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Magnesium Gluconate BP USP & Commercial Pure AR LR ACS Analytical Reagent FCC Food Grade Manufacturers, SDS MSDS Sheet
Magnesium Gluconate CAS Number 3632-91-5 or (59625-89-7 for hydrate), EINECS EC Number 222-848-2, HS Code ---**; Molecular Weight C12H22MgO14, Molecular Formula: 414.6
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MSDS Sheet of Magnesium Gluconate Manufacturers
Magnesium gluconate is a is the magnesium salt of gluconic acid. Magnesium gluconate shows the highest level of bioavailability of any magnesium salt and is recommended as the optimal salt for human supplementation. It has E number "E580".
Magnesium Gluconate BP Ph Eur Grade
C12H22MgO14,xH2O -- 414.6 -- 3632-91-5 (anhydrous)
Anhydrous or hydrated magnesium D-gluconate.
98.0 per cent to 102.0 per cent (anhydrous substance).
Appearance: White or almost white, amorphous, hygroscopic, crystalline or granular powder.
Solubility: Freely soluble in water, slightly soluble in ethanol (96 per cent), very slightly soluble in methylene chloride.
A. Thin-layer chromatography.
B. To 10 ml of solution S (see Tests) add 3 ml of ammonium chloride solution. A slight opalescence may be observed. Add 10 ml of disodium hydrogen phosphate solution. A white precipitate is formed that does not dissolve upon the addition of 2 ml of dilute ammonia.
Solution S: Dissolve 1.0 g in water R and dilute to 50 ml with the same solvent.
Appearance of solution: Solution S is clear (2.2.1) and not more intensely coloured than reference solution Y7 (2.2.2, Method II).
Sucrose and reducing sugars: Dissolve 0.5 g in a mixture of 2 ml of hydrochloric acid R1 and 10 ml of water R. Boil for 5 min, allow to cool, add 10 ml of sodium carbonate solution R and allow to stand for 10 min. Dilute to 25 ml with water and filter. To 5 ml of the filtrate add 2 ml of cupri-tartaric solution and boil for 1 min. Allow to stand for 2 min. No red precipitate is formed.
Chlorides: Maximum 500 ppm.
Sulphates: Maximum 500 ppm.
Heavy metals: Maximum 10 ppm.
Water: Maximum 12.0 per cent, determined on 80 mg.
Microbial contamination: Total viable aerobic count (2.6.12) not more than 103 micro-organisms per gram, determined by plate count.
Magnesium Gluconate USP Grade
C12H22MgO14xH2O -- (anhydrous) 414.60
D-Gluconic acid, magnesium salt (2:1), hydrate.
Magnesium D-gluconate (1:2) hydrate.
Magnesium D-gluconate (1:2) dihydrate 450.64 [59625-89-7].
Magnesium Gluconate contains not less than 98.0 percent and not more than 102.0 percent of C12H22MgO14, calculated on the anhydrous basis.
A: A solution (1 in 10) responds to the tests for Magnesium.
B: Chromatographic plate test.
pH: between 6.0 and 7.8, in a solution (1 in 20).
Water: between 3.0% and 12.0%.
Chloride: A 1.0-g portion shows no more chloride than corresponds to 0.70 mL of 0.020 N hydrochloric acid (0.05%).
Sulfate: A 2.0-g portion shows no more sulfate than corresponds to 1.0 mL of 0.020 N sulfuric acid (0.05%).
Heavy metals: the limit is 0.002%.
Reducing substances: the limit is 1.0%.
Magnesium Gluconate FCC Food Grade
C12H22MgO14 Formula wt, anhydrous 414.60
C12H22MgO14·2H2O Formula wt, dihydrate 450.63
INS: 580 CAS: anhydrous [3632-91-5]
CAS: dihydrate [59625-89-7]
Magnesium Gluconate occurs as a white to off white powder or granulate. It is anhydrous, the dihydrate, or a mixture of both. It is very soluble in water and is sparingly soluble in alcohol. It is insoluble in ether.
A. A 1:20 aqueous solution gives positive tests for Magnesium.
B. Chromatography Test.
Assay: Not less than 98.0% and not more than 102.0% of C12H22MgO14, calculated on the anhydrous basis.
Chloride: Not more than 0.05%.
Lead: Not more than 2 mg/kg.
Reducing Substances: Not more than 1.0%.
Sulfate: Not more than 0.05%.
Water: Between 3.0% and 12.0%.
For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
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Last 22 March, 2017
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Magnesium Gluconate SDS MSDS Sheet, Material Safety Data Sheet
Section 1: Chemical Product and Company Identification
Product Name: Magnesium Gluconate
Synonym: D-Gluconic acid, magnesium salt (2:1); Glucomag; Glucosium; Menesia
Chemical Formula: C12H22MgO14 · xH2O
Molecular Weight: 414.6
CAS Number: 3632-91-5
EINECS EC Code: 222-848-2
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.
Section 2: Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Labeling according GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Word: None
Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
OSHA Hazards: No known OSHA hazards.
Section 3: Composition and Information on Ingredients
Name: Magnesium Gluconate
CAS Number: 3632-91-5
EINECS EC Code: 222-848-2
Section 4: First Aid Measures
Always seek medical advice after the first aid treatment.
Skin: Rinse with water. Soap may be used. Seek Medical Aid.
Eyes: Wash eyes with plenty of water for at least 15 minutes, lifting lids occasionally. Seek Medical Aid.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Ingestion: If swallowed, induce vomiting immediately after giving two glasses of water. Never give anything by mouth to an unconscious person.
Notes to Physician: Treat symptomatically.
Section 5: Fire and Explosion Data
Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Magnesium oxide, Fumes and Oxides of carbon.
Fire Fighting Media and Instructions: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Section 6: Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.
Large Spill: Do not inhale vapors, mist, or gas. Avoid dust formation. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV with local authorities.
Section 7: Handling and Storage
Precautions: Do not breathe dust. Keep away from incompatibles such as oxidizing agents, acids.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Section 8: Exposure Controls/Personal Protection
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent Gloves.
Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Section 9: Physical and Chemical Properties
Physical state and appearance: Solid white to off-white powder or granules.
Chemical Formula: C12H22MgO14 · xH2O
Molecular Weight: 414.6
pH (5% soln/water): Not available.
Boiling Point: Not available.
Melting Point: Not available.
Solubility: Soluble in water.
Section 10: Stability and Reactivity Data
Stability: It is stable.
Conditions of instability: Incompatible materials
Incompatibility with various substances: Heat, light, strong oxidizing agents, bases, amines, reducing agents, acids, acid anhydrides.
Polymerization: Will not occur.
Section 11: Toxicological Information
Toxicity to Animals: LD50 Intravenous - mouse - 321 mg/kg
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH, OSHA.
Section 12: Ecological Information
Ecotoxicity: The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. Not dangerous for the ozone layer.
Products of Biodegradation: The product itself and its products of degradation are not toxic.
Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
DOT (US): Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
ADR/RID: Not dangerous goods
Section 15: Other Regulatory Information
USA Federal and State Regulations:
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: No SARA Hazards
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Canada: Listed on the Canadian DSL (Domestic Substances List)
WHMIS Hazard Class: Non-controlled
EINECS EC Code: 222-848-2
Section 16 - Additional Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.