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Sodium Stibogluconate or Sodium Antimony Gluconate BP Manufacturers, SDS GHS MSDS Sheet
Sodium Stibogluconate: CAS Number: 16037-91-5, EINECS EC Number: yyyyy, HS Code ---**
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SDS MSDS Sheet of Sodium Stibogluconate Manufacturers
Pure & BP Grade
Sodium stibogluconate, sold under the brand name Pentostam among others and it is used in pharmacy.
Sodium Stibogluconate BP Grade
Sodium Stibogluconate is mainly the disodium salt of μ-oxy-bis[gluconato(3-)-c2,c3,c4hydroxoantimony]. It contains not less than 30.0% and not more than 34.0% of antimony(V), calculated with reference to the dried and methanol-free substance.
The method of manufacture is such as to ensure consistently controlled reaction stoichiometry in order to yield sodium stibogluconate that is satisfactory with regard to intrinsic toxicity.
A colourless, mostly amorphous powder.
Very soluble in water; practically insoluble in ethanol (96%) and in ether.
A. A solution is dextrorotatory.
B. Pass hydrogen sulphide into a 5% w/v solution for several minutes. An orange precipitate is produced.
C. When heated, it chars without melting leaving a residue which yields the reactions characteristic of antimony compounds and the reactions characteristic of sodium salts.
Stability and acidity of solution: Heat a solution containing the equivalent of 10% w/v of antimony(V) in an autoclave at 115.5C and at a pressure of 70 kPa for 30 minutes. The resulting solution is colourless or almost colourless and has a pH of 5.0 to 5.6.
Antimony(III): Dissolve 2 g in 30 ml of water, add 15 ml of hydrochloric acid and titrate with 0.00833M potassium bromate using methyl orange solution as indicator. Not more than 1.3 ml of 0.00833M potassium bromate is required.
Chloride: Dissolve 2.5 g in 50 ml of water and add 2 ml of 2M nitric acid and 75 ml of acetate buffer pH 5.0 . Titrate with 0.1M silver nitrate determining the end point potentiometrically. Not more than 3.0 ml of 0.1M silver nitrate is required.
Methanol: Not more than 2.0% w/w when determined by the method.
Loss on drying: When dried to constant weight at 130C at a pressure not exceeding 0.7 kPa, loses not more than 15.0% of its weight. Use 1 g.
ASSAY: Dissolve 0.16 g in 30 ml of hydrochloric acid , add 70 ml of orthophosphoric acid and stir carefully until completely mixed. Titrate with 0.05M ammonium iron( II ) sulphate prepared using sulphuric acid (1%) and determining the end point potentiometrically using a platinum electrode and a silver-silver chloride reference electrode. Each ml of 0.05M ammonium iron(II) sulphate is equivalent to 3.044 mg of antimony(V).
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Last 3 October, 2017
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Sodium Stibogluconate or Sodium Antimony Gluconate SDS MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Synonyms: Sodium Stibogluconate, Sodium Antimony Gluconate
CAS No.: 16037-91-5
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral Category 4
Acute toxicity, inhalation Category 4
Chronic aquatic toxicity (Category 2)
Labeling according GHS & Regulation (EC) No 1272/2008
GHS Label Elements
GHS Label Elements
Signal Words: Danger
H302: Harmful if swallowed.
H332: Harmful if inhaled.
H411: Toxic to aquatic life with long lasting effects.
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P330: Rinse mouth.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P391: Collect spillage.
P501: Dispose of contents/ container to an approved waste disposal plant.
According to European Directive 67/548/EEC as amended:
N Dangerous for the environment
R20 Harmful by inhalation
R22: Harmful if swallowed.
3. Composition/Information on Ingredients
Synonyms: Sodium Stibogluconate
CAS No.: 16037-91-5
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Flammability of the Product: Non-flammable.
Products of Combustion: Carbon oxides, Sodium oxides, Antimony oxide.
Fire: Not considered to be a fire hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.
6. Accidental Release Measures
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.
7. Handling and Storage
Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: TWA 0.5 mg/m3 USA, Occupational Exposure Limits, (OSHA) - Table Z-1 Limits for Air Contaminants.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Solid white powder or lumps.
Odor: It is odorless.
Solubility: Not available.
pH: <1 @ 50g/liter
Density: Not available.
% Volatiles by volume @ 21C (70F): Not available.
Boiling Point: Not available.
Melting Point: Not available.
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits fumes, oxides of carbon and antimony oxide when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents.
Conditions to Avoid: Incompatibles heat and moisture.
11. Toxicological Information
LD50 Intraperitoneal - Mouse - 33 mg/kg
Carcinogenic Effects: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, ACGIH, NTP, OSHA.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
12. Ecological Information
Toxicity to fish: Not available.
Environmental Fate: Not available.
Environmental Toxicity: It is toxic to fish. Harmful to aquatic life in very low concentrations.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
14. Transport Information
DOT (USA) & ADR/RID: Not dangerous goods: Not dangerous goods
TDG/IMDG: Not dangerous goods
IATA: Not dangerous goods
15. Regulatory Information
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 311/312 Hazards: Acute Health Hazard
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
16. Other Information
Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.