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Ferrous Fumarate USP BP IP Pure AR Reagent FCC Food Grade Manufacturers, SDS MSDS Sheet
Ferrous Iron Fumarate CAS Number 141-01-5, EINECS EC Number 205-447-7, HS Code ---**; Molecular Weight 169.9, Molecular Formula: C4H2FeO4
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MSDS Sheet of Ferrous Fumarate Manufacturers
Iron (II) fumarate, also known as ferrous fumarate, is the iron(II) salt of fumaric acid, occurring as a reddish-orange powder, used to supplement iron intake. It has the chemical formula C4H2FeO4. We offer Commercial pure, USP BP IP and FCC Food grade.
Ferrous Fumarate USP Grade
C4H2FeO4 --- 169.90
2-Butenedioic acid, (E)-, iron(2+) salt.
Iron(2+) fumarate [141-01-5].
Ferrous Fumarate contains not less than 97.0 percent and not more than 101.0 percent of C4H2FeO4, calculated on the dried basis.
A: To 1.5 g add 25 mL of dilute hydrochloric acid (1 in 2). Dilute with water to 50 mL, heat to dissolve, then cool, filter on a fine-porosity, sintered-glass crucible, wash the precipitate with dilute hydrochloric acid (3 in 100), saving the filtrate for Identification test B, and dry the precipitate at 105C: the IR absorption of a potassium bromide dispersion of the dried precipitate so obtained exhibits maxima only at the same wavelengths as that of a similar preparation of USP Fumaric Acid RS.
B: A portion of the filtrate obtained in the preceding test responds to the tests for Iron.
Loss on drying: Dry it at 105C for 16 hours: it loses not more than 1.5% of its weight.
Sulfate: Transfer 1.0 g to a 250-mL beaker, add 100 mL of water, and heat on a steam bath, adding hydrochloric acid drop wise, until complete solution is effected (about 2 mL of the acid will be required). Filter the solution if necessary, and dilute the filtrate with water to 100 mL. Heat the filtrate to boiling, add 10 mL of barium chloride TS, warm on a steam bath for 2 hours, cover, and allow to stand for 16 hours. (If crystals of ferrous fumarate form, warm the solution on the steam bath to dissolve them.) Pass the solution through ash less filter paper, wash the residue with hot water until, with the addition of ammonium sulfide TS, a black precipitate is no longer formed in the filtrate, and transfer the paper containing the residue to a tared crucible. Char the paper, without burning, and ignite the crucible and its contents at 600 to constant weight: each mg of residue is equivalent to 0.412 mg of SO4. Not more than 0.2% is found.
Arsenic: Transfer 2.0 g to a beaker, and add 10 mL of water and 10 mL of sulfuric acid. Warm to precipitate the fumaric acid completely, cool, add 30 mL of water, and filter into a 100-
mL volumetric flask. Wash the precipitate with water, adding the washings to the flask, add water to volume, and mix. Transfer 50.0 mL of this solution into the arsine generator flask, and dilute with water to 55 mL: the resulting solution meets the requirements of the test, the addition of 20 mL of 7 N sulfuric acid specified for Procedure being omitted. The limit is 3 ppm.
Limit of ferric iron: Transfer 2.0 g, accurately weighed, to a glass-stoppered, 250-mL conical flask, add 25 mL of water and 4 mL of hydrochloric acid, and heat on a hot plate until solution is complete. Insert the stopper in the flask, and cool to room temperature. Add 3 g of potassium iodide, insert the stopper in the flask, swirl to mix, and allow to stand in the dark for 5 minutes. Remove the stopper, add 75 mL of water, and titrate with 0.1 N sodium thiosulfate VS, adding 3 mL of starch TS as the end-point is approached. Not more than 7.16 mL of 0.1 N sodium thiosulfate is consumed (2.0%).
Limit of lead: To pass the atomic absorption spectrophotometer test. The Test solution does not exceed that of the Standard solution (0.001%).
Mercury: To pass the test of 3 µg per g.
