P-Anisidine or 4-Methoxyaniline or 4-Aminoanisole or 4-Aminophenyl methyl ether Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of P-Anisidine or 4-Methoxyaniline or 4-Aminoanisole or 4-Aminophenyl methyl ether, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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P-Anisidine or 4-Methoxyaniline or 4-Aminoanisole or 4-Aminophenyl methyl ether CAS Number 104-94-9, EINECS EC Number: 203-254-2, Molecular Formula: CH3OC6H4NH2, Molecular Weight: 123.15, HS Code 29222990

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SDS MSDS Sheet of P-Anisidine or 4-Methoxyaniline or 4-Aminoanisole or 4-Aminophenyl methyl ether Manufacturers

P-Anisidine
4-Methoxyaniline or 4-Aminoanisole or 4-Aminophenyl methyl ether Suppliers
P-Anisidine

General Properties and Specifications of P-Anisidine or 4-Methoxyaniline or 4-Aminoanisole or 4-Aminophenyl Methyl Ether:
Appearance: Off-white to gray crystalline compound.
Odor: Amine-like odor.
Solubility of 10% solution in methanol: Clear.
Assay: 98% minimum.
pH: 8.34 in water @ 32C.
Relative density: about 1.07
Melting Point: 56C to 60C.
Boiling Point: 246C.
Flash Point: 122C.
Auto-ignition temperature: 450C.
Solubility: Appreciable solubility in water.
Storage: Room Temperature. Light Sensitive, Air Sensitive, Heat Sensitive.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

We also manufacture and supply as under:

Aniline

Anisaldehyde

Para Anisidine

Butylated Hydroxy Anisole

2,6-Dimethylaniline

4-Methoxyphenol.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

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Copyright and Usual Disclaimer is Applicable.
Last 10 October, 2023

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P-Anisidine or 4-Methoxyaniline or 4-Aminoanisole or 4-Aminophenyl Methyl Ether SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
10-Oct-23

Section 1. Product Information

Product Name & Other Names: P-Anisidine or 4-Methoxyaniline or 4-Aminoanisole or 4-Aminophenyl Methyl Ether.
CAS No.: 104-94-9
EINECS EC Number: 203-254-2
Chemical Formula: CH3OC6H4NH2
Molecular Weight: 123.15
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 2), H300
Acute toxicity, Dermal (Category 1), H310
Acute toxicity, Inhalation (Category 2), H330
Carcinogenicity (Category 1B), H350
Specific target organ toxicity - repeated exposure (Category 2), H373
Short-term (acute) aquatic hazard (Category 1), H400

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

GHS Label Elements
toxic.png
Toxic

GHS Label Elements
healthhazard.png
Health Hazard

Signal Words: Danger

Hazard statements:
H300 Fatal if swallowed.
H 310 Fatal in contact with skin.
H330 Fatal if inhaled.
H350 May cause cancer.
H373 May causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.

Precautionary statements:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get medical advice/attention if you feel unwell.
P330: Rinse mouth.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P391: Collect spillage.
P405: Store locked up.
P403+233: Store in a well-ventilated place. Keep container tightly closed.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T+ = Very toxic.
N = Dangerous for the environment.
Risk Phrases:
R23/24 = Toxic by inhalation and in contact with skin.
R28 = Very toxic if swallowed.
R45 May cause cancer.
R48 Danger of serious damage to health by prolonged exposure.
R51 Toxic to aquatic organisms.
R68 Possible risk of irreversible effects.

Section 3: Composition and Information on Ingredients

Product Name & Other Names: P-Anisidine or 4-Methoxyaniline or 4-Aminoanisole or 4-Aminophenyl Methyl Ether.
CAS No.: 104-94-9
EINECS EC Number: 203-254-2

Section 4. First Aid & Procedure

Always get medical attention after the first aid is over.

Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and shoes before reuse. Get medical attention if irritation develops.
Eyes:
Immediately flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower eyelids. Hold eyelids apart during irrigation. Get medical attention.
Inhalation:
Remove person to fresh air. If breathing is difficult, give oxygen. If not breathing administer artificial respiration. Get medical attention.

