Heat, moisture.
Incompatibility with various substances: Reactive with oxidizing agents, acids. Avoid Nitric acid, fluoride, potassium nitrate, strong oxidizers and diketene.
Special Remarks on Reactivity: Hygroscopic; keep container tightly closed.
Polymerization: Will not occur.

Section 11: Toxicological Information

Toxicity to Animals:
LD50 Oral - Rat - 2.700 mg/kg
LC50 Inhalation - Rat - 4 h - > 5,6 mg/l
LD50 Dermal - Rabbit - > 20.000 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.

Section 12: Ecological Information

Toxicity to fish: semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - > 1.000 mg/l - 96 h
Toxicity to daphnia and aquatic invertebrates: static test EC50 - Daphnia (water flea) - > 919 mg/l - 48 h
BOD5 and COD: Not available.
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Section 13: Disposal Considerations

Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT (US): Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
ADT/RID: Not dangerous goods

Section 15: Other Regulatory Information

TSCA Inventory Status
: All ingredients are listed on the TSCA inventory.
California Proposition 65: Not Listed
SARA 302: Not Listed
SARA 304: Not Listed
SARA 311: No SARA Hazards
SARA 312: No SARA Hazards
SARA 313: Not Listed

Canada WHMIS: Not Listed

EINECS EC Number: 200-540-9

Section 16 - Additional Information

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.