Assay— Transfer 500 mg of Ferrous Fumarate, accurately weighed, to a 500-mL conical flask, and add 25 mL of dilute hydrochloric acid (2 in 5). Heat to boiling, and add a solution of 5.6 g of stannous chloride in 50 mL of dilute hydrochloric acid (3 in 10) drop wise until the yellow color disappears, then add 2 drops in excess. Cool the solution in an ice bath to room temperature, add 10 mL of mercuric chloride solution (1 in 20), and allow to stand for 5 minutes. Add 200 mL of water, 25 mL of dilute sulfuric acid (1 in 2), and 4 mL of phosphoric acid, then add 2 drops of orthophenanthroline TS, and titrate with 0.1 N ceric sulfate VS. Perform a blank determination, and make any necessary correction. Each mL of 0.1 N ceric sulfate is equivalent to 16.99 mg of C4H2FeO4.
Ferrous Fumarate BP Grade Ph Eur
C4H2FeO4 --- 169.9 --- 141-01-5
Iron (II) (E)-butenedioate.
93.0 per cent to 101.0 per cent (dried substance).
Appearance: Fine, reddish-orange or reddish-brown powder.
Solubility :Slightly soluble in water, very slightly soluble in ethanol (96 per cent).
A. Thin-layer chromatography.
B. Mix 0.5 g with 1 g of resorcinol R. To 0.5 g of the mixture in a crucible add 0.15 ml of sulphuric acid R and heat gently. A dark red semi-solid mass is formed. Add the mass, with care, to 100 ml of water R. An orange-yellow colour develops and the solution shows no fluorescence.
C. The filtrate obtained during preparation of the test solution in identification test A gives reaction (a) of iron (2.3.1).
Solution S :Dissolve 2.0 g in a mixture of 10 ml of lead-free hydrochloric acid R and 80 ml of water R, heating slightly if necessary. Allow to cool, filter if necessary and dilute to 100 ml with water R.
Sulphates: Maximum 0.2 per cent.
Arsenic: Maximum 5 ppm.
Ferric ion: Maximum 2.0 per cent.
Cadmium: Maximum 10.0 ppm.
Chromium: Maximum 2.00 × 102 ppm.
Lead: Maximum 20.0 ppm.
Mercury: Maximum 1.0 ppm.
Nickel: Maximum 2.00 × 102 ppm.
Zinc: Maximum 5.00 × 102 ppm.
Loss on drying: Maximum 1.0 per cent, determined on 1.000 g by drying in an oven at 105°C.
Dissolve with slight heating 0.150 g in 7.5 ml of dilute sulphuric acid R. Cool and add 25 ml of water R. Add 0.1 ml of ferroin R. Titrate immediately with 0.1 M cerium sulphate until the
colour changes from orange to light bluish-green. 1 ml of 0.1 M cerium sulphate is equivalent to 16.99 mg of C4H2FeO4.
Ferrous Fumarate IP Grade
Ferrous Fumarate FCC Food Grade
Iron (II) Fumarate FCC
C4H2FeO4 --- Formula weight 169.90 --- CAS: [141-01-5]
Ferrous Fumarate occurs as a red-orange to red-brown powder. It may contain soft lumps that produce a yellow streak when crushed. It is soluble in water and in alcohol.
A. Add 25 mL of 1:2 hydrochloric acid to about 1.5 g of sample, and dilute to 50 mL with water. Heat to effect complete solution; then cool; filter on a fine-porosity, sintered glass crucible; wash the precipitate with 2:100 hydrochloric acid, saving the filtrate for Identification Test B; and dry the precipitate at 105°C. Add 3 mL of water and 7 mL of 1 N sodium hydroxide to 400 mg of the dried precipitate, and stir until solution is complete. Add, drop wise, 2.7 N hydrochloric acid until the solution is just acid to litmus; add 1 g of pnitrobenzyl
bromide and 10 mL of alcohol; and reflux the mixture for 2 h. Cool, filter, and wash the precipitate with two small portions of a 2:1 alcohol:water mixture, followed by two small portions of water. The precipitate, recrystallized from hot alcohol and dried at 105°C, melts at about 152°C.
