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Propylene Glycol BP USP FCC Food Grade Manufacturers, SDS GHS MSDS Sheet
Propylene Glycol: CAS Number: 57-55-6, EINECS EC Number: 200-338-0, Molecular Formula: CH3CH(OH)CH2OH , Molecular Weight: 76.09, FEMA Number 2940, HS Code ---**
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SDS MSDS Sheet of Propylene Glycol Manufacturers
Pure BP USP FCC Food Grade
Propylene glycol, also called propane-1,2-diol, is a viscous colorless hygroscopic liquid which is nearly odorless with a faintly sweet taste. It is used in food processing as the E-number E1520. The freezing point of water is depressed when mixed with propylene. In general, glycols are non-corrosive, have very low volatility and very low toxicity. Propylene glycol is used as a humectant (E1520), solvent and preservative in food and for tobacco products. It is also one of the major ingredients used in electronic. Propylene glycol is also used in various edible items such as coffee-based drinks, liquid sweeteners, ice cream, whipped dairy products and soda.
Propylene Glycol BP Grade
Ph Eur C3H8O2 -- 76.1 -- 57-55-6
Action and use: Excipient.
Propylene glycol is (RS)-propane-1,2-diol.
A viscous, clear, colourless, hygroscopic liquid, miscible with water and with ethanol (96 per cent).
A. It complies with the test for relative density.
B. It complies with the test for refractive index.
C. Boiling point: 184C to 189C.
D. To 0.5 ml add 5 ml of pyridine and 2 g of finely ground nitrobenzoyl chloride. Boil for 1 min and pour into 15 ml of cold water with shaking. Filter, wash the precipitate with 20 ml of a saturated solution of sodium hydrogen carbonate and then with water and dry. Dissolve in boiling ethanol (80 per cent V/V) and filter the hot solution. On cooling, crystals are formed which, after drying at 100-105 °C, melt at 121 °C to 128 °C.
Appearance: It is clear and colourless.
Relative density: 1.035 to 1.040.
Refractive index: 1.431 to 1.433.
Acidity: To 10 ml add 40 ml of water R and 0.1 ml of bromothymol blue solution. The solution is greenish-yellow. Not more than 0.05 ml of 0.1 M sodium hydroxide is required to change the colour of the indicator to blue.
Oxidising substances: To 10 ml add 5 ml of water, 2 ml of potassium iodide solution and 2 ml of dilute sulphuric acid and allow to stand in a ground-glass-stoppered flask protected from light for 15 min. Titrate with 0.05 M sodium thiosulphate, using 1 ml of starch solution as indicator. Not more than 0.2 ml of 0.05 M sodium thiosulphate is required.
Reducing substances: To 1 ml add 1 ml of dilute ammonia and heat in a water-bath at 60C for 5 min. The solution is not yellow. Immediately add 0.15 ml of 0.1 M silver nitrate and allow to stand for 5 min. The solution does not change its appearance.
Heavy metals: 5 ppm m/V.
Water: Not more than 0.2 per cent, determined on 5.00 g by the semi-micro determination of water.
Sulphated ash: Heat 50 g until it burns and ignite. Allow to cool. Moisten the residue with sulphuric acid and ignite; repeat the operations. The residue weighs not more than 5 mg (0.01 per cent).
Propylene Glycol USP Grade
Propylene Glycol contains not less than 99.5 percent of C3H8O2.
Identification: Infrared Absorption 1on undried specimen.
Specific gravity: between 1.035 and 1.037.
Acidity: Add 1 mL of phenolphthalein to 50 mL of water, then add 0.1 N sodium hydroxide until the solution remains pink for 30 seconds. Then add 10 mL of Propylene Glycol, accurately measured, and titrate with 0.10 N sodium hydroxide until the original pink color returns and remains for 30 seconds: not more than 0.20 mL of 0.10 N sodium hydroxide is required.
Water: not more than 0.2%.
Residue on ignition: Heat 50 g in a tared 100-mL shallow dish until it ignites, and allow it to burn without further application of heat in a place free from drafts. Cool, moisten the residue with 0.5 mL of sulfuric acid, and ignite to constant weight: the weight of the residue does not exceed 3.5 mg.
Chloride: A 1-mL portion shows no more chloride than corresponds to 0.10 mL of 0.020 N hydrochloric acid (0.007%).
Sulfate: A 5.0-mL portion shows no more sulfate than corresponds to 0.30 mL of 0.020 N sulfuric acid (0.006%).
Heavy metals: Mix 4.0 mL with water to make 25 mL: the limit is 5 ppm.
Polypropylene Glycol FCC Food Grade
Polypropylene Glycol occurs as a clear, colorless or practically colorless, viscous liquid. It is an addition polymer of propylene glycol and water represented by the formula HO(C3H6O)n- C3H6OH, in which n represents the average number of oxypropylene groups. It is soluble in water and in such organic solvents as aliphatic ketones and alcohols, but it is insoluble in ether and in most aliphatic hydrocarbons.
Function: Defoaming agent.
Lead:Not more than 1 mg/kg.
