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Benzyl Benzoate BP USP NF FCC Food Grade Manufacturers, SDS GHS, MSDS Sheet
CAS No.120-51-4; EINECS No. 204-402-9; FEMA No. 2138
Molecular Weight 149.24, Molecular Formula C10H15N, HS Code ---**
For MSDS Sheet Click
MSDS Sheet of Benzyl Benzoate Manufacturers
BP & Commercial Pure
Benzyl Benzoate BP Grade
C14H12O2 -- 212.2 -- 120-51-4
Content: 99.0 per cent to 100.5 per cent.
Appearance: Colourless or almost colourless crystals or colourless or almost colourless, oily liquid.
Solubility: Practically insoluble in water, miscible with ethanol (96 per cent), with methylene chloride and with fatty and essential oils.
Second identificationıB, C.
A. Infrared absorption spectrophotometry (2.2.24). ComparisonıPh. Eur. reference spectrum of benzyl benzoate.
B. To 2 g add 25 ml of alcoholic potassium hydroxide solution and boil under a reflux condenser for 2 h. Remove the ethanol on a water-bath, add 50 ml of water and distill. Collect about 25 ml of distillate and use it for identification test C. Acidify the liquid remaining in the distillation flask with dilute hydrochloric acid. A white precipitate is formed that, when washed with water and dried in vacuum melts at 121 °C to 124 °C.
C. To the distillate obtained in identification test B add 2.5 g of potassium permanganate and 5 ml of dilute sodium hydroxide solution. Boil under a reflux condenser for 15 min, cool and filter. Acidify the filtrate with dilute hydrochloric acid. A white precipitate is formed that, when washed with water and dried in vacuum, melts at 121 °C to 124 °C.
Acidity: Dissolve 2.0 g in ethanol (96 per cent) R and dilute to 10 ml with the same solvent. Titrate with 0.1 M sodium hydroxide using phenolphthalein solution R as indicator. Not more than 0.2 ml is required to change the colour of the indicator to pink.
Relative density: 1.118 to 1.122.
Refractive index: 1.568 to 1.570.
Freezing point: Minimum 17.0 °C.
Sulphated ash: Maximum 0.1 per cent, determined on 1.0 g.
ASSAY: To 2.000 g add 50.0 ml of 0.5 M alcoholic potassium hydroxide and boil gently under a reflux condenser for 1 h. Titrate the hot solution with 0.5 M hydrochloric acid using 1 ml of phenolphthalein solution as indicator. Carry out a blank determination. 1 ml of 0.5 M alcoholic potassium hydroxide is equivalent to 106.1 mg of C14H12O2.
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Last : 11 April, 2017
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Benzyl Benzoate SDS GHS, MSDS Sheet, Material Safety Data Sheet
Commercial Name: Benzyl Benzoate
2. HAZARDS IDENTIFICATION
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, oral Category 4 H(302)
Hazardous to the aquatic environment, long-term hazard Category 2 (H411)
Labelling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
GHS Label Elements
Signal Words: Warning
H302: Harmful if swallowed.
H411: Toxic to aquatic life with long lasting effects.
Precautionary Statements: P330,
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P330: Rinse mouth.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P391: Collect spillage.
P501: Dispose of contents/container in accordance with local/national regulation.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xn Harmful R22
N Dangerous for the environment R51/53
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name: Benzyl Benzoate
CAS Number: 120-51-4
EINECS EC Number: 204-402-9, Xn Harmful, N Dangerous for the environment, R22 Harmful if swallowed, R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST-AID MEASURES
Always seek medical attention after first aid measures are provided.
Eye Contact: Rinse immediately with plenty of water for 10 minutes at least. Contact a physician if symptoms persist.
Skin Contact: Wash thoroughly with soap and water; flush with plenty of water. Take off spoilt clothes. Contact physician if symptoms persist.
Ingestion: Wash the mouth with water; seek medical advice immediately.
Inhalation: Remove from exposure site to fresh air and keep at rest. Obtain medical advice.
