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Hydrated Manganese Glycerophosphate BP, FCC Food Grade Manufacturers, SDS GHS MSDS Sheet
Hydrated Manganese Glycerophosphate: CAS Number: 1320-46-3, EINECS EC Number: 215-301-4, Molecular Formula: C3H7MnO6P . xH2O, Molecular Weight: 225 HS Code ---**
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SDS MSDS Sheet of Hydrated Manganese Glycerophosphate Manufacturers
Hydrated Manganese Glycerophosphate
Pure BP FCC Food Grade
Hydrated Manganese Glycerophosphate BP Grade
C3H7MnO6P,xH2O -- 225.0
Mixture of variable proportions of hydrated manganese (II) (2RS)-2,3-dihydroxypropyl phosphate and hydrated manganese (II) 2-hydroxy-1-(hydroxymethyl)ethyl phosphate.
Content: 97.0 per cent to 102.0 per cent (dried substance).
Appearance: White or pale pink, hygroscopic powder.
Solubility: Practically insoluble in water and in ethanol (96 per cent). It is freely soluble in dilute mineral acids.
A. Mix 1 g with 1 g of potassium hydrogen sulphate R in a test tube fitted with a delivery tube. Heat strongly and direct the white vapour towards a piece of filter paper impregnated with a freshly prepared 10 g/l solution of sodium nitroprusside R. The filter paper develops a blue colour in contact with piperidine.
B. Disperse 50 mg in 5 ml of water R. Add 0.5 ml of ammonium sulphide solution. A pale pink precipitate is formed that dissolves on the addition of 1 ml of acetic acid R.
C. Ignite 0.1 g in a crucible. Take up the residue with 5 ml of nitric acid R and heat on a water-bath for 1 min. Filter. The filtrate gives reaction (b) of phosphates.
Solution S: Dissolve 5.0 g in 20 ml of dilute hydrochloric acid. Filter if necessary. Add dilute ammonia until a precipitate is formed. Dissolve the precipitate by adding the minimum quantity needed of dilute hydrochloric acid and dilute to 100 ml with distilled water.
Glycerol and ethanol (96 per cent)-soluble substances: Maximum 1.0 per cent.
Shake 1.00 g with 25 ml of ethanol (96 per cent) for 1 min. Filter. Evaporate the filtrate to dryness on a water-bath and dry the residue at 70 °C for 1 h. The residue weighs a maximum of 10 mg.
Chlorides: Maximum 0.15 per cent.
Phosphates: Maximum 0.3 per cent.
Sulphates: Maximum 0.2 per cent.
Iron: Maximum 50 ppm.
Heavy metals: Maximum 20 ppm.
Loss on drying: Maximum 12.0 per cent, determined on 1.000 g by drying in an oven at 105 °C for 4 h.
To 0.200 g add 50 ml of water and stir until dissolution. Add 10 mg of ascorbic acid, 20 ml of ammonium chloride buffer solution pH 10.0 and 0.3 ml of a 2 g/l solution of mordant black 11 in triethanolamine. Titrate with 0.1 M sodium edetate until the colour changes from violet to pure blue.
In an airtight container .
Manganese Glycerophosphate FCC Food Grade
C3H7MnO6P·xH2O Formula wt, anhydrous 225.00
Manganese Glycerophosphate occurs as a white or pink-white powder. One gram dissolves in about 5 mL of 1:4 citric acid solution. It is slightly soluble in water, and is insoluble in alcohol.
Identification: A 1:20 solution in 2.7 N hydrochloric acid gives positive tests for Manganese.
Assay: Not less than 98.0% and not more than 100.5% of C3H7MnO6P after drying.
Lead: Not more than 4 mg/kg.
Loss on Drying: Not more than 12.0%.
For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
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Last 17 May, 2017
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Hydrated Manganese Glycerophosphate SDS MSDS Sheet, Material Safety Data Sheet
Section 1: Chemical Product and Company Identification
Product Name: Hydrated Manganese Glycerophosphate
Chemical Formula: C3H7MnO6P . xH2O
Molecular Weight: 225
CAS Number: 1320-46-3
EINECS EC Code: 215-301-4
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.
Section 2: Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity,oral Category 4
Skin corrosion/irritation Category 3
Serious eye damage/eye irritation Category 2B
Labeling according GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Word: Warning
Hazards not otherwise classified (HNOC):
H302 Harmful if swallowed
H316 Causes mild skin irritation.
H320 Causes eye irritation.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P262: Do not get in eyes, on skin, or on clothing.
P270: Do not eat, drink or smoke when using this product.
P281: Use personal protective equipment as required.
P330: Rinse mouth.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+313: If skin irritation occurs: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.
P501: Dispose of contents/container to authorized agents only.
Section 3: Composition and Information on Ingredients
Name: Manganese Gluconate
CAS Number: 1320-46-3
EINECS EC Code: 215-301-4
Section 4: First Aid Measures
Always seek medical advice after the first aid treatment.
Skin: Rinse with water. Soap may be used. Seek Medical Aid.
Eyes: Wash eyes with plenty of water for at least 15 minutes, lifting lids occasionally. Seek Medical Aid.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Ingestion: If swallowed, induce vomiting immediately after giving two glasses of water. Never give anything by mouth to an unconscious person.
Notes to Physician: Treat symptomatically.
Section 5: Fire and Explosion Data
Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Manganese oxide, Fumes and Oxides of carbon.
Fire Fighting Media and Instructions: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Section 6: Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.
Large Spill: Do not inhale vapors, mist, or gas. Avoid dust formation. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV with local authorities.
Section 7: Handling and Storage
Precautions: Do not breathe dust. Keep away from incompatibles such as oxidizing agents, acids.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Section 8: Exposure Controls/Personal Protection
TWA: 1 STEL: 3 (mg/m3) from ACGIH
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent Gloves.
Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Section 9: Physical and Chemical Properties
Physical state and appearance: Solid pinkish powder or granules.
Chemical Formula: C3H7MnO6P . xH2O
Molecular Weight: 225
Relative Density: NA
pH (5% soln/water): Not available.
Boiling Point: Not available.
Melting Point: Decomposes on heating.
Solubility: Soluble in water.
Section 10: Stability and Reactivity Data
Stability: It is stable.
Conditions of instability: Incompatible materials
Incompatibility with various substances: Heat, light, strong oxidizing agents, bases, amines, reducing agents, acids, acid anhydrides.
Hazardous decomposition products: Carbon oxides & Manganese oxides are expected.
Polymerization: Will not occur.
Section 11: Toxicological Information
Toxicity to Animals: Not available.
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH, OSHA.
Section 12: Ecological Information
Ecotoxicity: The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. Not dangerous for the ozone layer.
BOD5 and COD: Not available.
Products of Biodegradation: The product itself and its products of degradation are not toxic.
Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
DOT (US): Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
ADR/RID: Not dangerous goods
Section 15: Other Regulatory Information
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
TSCA 8(b) inventory: No products were found.
Canada: WHMIS Hazard Class: CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
EINECS EC Code: 215-301-4
Section 16 - Additional Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.