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Sodium Alginate BP, FCC Food Grade Manufacturers, SDS GHS MSDS Sheet

Sodium Alginate: CAS Number: 9005-38-3, EINECS EC Number: ----, FEMA Number: 2015, Molecular Formula: (C6H7O6Na)n, Molecular Weight: Equiv wt, calculated 198.11, HS Code ---**

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SDS MSDS Sheet of Sodium Alginate Manufacturers

Sodium Alginate
Pure BP USP FCC Food Grade
Sodium Alginate

Sodium Alginate BP Grade
Ph Eur
Action and use: Excipient.

DEFINITION
Sodium alginate consists mainly of the sodium salt of alginic acid, which is a mixture of polyuronic acids [C6H8O6)n] composed of residues of D-mannuronic acid and L-guluronic acid. Sodium alginate is obtained mainly from algae belonging to the Phaeophyceae.

CHARACTERS
Appearance: White or pale yellowish-brown powder.
Solubility: Slowly soluble in water forming a viscous, colloidal solution, practically insoluble in ethanol (96 per cent).

IDENTIFICATION
A. Dissolve 0.2 g with shaking in 20 ml of water. To 5 ml of this solution add 1 ml of calcium chloride solution. A voluminous gelatinous mass is formed.
B. To 10 ml of the solution prepared in identification test A add 1 ml of dilute sulphuric acid. A gelatinous mass is formed.
C. To 5 mg add 5 ml of water, 1 ml of a freshly prepared 10 g/l solution of 1,3-dihydroxynaphthalene in ethanol (96 per cent) and 5 ml of hydrochloric acid. Boil for 3 min, cool, add 5 ml of water, and shake with 15 ml of di-isopropyl ether. Carry out a blank test. The upper layer obtained with the substance to be examined exhibits a deeper bluish-red colour than that obtained with the blank.
D. It complies with the test for sulphated ash. The residue obtained, dissolved in 2 ml of water, gives reaction (a) of sodium.

TESTS
Solution S: Dissolve 0.10 g in water, with constant stirring, dilute to 30 ml with the same solvent and allow to stand for 1 h.
Appearance of solution: The solution is not more opalescent than reference and not more intensely coloured than intensity 6 of the range of reference solutions of the most appropriate colour.
Dilute 1 ml of solution S to 10 ml with water R.
Chlorides: Maximum 1.0 per cent.
Calcium: Maximum 1.50 per cent.
Heavy metals: Maximum 20 ppm.
Loss on drying: Maximum 15.0 per cent, determined on 0.1000 g by drying in an oven at 105C for 4 h.
Sulphated ash: 30.0 per cent to 36.0 per cent (dried substance), determined on 0.1000 g.
Microbial contamination: Total viable aerobic count not more than 103 micro-organisms per gram, determined by plate-count. It complies with the tests for Escherichia coli and Salmonella.

Sodium Alginate FCC Food Grade
Algin
(C6H7O6Na)n Equiv wt, calculated 198.11
Equiv wt, actual (avg.) 222.00
INS: 401 CAS: [9005-38-3]

DESCRIPTION
Sodium Alginate occurs as a white to yellow-brown, fibrous or granular powder. It is the sodium salt of alginic acid. It dissolves in water to form a viscous, colloidal solution. It is insoluble in alcohol and in hydroalcoholic solutions in which the alcohol content is greater than about 30% by weight. It is insoluble in chloroform, in ether, and in acids having a pH lower than about 3.
Function: Stabilizer; thickener; emulsifier; gelling agent.

REQUIREMENTS
Identification: -
A. Add 1 mL of calcium chloride to 5 mL of a 1:100 aqueous solution. A voluminous, gelatinous precipitate forms.
B. Add 1 mL of 2 N sulfuric acid to 10 mL of a 1:100 aqueous solution. A heavy, gelatinous precipitate forms.
C. Place about 5 mg of sample into a test tube, add 5 mL of water, 1 mL of a freshly prepared 1:100 naphtholresorcinol:ethanol solution, and 5 mL of hydrochloric acid. Heat the mixture to boiling, boil gently for about 3 min, and then cool to about 15C. Transfer the contents of the test tube to a 30-mL separator with the aid of 5 mL of water, and extract with 15 mL of isopropyl ether. Perform a blank determination and make any necessary correction. The isopropyl ether extract from the sample exhibits a deeper purple hue than that from the blank.
Assay: A sample yields not less than 18.0% and not more than 21.0% of carbon dioxide (CO2), corresponding to between 90.8% and 106.0% of Sodium Alginate (equiv wt 222.00).
Arsenic: Not more than 3 mg/kg.
Lead: Not more than 5 mg/kg.
Loss on Drying: Not more than 15.0%.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) 91-22-23770100, 23726950
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e-mail: info@mubychem.com