5. FIRE-FIGHTING MEASURES
Extinguishing Media Recommended: CO2, foam, dry chemicals.
Non Recommended: Do not use direct water jet on burning material.
Extinguishing Procedure: Closed containers may build up pressure at elevated temperatures. If possible, containers should be cooled with a water spray.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Use an individual protective equipment (waterproof boots, suitable protective clothing, safety glasses). Prevent any contact with hot surfaces. Do not approach facing the wind.
Environment Precautions: Keep Benzyl Benzoate away from drains, surface and groundwater and soil.
Method of Clean-up: Contain spilled material. Cover with an inert, non-combustible, inorganic absorbent material, or sweep up, and remove to an approved disposal container. Avoid open flames or other sources of ignition.
7. HANDLING AND STORAGE
Precautions in Handling: Apply according to good manufacturing and industrial hygiene practices with proper ventilation. Do not drink, eat or smoke while handling. Respect good personal hygiene.
Storage Conditions: Store in cool, dry and ventilated area away from heat sources and protected from light in tightly closed original container. Keep air contact to a minimum.
Fire Protection: Keep Benzyl Benzoate away from ignition sources and naked flame.
8. EXPOSURE CONTROL
Respiratory Protection: Avoid to breath directly on the product. Apply local ventilations when appropriate.
Ventilation: Ensure good ventilation of the work station.
Hand Protection: Avoid skin contact. Use chemical resistant gloves as needed.
Eye Protection: Use safety glasses.
Work Hygienic Practices: Wash hands with soap and water after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
Odor: Light, Balsamic, Almonds-like.
Color: Benzyl Benzoate is colorless.
Appearance: Oily Liquid / Crystalline Solid.
Flash Point (C): 148
Boiling Point (C): 323 – 325
Melting Point (C): 18 - 19
10. STABILITY AND REACTIVITY
Reactivity: It presents no significant reactivity hazards, by itself or in contact with water. Avoid contact with strong acids, alkali or oxidizing agents.
Decomposition: Carbon monoxide and unidentified organic compounds may be formed during combustion.
11. TOXICOLOGICAL INFORMATION
LD50 Oral - rabbit - 1,680 mg/kg
LD50 Dermal - rabbit - 4,000 mg/kg
LD50 Oral - rat - 1900 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
12. ECOLOGICAL INFORMATION
LC50 Fish 96 hour 2.3-3.9 mg/L Species Brachydanio rerio
Biodegradability: Readily biodegradable.
Precautions: Prevent contamination of soil, ground and surface water.
13. DISPOSAL CONSIDERATIONS
In accordance with local environmental laws. Avoid disposing into drainage systems and into the environment.
14. TRANSPORT REGULATIONS
Not dangerous goods
IMDG & ADR/RID
UN number: 3082 Class: 9 Packing group: III EMS-No: F-A, S-F
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Benzyl benzoate). Marine pollutant: Marine pollutant
UN number: 3082 Class: 9 Packing group: III
Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (Benzyl benzoate)
15. REGULATORY INFORMATION
OSHA Hazards: Harmful by ingestion.
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: Acute Health Hazard
Massachusetts Right To Know Components: No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components: Benzyl benzoate, CAS-No. 120-51-4
New Jersey Right To Know Components: Benzyl benzoate, CAS-No. 120-51-4
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
HMIS (Perceived): Health hazard: 1, Flammability: 1, Physical Hazard 0
NFPA (Perceived): Health hazard: 0, Fire Hazard: 1, Reactivity Hazard: 0
Canada Workplace Hazardous Material Information System (WHMIS) classification: D2B
Canadian Ingredient Disclosure List: None known to be present or none in reportable amounts
Section 16 - Additional Information
EINECS EC Number: 204-402-9
H302 = Harmful if swallowed.
H411 = Toxic to aquatic life with long lasting effects.
N = Dangerous for the environment
Xn = Harmful
R22 = Harmful if swallowed.
R51/53 = Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.