B. A portion of the filtrate obtained in Identification Test A gives positive tests for Iron.
Assay: Not less than 97.0% and not more than 101.0% of C4H2FeO4, calculated on the dried basis.
Ferric Iron: Not more than 2.0%.
Lead: Not more than 2 mg/kg.
Loss on Drying: Not more than 1.5%.
Mercury: Not more than 3 mg/kg.
Sulfate: Not more than 0.2%.
For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
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Last 22 March, 2017
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Ferrous Fumarate SDS MSDS Sheet, Material Safety Data Sheet
Section 1: Chemical Product and Identification
Product Name: Ferrous Fumarate, Iron Fumarate, Fumaric acid Ferrous salt
EINECS EC-No.: 205-447-7
Chemical Formula: C4H2FeO4
Molecular Weight: 169.9
Intended Use: Laboratory and Industrial Manufacturing.
SUPPLIER: As per letterhead.
Section 2: Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Word: None
Not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200)
Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May Causes mild eye irritation.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
Section 3: Composition and Information on Ingredients
Composition: Ferrous Fumarate
EINECS EC-No.: 205-447-7
% by Weight: 100
Section 4: First Aid Measures
Always seek medical attention after first aid measures are provided.
Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Skin Contact: In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Thoroughly clean shoes and clothes before reuse. Get medical attention.
Inhalation: If Ferrous Fumarate is inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately.
Section 5: Fire and Explosion Data
Flammability of the Product: Ferrous Fumarate may be combustible at high temperature.
Auto-Ignition Temperature: Not available.
Products of Combustion: Some metallic oxides CO CO2 and fumes.
Fire Hazards in Presence of Various Substances: Slightly flammable in presence of heat. Non-flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances: Slightly explosive in presence of open flames and sparks. Non-explosive in presence of shocks.
Fire Fighting Media and Instructions:
Small Fire: Use DRY chemical powder.
Large Fire: Use water spray, fog or foam. Avoid water jet.
Section 6: Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal authority requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow drain.
Section 7: Handling and Storage
Precautions: Keep away from heat. Keep away from sources of ignition. Do not breathe dust.
Storage: Keep Ferrous Fumarate container tightly closed. Keep container in a cool, well-ventilated area.
Section 8: Exposure Controls/Personal Protection
Exposure Limits: TWA 1 mg/m3 - US. ACGIH Threshold Limit Values (2011).
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Section 9: Physical and Chemical Properties
Physical state and appearance: Ferrous Fumarate is solid. (Powdered solid. Crystalline powder.)
Taste: Not available.
Chemical Formula: C4H2FeO4
Molecular Weight: 169.9
Color: Not available.
pH (1% soln/water): Not available.
Melting Point: 280C
Specific Gravity: 2.4
Solubility: Soluble in water.
Section 10: Stability and Reactivity Data
Stability: It is stable.
Conditions of Instability: Excessive heat, dust generation
Incompatibility with various substances: Strong oxidising agents.
Polymerization: Will not occur.
Section 11: Toxicological Information
Toxicity to Animals:
LD50/oral/rat = 3850 mg/kg.
LD50/oral/mouse = 1570 mg/kg.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Environmental Toxicity: Not available.
Section 12: Ecological Information
Ecotoxicity: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance legal regulations.
Section 14: Transport Information
DOT (USA) & ADR/RID: Not dangerous goods
TDG/IMDG: Not dangerous goods
IATA: Not dangerous goods
Section 15: Other Regulatory Information
OSHA: Not considered hazardous by the OSHA Hazard Communication Standard
Section 313 (Specific toxic chemical listings):Substance is not listed.
TSCA (Toxic Substances Control Act: Substance is not listed.
California Proposition 65 Chemicals known to cause cancer: Substance is not listed.
Canada WHMIS: Not controlled under WHMIS (Canada).
EINECS EC-No.: 205-447-7
Section 16 - Additional Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.