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Tartaric Acid BP USP NF FCC Food Grade Manufacturers, SDS MSDS Sheet
Tartaric Acid: CAS Number: 87-69-4, EINECS EC Number: 201-766-0, Molecular Formula: C4H6O6, Molecular Weight: 150.1 HS Code ---**
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MSDS Sheet of Tartaric Acid Manufacturers
BP USP FCC Food Grade
Tartaric Acid BP Grade
C4H6O6 --- 150.1--- 87-69-4
Content: 99.5 per cent to 101.0 per cent (dried substance).
Appearance: White or almost white, crystalline powder or colourless crystals.
Solubility: Very soluble in water, freely soluble in ethanol (96 per cent).
A. Solution S (see Tests) is strongly acid.
B. It gives the reactions of tartrates.
Solution S: Dissolve 5.0 g in distilled water and dilute to 50 ml with the same solvent.
Appearance of solution: Solution S is clear and not more intensely coloured than reference solution.
Specific optical rotation: + 12.0 to + 12.8 (dried substance)
Oxalic acid: Maximum 350 ppm, calculated as anhydrous oxalic acid.
Chlorides: Maximum 100 ppm.
Sulphates: Maximum 150 ppm.
Calcium: Maximum 200 ppm.
Heavy metals: Maximum 10 ppm.
Loss on drying: Maximum 0.2 per cent, determined on 1.000 g by drying in an oven at 105 °C
Sulphated ash: Maximum 0.1 per cent, determined on 1.0 g.
Dissolve 0.650 g in 25 ml of water. Titrate with 1 M sodium hydroxide using 0.5 ml of
phenolphthalein solution as indicator, until a pink colour is obtained.
1 ml of 1 M sodium hydroxide is equivalent to 75.05 mg of C4H6O6.
Tartaric Acid USP NF Grade
Butanedioic acid, 2,3-dihydroxy-; Butanedioic acid, 2,3-dihydroxy-, [R-(R*,R*)]-.
Tartaric acid; L -(+)-Tartaric acid [526-83-0] and [87-69-4].
Tartaric Acid, dried over phosphorus pentoxide for 3 hours, contains not less than 99.7 percent and not more than 100.5 percent of C4H6O6.
A: It responds to the tests for Tartrate.
B: When ignited, it gradually decomposes, emitting an odor resembling that of burning sugar
(distinction from citric acid).
Specific rotation: between +12.0 and +13.0 .
Test solution: 200 mg per mL, in water.
Loss on drying: Dry it over phosphorus pentoxide for 3 hours: it loses not more than 0.5% of its weight.
Residue on ignition: not more than 0.1%.
Limit of oxalate: Nearly neutralize 10 mL of a solution of it (1 in 10) with 6 N ammonium hydroxide, and add 10 mL of calcium sulfate TS: no turbidity is produced.
Sulfate: To 10 mL of a solution (1 in 100) add 3 drops of hydrochloric acid and 1 mL of barium chloride: no turbidity is produced.
Heavy metals: 0.001%.
Assay: Place about 2 g of Tartaric Acid, previously dried and accurately weighed, in a conical flask. Dissolve it in 40 mL of water, add phenolphthalein TS, and titrate with 1 N sodium hydroxide VS. Each mL of 1 N sodium hydroxide is equivalent to 75.04 mg of C4H6O6.
Tartaric Acid FCC Food Grade
C4H6O6 Formula wt 150.09
Tartaric Acid occurs as colorless or translucent crystals or as a white, fine to granular, crystalline powder. It is stable in air. One gram dissolves in 0.8 mL of water at 25°, in about 0.5 mL of boiling water, and in about 3 mL of alcohol. Its solutions are dextrorotatory.
Function: Acidifier; sequestrant; flavoring agent.
Identification :A sample solution gives positive tests for Tartrate.
Assay: Not less than 99.7% and not more than 100.5% of C4H6O6 after drying.
Lead: Not more than 2 mg/kg.
Loss on Drying: Not more than 0.5%.
Optical (Specific) Rotation: Between +12.0° and +13.0°.
Oxalate: Passes test.
Residue on Ignition: Not more than 0.05%.
Sulfate: Passes test.