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Last 16 August, 2017

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Borax; Sodium Borate Boric Acid
Calcium Acetate Calcium Chloride
Calcium Gluconate Calcium Hydroxide
Calcium Lactate Calcium Oxide
Calcium Saccharate Calcium Sulfate
Chromic Chloride Citric Acid
Calcium Citrate Copper Gluconate
Copper Sulfate, Cupric Sulphate Cupric Chloride
Ferrous Fumarate Ferrous Gluconate
Fumaric Acid Ferrous Sulphate
Ferric Sulfate Ferric Ammonium Citrate
Ferric Chloride  
Gentian Violet Mannitol
Magnesium Chloride Magnesium Gluconate
Magnesium Lactate Dihydrate Magnesium Sulfate
Magnesium Trisilicate Maleic Acid
Malic Acid BP USP Manganese Gluconate
Manganese Sulfate Manganese Chloride
Methylene Blue Potassium Bromide
Potassium Chloride Potassium Gluconate
Potassium Bitartrate, Cream of Tartar Potassium Hydroxide
Potassium Iodide Potassium Iodate
Potassium Sorbate Sodium Acetate
Sodium Bicarbonate Sodium Butyrate
Sodium Caprylate Sodium Fluoride
Sodium Gluconate Sodium Hydroxide Pellets
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Sodium Perborate Sodium Propionate
Sodium Thiosulfate Sodium Sulfate
Stannous Chloride Dihydrate Zinc Carbonate
Zinc Chloride Zinc Gluconate
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Sodium Alginate SDS MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Algin, Alginic acid sodium salt.
CAS No.: 9005-38-3
EINECS EC Number: -
Molecular Weight: -
Chemical Formula: (C6H7O6Na)n
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.

2. HAZARD IDENTIFICATION

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
None

Signal Words: None

Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes eye mild irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.

HMIS (Perceived): Health hazard: 0, Flammability: 0, Physical hazards: 0
NFPA (Perceived): Health hazard: 0, Fire: 0, Reactivity Hazard: 0

3. COMPOSITION/INFORMATION ON INGREDIENTS

Principal Components: Sodium Alginate
CAS No.: 9005-38-3
EINECS EC Number: -

4. FIRST AID MEASURES

Always get medical attention after the first aid is over.

Emergency and First Aid Procedures:
Eyes - Flush with water for at least 15 minutes, raising and lowering eyelids occasionally. Get medical attention if irritation persists.
Skin - Thoroughly wash exposed area for at least 15 minutes. Remove contaminated clothing. Launder contaminated clothing before reuse. Get medical attention if irritation persists.
Ingestion - If Sodium Alginate is swallowed, if conscious, give plenty of water. Immediately call a physician. Never give anything by mouth to an unconscious person.
Inhalation - Remove to fresh air. Give oxygen if breathing is difficult; give artificial respiration if breathing has stopped. Get medical attention.

5. FIREFIGHTING PROCEDURES

Extinguisher Media: Use media suitable to extinguish surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Flammable Limits in Air % by Volume: N/A
Special Fire fighting Procedures: Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus.

6. SPILL OR LEAK PROCEDURES

Steps to be taken in Case Sodium Alginate is Released or Spilled:
Ventilate area of leak or spill. Wear appropriate personal protective equipment.
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. Small amounts of residue may be flushed to sewer with plenty of water.

7. SPECIAL PRECAUTIONS

Keep Sodium Alginate in a well closed container stored under cold to warm conditions. Protect against physical damage. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. SPECIAL PROTECTION INFORMATION

Respiratory Protection (Specify Type): None needed under normal conditions of use with adequate ventilation. NIOSH approved equipment should be worn if PELs are exceeded.
Ventilation Local Exhaust: Yes
Eye Protection: Splash proof chemical safety goggles should be worn at all times.
Other Protective Clothing or Equipment: Lab apron, eye wash, and safety shower.

9. PHYSICAL DATA

Chemical Formula: (C6H7O6Na)n
Appearance and Odor: Sodium Alginate is beige powder, odorless
Melting Point: N/A
Boiling Point: N/A
Vapor Pressure: N/A
Vapor Density (Air=1): N/A
Percent Volatile by Volume: 0 (21C)
Evaporation Rate(H2O=1): N/A
Solubility in Water: Soluble.

10. REACTIVITY DATA

Stability: Sodium Alginate is stable
Conditions to Avoid: Heat, humidity, Dust generation.
Incompatibility (Materials to Avoid): Strong oxidizing agents, Strong acids and bases.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide
Hazardous Polymerization: Will not occur

11. TOXICITY DATA

Toxicity Data:
LD50 Oral - Rat - > 5,000 mg/kg(Alginic acid, sodium salt)
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, NTP, ACGIH & OSHA.

12. ECOLOGICAL DATA

Toxicity to fish: Not available.
Bioaccumulative potential: Does not bioaccumulate.
EPA Waste Numbers: None
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. DISPOSAL INFORMATION

Waste Disposal Methods: Dispose Sodium Alginate in accordance with all applicable Federal, State and Local regulations.

14. TRANSPORT INFORMATION

DOT & ADR/IRD
Not regulated.
IMDG
Not regulated.
IATA
Not regulated.

15. REGULATORY INFORMATION

USA:
TSCA 8(b) inventory
: Sodium alginate
OSHA Hazards: No known OSHA hazards
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Water Act: This product does not contain any Hazardous Substances listed under the U.S. Clearwater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. Clearwater Act, Section 311, Table 117.3.
California Prop 65 Components: This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.

WHMIS (Canada): Not controlled under WHMIS (Canada).
DSL: All components of this product are on the Canadian DSL.
DSCL (EEC): This product is not classified according to the EU regulations.

16. ADDITIONAL INFORMATION
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.