Ethyl acetoacetate or Ethyl 3-oxobutanoate or Ethyl acetylacetate or Ethyl aceto acetate Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Ethyl acetoacetate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Ethyl acetoacetate or Ethyl 3-oxobutanoate or Ethyl acetylacetateor Ethyl aceto acetate: CAS Number: 141-97-9, EINECS EC Number: 205-516-1, Molecular Formula: CH3COCH2COOC2H5 or C6H10O3, Molecular Weight: 130.14, FEMA Number: 2415, HS Code ---**

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SDS MSDS Sheet of Ethyl acetoacetate or Ethyl 3-oxobutanoate or Ethyl acetylacetate Manufacturers

Ethyl acetoacetate
Ethyl aceto acetate Ethyl 3-oxobutanoate or Ethyl acetylacetate Pure Suppliers
Ethyl acetoacetate

Ethyl acetoacetate or EAA appears as a colorless liquid with a fruity odor. Ethyl acetoacetate is mainly used as a chemical intermediate in the production of several compounds, such as amino acids, analgesics, antibiotics, antimalarial agents, antipyrine and aminopyrine, and vitamin B1; as well as the manufacture of dyes, inks, lacquers, perfumes, plastics, and yellow paint pigments. It is also used as a flavoring for food.

Properties and Specifications of Ethyl acetoacetate or Ethyl 3-oxobutanoate or Ethyl acetylacetate:
Appearance: Colorless liquid with a fruity odor
Assay: 99% minimum
Melting point: -45C.
Boiling point: 181C.
Flash point: 73C literature.
Relative density: around 1.02 to 1.03
Solubility: Soluble in water and in benzene, chloroform etc.

We manufacture and supply as under:

Acetophenone

Ethyl Acetoacetate

Ethyl Cyanoacetate

Methyl Acetoacetate

Ethyl Acetate

Aluminum Acetate

Butyl Acetate

Ethyl 4-Chloroacetoacetate.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

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Last 3 October, 2023

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Ethyl acetoacetate or Ethyl 3-oxobutanoate or Ethyl acetylacetate SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
 18-Oct-20

Section 1 - Chemical Product and Company Identification

Product Name & Other Names: Ethyl acetoacetate or Ethyl 3-oxobutanoate or Ethyl acetylacetate.
CAS Number: 141-97-9
EINECS EC Number: 205-516-1
FEMA Number: 2415
Molecular Formula: CH3COCH2COOC2H5 or C6H10O3
Molecular Weight: 130.14
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

Section 2 - Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling according to GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
NONE

Signal Word: None

Hazards not otherwise classified (HNOC):
May cause mild skin irritation.
May causes mild eye irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Section 3 - Composition, Information on Ingredients

Product Name & Other Names: Ethyl acetoacetate or Ethyl 3-oxobutanoate or Ethyl acetylacetate.
CAS Number: 141-97-9
EINECS EC Number: 205-516-1
FEMA Number: 2415

Section 4 - First Aid Measures

Always consult a physician after the first aid is given.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cup full of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Flammability: Combustible. Explosive in presence of oxidizing materials.
Extinguishing Media: Use Water, dry chemical powder, alcohol foam, water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, auto-ignition or explosion.

Section 6 - Accidental Release Measures

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Use proper personal protective equipment. Restrict unprotected personnel from the area. Remove all ignition sources and ventilate area. Use water spray to dilute spill to a non-flammable mixture. Avoid runoff into storm sewers and ditches which lead to waterways. Wash area with soap and water. Use water spray to disperse the gas/vapor.

Section 7 - Handling and Storage

Precautions for safe handling: Avoid ingestion and inhalation. Do not allow contact with heat. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like acids, bases, oxidizing agents, reducing agents.

Section 8 - Exposure Controls, Personal Protection

Airborne Exposure Limits: Not established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9 - Physical and Chemical Properties

Appearance: Colorless liquid with a fruity odor.
Odor: Pleasant fruity odor.
Odor threshold: Not available.
pH: 4,0 int 110 g/l @ 20C.
Relative density: around 1.02 to 1.03
Boiling Point: 181C.
Melting Point:
-45C.
Flash point: 73C literature.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water and in benzene, chloroform etc.
Viscosity: Not available.
Molecular Formula: CH3COCH2COOC2H5 or C6H10O3
Molecular Weight: 130.14

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, exposure to heat, spark.
Incompatibilities with Other Materials: Acids, bases, oxidizing agents, reducing agents.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

Acute toxicity: LD50 Oral Rat: 3980 mg/kg. LD50 Dermal Rabbit: > 5000 mg/kg.
Carcinogenicity: None of the components of this formulation are listed as a carcinogen by IARC, NTP or OSHA..
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Section 12 - Ecological Information

Toxicity to fish: semi-static test LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h
Persistence and Degradability: Readily biodegradable.
Mobility: Will likely be mobile in the environment due to its water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Section 13 - Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container of Glycerin and unused contents in accordance with law.

Section 14 - Transport Information

DOT USA & ADR/RID Europe: Not Regulated.
IMDG: Not Regulated.
IATA: Not Regulated.

Section 15 - Regulatory Information

USA:
Section 313
: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Section 16 - Additional Information

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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