Section 5. Fire Fighting Measures

Fire/Explosion: Not considered to be a fire and explosion hazard.
Extinguishing Medium:
Water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance/ mixture: Nitrogen oxides (NOx), Carbon oxides and fumes.
Fire Fighting Instructions: Use suitable protective equipment for surrounding fire.
Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Section 6. Spills and Disposals

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Section 7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like Oxidizing agents, Acids, Acid chlorides, Acid anhydrides. Storage: Room Temperature. Light Sensitive, Air Sensitive, Heat Sensitive.

Section 8. Exposure Controls & Personal Protection

Exposure Limits:
ACGIH TLV(TWA): 0.5 mg/m3 (skin)
OSHA PEL(TWA): 0.5 mg/m3 (skin)
JSOH OELs(TWA): 0.5 mg/m3 (skin)
Engineering Controls: Use adequate exhaust ventilation to keep airborne concentrations below the allowable exposure limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9. Physical & Chemical Data

Appearance: Off-white to gray crystalline compound.
Odor: Amine-like odor.
Odor threshold: Not available.
pH: 8.34 in water @ 32C.
Relative density: about 1.07
Melting point/freezing point: 56C to 60C.
Initial boiling point and boiling range: 246C.
Flash point: 122C.
Auto-ignition temperature: 450C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Appreciable solubility in water.
Viscosity: Not available.
Chemical Formula: CH3OC6H4NH2
Molecular Weight: 123.15

Section 10. Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Incompatibility (Materials to Avoid):
Oxidizing agents, Acids, Acid chlorides, Acid anhydrides.
Conditions to Avoid: Incompatible materials, exposure to excessive heat.
Hazardous Decomposition Products: Nitrogen oxides (NOx), Carbon oxides and fumes.
Hazardous Polymerization:
Will not occur.

Section 11. Toxicological Information

Toxicity to Animals:
LD50 Oral - Rat – 45.06 mg/kg.
Acute toxicity estimate Inhalation - 4h – 0.0501 mg/l - dust/mist.
Acute toxicity estimate Dermal – 5.01 mg/kg.
Carcinogenicity: IARC = Group 3 (Not classifiable as carcinogenic to humans).
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.
May cause damage to organs through prolonged or repeated exposure.

Section 12. Ecological Information

Toxicity to daphnia and other aquatic invertebrates: semi-static test EC50 - Daphnia magna (Water flea) – 4.12 mg/l - 48 h.
Ecotoxicity: Very toxic to aquatic organisms.
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Section 13. Disposal Suggestions

Dispose of in accordance with all applicable local, state, and federal regulations at an approved waste disposal facility.

Section 14. Transport and Label Information

DOT (USA) & ADR/RID Europe:
UN-No UN 2811
Proper Shipping Name: Toxic solid, organic, n.o.s.
Hazard Class 6.1; Packing Group III.
IMDG/IMO
UN-No UN 2811
Proper Shipping Name: Toxic solid, organic, n.o.s.
Hazard Class 6.1; Packing Group III.
IATA:
UN-No UN 2811
Proper Shipping Name: Toxic solid, organic, n.o.s.
Hazard Class 6.1; Packing Group III.

Section 15. Regulatory Information

USA:
SARA 311/312 Hazards
: Acute Health Hazard, Chronic Health Hazard.

Section 16. Other Information

European Labeling in Accordance with EC Directives:
H300 Fatal if swallowed.
H 310 Fatal in contact with skin.
H330 Fatal if inhaled.
H350 May cause cancer.
H373 May causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T+ = Very toxic.
N = Dangerous for the environment.
Risk Phrases:
R23/24 = Toxic by inhalation and in contact with skin.
R28 = Very toxic if swallowed.
R45 May cause cancer.
R48 Danger of serious damage to health by prolonged exposure.
R51 Toxic to aquatic organisms.
R68 Possible risk of irreversible effects.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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