Nominal Molecular Weight: Not less than 90.0% and not more than 110.0% of the labeled value.
pH: Between 6.0 and 9.0.
Propylene Oxide: Not more than 0.02%.
Residue on Ignition: Not more than 0.01%.
Viscosity: Passes test.
For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
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Last : 11 April, 2017
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Propylene Glycol SDS MSDS Sheet, Material Safety Data Sheet
1. PRODUCT DESCRIPTION
Product Name: Propylene Glycol
CAS Number: 57-55-6
EINECS EC Number: 200-338-0
Molecular Weight: 76.09
Molecular Formula: CH3CH(OH)CH2OH
Recommended usage: Industrial Manufacturing.
Supplier: As per letterhead.
2. HAZARD IDENTIFICATION
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Labeling as per GHS & Regulation EC 1272/2008 (CLP) & GHS
GHS Label Elements
Signal Words: None
Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation, if exposed in large quantity.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
HMIS (Perceived): Health hazard: 0, Flammability:1, Physical hazards: 0
NFPA (Perceived): Health hazard: 0, Fire: 1, Reactivity Hazard: 0
3. COMPOSITION/INFORMATION ON INGREDIENTS
Product Name: Propylene Glycol
CAS Number: 57-55-6
EINECS EC Number: 200-338-0
4. FIRST AID MEASURES
Always get medical attention after the first aid is over.
Emergency and First Aid Procedures:
Eyes - Flush with water for at least 15 minutes, raising and lowering eyelids occasionally. Get medical attention if irritation persists.
Skin - Thoroughly wash exposed area for at least 15 minutes. Remove contaminated clothing. Launder contaminated clothing before reuse. Get medical attention if irritation persists.
Ingestion - If it is swallowed, if conscious, give plenty of water. Immediately call a physician. Never give anything by mouth to an unconscious person.
Inhalation - Remove to fresh air. Give oxygen if breathing is difficult; give artificial respiration if breathing has stopped. Get medical attention.
5. FIREFIGHTING PROCEDURES
Extinguisher Media: Use media suitable to extinguish surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Flammable Limits in Air % by Volume: N/A
Special hazards arising from the substance or mixture: Carbon oxides, Nitrogen oxides (NOx)
Special Fire fighting Procedures: Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus.
6. SPILL OR LEAK PROCEDURES
Steps to be taken in Case if Released or Spilled:
Avoid dust formation. Avoid breathing vapors, mist or gas. Ventilate area of leak or spill. Wear appropriate personal protective equipment.
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. Do not let product enter drains. Small amounts of residue may be flushed to sewer with plenty of water.
7. SPECIAL PRECAUTIONS
Keep in a well closed container stored under cold to warm conditions, in a ventilated area. Protect against physical damage. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed.
8. SPECIAL PROTECTION INFORMATION
Respiratory Protection (Specify Type): None needed under normal conditions of use with adequate ventilation. NIOSH approved equipment should be worn if PELs are exceeded.
Ventilation Local Exhaust: Yes
Eye Protection: Splash proof chemical safety goggles should be worn at all times.
Other Protective Clothing or Equipment: Lab apron, eye wash, and safety shower.
9. PHYSICAL DATA
Molecular Weight: 76.09
Molecular Formula: CH3CH(OH)CH2OH
Appearance and Odor: Clear viscous liquid. Odor not defined.
Melting Point: -60C
Boiling Point: 187C
Specific gravity: 1.04
Percent Volatile by Volume: No data.
Evaporation Rate(H2O=1): No data.
Solubility in Water: No data.
10. REACTIVITY DATA
Stability: It is stable
Conditions to Avoid: Heat, Dust generation.
Incompatibility (Materials to Avoid): Acid chlorides, Acid anhydrides, Oxidizing agents, Chloroformates, Reducing agents.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, fumes.
Hazardous Polymerization: Will not occur
11. TOXICITY DATA
LD50 Oral - Rat - 20,000 mg/kg
LD50 Dermal - Rabbit - 20,800 mg/kg
LD50 Intramuscular - Rat - 14 g/kg
LD50 Intravenous - Dog - 26 g/kg
Carcinogenicity: This product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, NTP, ACGIH & OSHA.
12. ECOLOGICAL DATA
Toxicity to fish: mortality NOEC - Pimephales promelas (fathead minnow) - 52,930 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: mortality NOEC - Daphnia (water flea) - 13,020 mg/l -48 h
EC50 - Daphnia magna (Water flea) - > 10,000 mg/l - 48 h
Bioaccumulative potential: Does not bioaccumulate.
EPA Waste Numbers: None
13. DISPOSAL INFORMATION
Waste Disposal Methods: Dispose in accordance with all applicable Federal, State and Local regulations.
14. TRANSPORT INFORMATION
DOT & ADR/RID: Not regulated.
IMDG: Not regulated.
IATA: Not regulated.
15. REGULATORY INFORMATION
OSHA Hazards: No known OSHA hazards
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: No SARA Hazards
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
16. ADDITIONAL INFORMATION
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.