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Hydrated Sodium Glycerophosphate BP & Pure Grade Manufacturers, SDS GHS MSDS Sheet
Hydrated Sodium Glycerophosphate: CAS Number: 1334-74-3 or 55073-41-1 & more, EINECS EC Number: 215-613-0 & more, Molecular Formula: C3-H7-Na2-O6-P, Molecular Weight: 216, HS Code ---**
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SDS MSDS Sheet of Sodium Glycerophosphate Manufacturers
Hydrated Pure BP & Pure Grade
Hydrated Sodium Glycerophosphate BP Grade
C3H7Na2O6P, xH2Oıı216.0 (anhydrous substance)
Mixture of variable proportions of sodium (2RS)-2,3-dihydroxypropyl phosphate and sodium 2-hydroxy-1-(hydroxymethyl)ethyl phosphate. The degree of hydration is 4 to 6.
Content: 98.0 per cent to 102.0 per cent (anhydrous substance).
Appearance: White or almost white, crystalline powder or crystals.
Solubility: Freely soluble in water, practically insoluble in acetone and in alcohol.
A. Solution S (see Tests) gives reaction (a) of sodium.
B. To 0.1 g add 5 ml of dilute nitric acid R. Heat to boiling and boil for 1 min. Cool. The solution gives reaction (b) of phosphates.
C. In a test-tube fitted with a glass tube, mix 0.1 g with 5 g of potassium hydrogen sulphate. Heat strongly and direct the white vapour into 5 ml of decolorised fuchsin solution. A violet-red colour develops which becomes violet upon heating for 30 min on a water-bath.
Solution S: Dissolve 10.0 g in carbon dioxide-free water prepared from distilled water and dilute to 100 ml with the same solvent.
Appearance of solution: Solution S is not more opalescent than reference suspension II (and not more intensely coloured than reference solution.
Alkalinity: To 10 ml of solution S add 0.2 ml of phenolphthalein solution. Not more than 1.0 ml of 0.1 M hydrochloric acid is required to change the colour of the indicator.
Glycerol and alcohol-soluble substances: Maximum 1.0 per cent.
Shake 1.000 g with 25 ml of alcohol R for 10 min. Filter. Evaporate the filtrate on a water-bath and dry the residue at 70 °C for 1 h. The residue weighs not more than 10 mg.
Chlorides: Maximum 200 ppm.
Phosphates: Maximum 0.1 per cent.
Sulphates: Maximum 500 ppm.
Iron: Maximum 20 ppm.
Heavy metals: Maximum 20 ppm.
Water: 25.0 per cent to 35.0 per cent, determined on 0.100 g.
ASSAYa = percentage content of water,
Dissolve 0.250 g in 30 ml of water. Titrate with 0.05 M sulphuric acid , determining the end-point potentiometrically.
Calculate the percentage content of sodium glycerophosphate (anhydrous substance) from the expression:
n1 = volume of 0.05 M sulphuric acid used in the assay, in millilitres,
n2 = volume of 0.1 M hydrochloric acid used in the test for alkalinity, in millilitres,
m = mass of the substance to be examined, in grams
For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
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Last : 23 March, 2017
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Hydrated Sodium Glycerophosphate SDS MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Synonyms: Glycerophosphate disodium salt hydrate
CAS No.: 1334-74-3 or 55073-41-1 or 154804-51-0
EINECS EC Number: 215-613-0, 212-464-3
Molecular Weight: 216
Chemical Formula: C3-H7-Na2-O6-P
Chemical Family: Amides
Intended Use: Industrial Manufacturing
Supplier: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Word: None
Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
OSHA Hazards: No known OSHA hazards.
3. Composition/Information on Ingredients
Ingredient: Hydrated Sodium Glycerophosphate
CAS No.: 1334-74-3 or 55073-41-1 or 154804-51-0
EINECS EC Number: 215-613-0, 212-464-3
4. First Aid Measures
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wash affected areas with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if symptoms occur.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Fire: It is not considered to be a fire hazard.
Explosion: Reactions with incompatibles may pose an explosion hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
6. Accidental Release Measures
Ventilate area of leak or spill. Wear appropriate personal protective equipment. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal.
7. Handling and Storage
Keep dry. If storage piles become wet, surrounding floor may be slippery. Reacts with oxidizing agents and may explode spontaneously in air. Store in a tightly closed container. Protect container from physical damage. Containers may be hazardous when empty.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: Contains no substances with occupational exposure limit values.
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece particulate respirator (NIOSH type N100 filters) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. If heat is involved, an ammonia/methylamine, dust/mist cartridge may be necessary.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection:: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance: It is white crystals or powder.
Solubility: Soluble in water.
Specific Gravity: NA.
pH: >9 (@ 50gm/liter)
% Volatile by volume @ 21C (70F): 0
Molecular Weight: 216
Chemical Formula: C3-H7-Na2-O6-P
Boiling Point: NA.
Melting Point: 102 - 104C.
10. Stability and Reactivity
Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Decomposes upon heating and can form products including ammonia, oxides of nitrogen and phosphorous, carbon dioxide.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents.
11. Toxicological Information
Oral rat LD50: Not available.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
12. Ecological Information
Toxicity to fish: Not available.
Environmental Fate: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Results of PBT and vPvB assessment: Not available
13. Disposal Considerations
Not considered a hazardous waste under Federal Hazardous Waste Regulations 40 CFR 261. Follow standard disposal procedures. Offer surplus and non-recyclable solutions to a licensed disposal company. Dispose of container and unused contents in accordance with legal requirements.
14. Transport Information
DOT (US): Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
ADT/RID: Not dangerous goods
15. Regulatory Information
OSHA: No known OSHA hazards
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: No SARA Hazards
California Proposition 65: This product contains no chemicals known to the State of California to cause cancer, birth defects, or other reproductive harm
EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Canada WHMIS (Canada): Not controlled under WHMIS (Canada). This product is on the Domestic Substances List (DSL). Canada NDSL: No
16. Other Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.