Tartaric Acid ACS AR Analytical Reagent Grade
Formula Wt 150.0
CAS Number 87-69-4
Assay: Not less than 99.0%
Insoluble matter: 0.005%
Residue after ignition: 0.02%
Chloride (Cl): 0.001%
Oxalate (C2O4): Passes test
Phosphate (PO4): 0.001%
Sulfur compounds (as SO4): 0.002%
Heavy metals (as Pb): 5 ppm
Iron (Fe): 5 ppm
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Last 18 May, 2017
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Tartaric Acid SDS, MSDS, Safety Data Sheet
1. Product Identification
Synonyms: 2,3-Dihydroxybutanedioic acid
CAS No.: 87-69-4
EINECS EC Number: 201-766-0
Molecular Formula: C4H6O6
Molecular Weight: 150.1
2. Hazards Identification
Skin irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity - single exposure, Target Organs - Respiratory system. Category 3
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
GHS Label Elements
Signal Words: Warning
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
P264: Wash … thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P362: Take off contaminated clothing and wash before reuse.
HMIS (Perceived): Health hazard: 2, Flammability: 1, Physical hazards: 0
NFPA (Perceived): Health hazard: 2, Fire: 1, Reactivity Hazard: 0
3. Composition/Information on Ingredients
Ingredient: Tartaric Acid
CAS No.: 87-69-4
EINECS EC Number: 201-766-0
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: If Tartaric Acid is inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and get medical attention immediately.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing and shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
Flash point: 150 °C (302 °F) - closed cup
6. Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Absorb and/or contain spill with inert material, then place in suitable container. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources.
7. Handling and Storage
Keep Tartaric Acid in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of Tartaric Acid may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. Avoid dust formation and control ignition sources. Employ grounding, venting and explosion relief provisions in accord with accepted engineering practices in any process capable of generating dust and/or static electricity. Empty only into inert or non-flammable atmosphere. Emptying contents into a non-inert atmosphere where flammable vapors may be present could cause a flash fire or explosion due to electrostatic discharge.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance: Tartaric Acid is white crystals or powder.
Odor: Not available
Solubility: Soluble in water. 150 g/l at 20 °C (68 °F)
pH: 1.0 - 2 at 150 g/l at 25 °C (77 °F).
% Volatile by volume @ 21C (70F): 0
Boiling Point: NA
Melting Point: 170 - 172 °C (338 - 342 °F) - lit.
Vapor Density (Air=1): 5.18
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.
Molecular Formula: C6H4(CO2H)2
10. Stability and Reactivity
Stability: Tartaric Acid is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers and bases, sodium nitrate, sodium nitrite, nitric acid.
Conditions to Avoid: Direct sunlight. Extremely high or low temperatures, Heat, dusting and incompatibles.
11. Toxicological Information
LD50 oral rat: > 2000 mg/kg
LD50 dermal rat: > 2000 mg/kg
Lowest Published Lethal Dose LDLo, oral, rat: 7500 mg/kg
LD50 Intravenous - mouse - 485 mg/kg
--------\Cancer Lists\---------------- --------------
---------------- NTP Carcinogen---
Ingredient ----- Known -- Anticipated -- IARC Category
---------------- --------- -- ------------- -- -------------
Tartaric Acid -- No ------- No -------- -- None
12. Ecological Information
EC50 Daphnia 1: 93.31 mg/l 48 hr.
EC50 other aquatic organisms 1: 51.4 mg/l 72 hr
Environmental Fate: Sufficient information is not available. When released into the soil, Tartaric Acid is expected to leach into groundwater. When released into the soil, this material is expected to biodegrade. When released into water, this material is expected to biodegrade. This material is not expected to significantly bio accumulate.
No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Tartaric Acid in accordance with legal requirements.
14. Transport Information
Not dangerous goods
Not dangerous goods
Not dangerous goods
15. Regulatory Information
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: Acute Health Hazard
Massachusetts Right To Know Components: No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components: (+)-Tartaric acid, CAS-No. 87-69-4
New Jersey Right To Know Components: (+)-Tartaric acid, CAS-No. 87-69-4
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
OSHA: None of the chemicals in this product are considered highly hazardous by OSHA.
WHMIS Classification Canada: Class E - Corrosive Material
Listed on the Canadian DSL (Domestic Substances List).
CAS #87-69-4 is not listed on Canada’s Ingredient Disclosure List.
European labeling in accordance with EC Directives:
Hazard Symbols: XI
Risk phrases: R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety phrases: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39: Wear suitable gloves and eye / face protection.
Section 16 - Additional InformationDisclaimer:
Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.