Magnesium Peroxide BP & Pure Grade Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Magnesium Peroxid, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Magnesium peroxide: CAS Number: 1335-26-8, EINECS EC Number: 215-627-7, Molecular Formula: MgO2, Molecular Weight: 56.3, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Magnesium peroxide.

Magnesium peroxide (MgO2) is an odorless fine powder peroxide with a white to off-white color.

General Specifications of Magnesium Peroxide
Composition: MgO2
Magnesium Peroxide 35% to 40%
Calcium: 0.85%
Chloride Cl: 0.030%
Sulphate SO4: 0.3%
Heavy metals (As Pb): 0.003%
pH: 10
Moisture: 2%
Appearance: Light yellow to white fine powder

DEFINITION
Mixture of magnesium peroxide and magnesium oxide.
Content: 22.0 per cent to 28.0 per cent of MgO2.

CHARACTERS
Appearance: White or slightly yellow, amorphous, light powder.
Solubility: Practically insoluble in water and in ethanol (96 per cent). It dissolves in dilute mineral acids.

IDENTIFICATION
A. Dissolve about 15 mg in 2 mL of dilute nitric acid and neutralise with dilute sodium hydroxide solution. The solution gives the reaction of magnesium.
B. Dissolve 0.1 g in 2 mL of dilute sulfuric acid and dilute to 10 mL with water. Shake 1 mL of this solution with 5 mL of ether and 0.5 mL of potassium dichromate solution. The ether layer is blue.

TESTS
Solution S1: Dissolve cautiously 5.0 g in 40 mL of hydrochloric acid. Cautiously evaporate the solution to 10 mL and dilute to 100 mL with a mixture of equal volumes of acetic acid and distilled water. Filter, if necessary, through a previously ignited and tared porcelain or silica filter crucible of suitable porosity to give a clear filtrate. Keep the residue for the test for acid insoluble substances.
Solution S2: Dilute 5 mL of solution S1 to 25 mL with distilled water R.
Appearance of solution: Solution S1 is not more intensely coloured than reference solution.
Acidity or alkalinity: To 2.0 g add 100 mL of carbon dioxide-free water and heat to boiling for 5 min. Filter whilst hot through a sintered-glass filter, allow to cool and dilute to 100 mL with carbon dioxide-free water. To 15 mL of the filtrate, add 0.1 mL of phenolphthalein solution. The solution is red. Not more than 0.2 mL of 0.1 M hydrochloric acid is necessary to change the colour of the indicator. Keep the filtrate for the test for soluble substances.
Acid insoluble substances: Maximum 0.1 per cent.
Soluble substances: Maximum 1.5 per cent.
Chlorides: Maximum 0.1 per cent.
Sulfates: Maximum 0.5 per cent.
Arsenic: Maximum 4 ppm, determined on 5 mL of solution S1.
Calcium: Maximum 1.0 per cent.
Iron: Maximum 500 ppm.
Heavy metals: Maximum 30 ppm.

ASSAY
Dissolve 80.0 mg, shaking cautiously, in a mixture, previously cooled to 20C, of 10 mL of sulfuric acid and 90 mL of water. Titrate with 0.02 M potassium permanganate until a pink colour is obtained.
1 mL of 0.02 M potassium permanganate is equivalent to 2.815 mg of MgO2.

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Magnesium Peroxide SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 27-Oct-20

Product Name & Other Names: Magnesium Peroxide or Magnesium Dioxide.
CAS No.: 1335-26-8
EINECS: EC Number: 215-627-7
Molecular Weight: 56.3
Chemical Formula: MgO2
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Oxidizing Solids Category 2, H272
Skin corrosion/irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3, H335

Hazard Statements:
H272 - May intensify fire; oxidizer
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation.

Precautionary Statements - Prevention
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/combustible materials
P221: Take any precaution to avoid mixing with combustibles
P264: Wash face, hands and any exposed skin thoroughly after handling
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection
Precautionary Statements - Response
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P333 + P313: If skin irritation or rash occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/ attention
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use water for extinction
Precautionary Statements - Storage
P501: Dispose of contents/container in accordance with local, regional, national, international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xi Irritant
O Oxidizer
Risk Phrases:
R8. Contact with combustible material may cause fire.
R36/37/38 Irritating to eyes, respiratory system, and skin.

Product Name & Other Names: Magnesium Peroxide or Magnesium Dioxide.
CAS No.: 1335-26-8
EINECS: EC Number: 215-627-7
Percentage: around 50% active. Balance is non-hazardous magnesium salt.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.

Flammability of the Product: Non-flammable but it is an oxidizer.
Products of Combustion: It emits oxides of magnesium.
Fire: It is supporting fire as an oxidizer.
Explosion: Contact with oxidizable substances may cause explosion.
Fire Extinguishing Media: Water spray, foam, dry chemical or carbon dioxide. Use means suitable for extinguishing surrounding fire. Water should be preferred.
Special Information: It is an oxidizer. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Eliminate all sources of ignition. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Eliminate all sources of ignition. Contain spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system if local laws permit.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like organic substances, reducing agents, acids, powdered metals, strong bases, alcohols, phosphorous, anhydrides, halogens. Protect against physical damage heat or combustible substances.

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: White to yellowish crystals or powder or granules.
Odor: None.
Odor threshold: Not available.
pH: 10 to 11.
Relative density: 3.9
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Not available.
Viscosity: Not available.
Molecular Weight: 56.3
Chemical Formula: MgO2

Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Oxygen, oxides of magnesium.
Hazardous Polymerization: Will not occur.
Incompatibilities: Organic substances, Strong reducing agents, Acids, Powdered metals, Strong bases, Alcohols, phosphorous, Anhydrides, Halogens, Acids Metal powders and Reducing agents. Heat.
Conditions to Avoid: Moisture, Heat, Incompatibles.

Toxicity to Animals: Not available.
Carcinogenic Effects: Not a reported carcinogen.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

BOD5 and COD: Not available.
Toxicity: Not available.
Persistence and degradability: Not available.
Bioaccumulative potential: Not available.
Mobility in soil: Not available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements. Small amounts of this material may be suitable for sanitary sewer or trash disposal.

DOT USA, TDG Canada & ADR/RID Europe
Shipping Name: Magnesium Peroxide
Hazard Class: 5.1; Packing Group: II
UN Number: UN1476
Hazard Label: Oxidizer
IMDG/IMO
Shipping Name: Magnesium Peroxide
Hazard Class: 5.1; Packing Group: II
UN Number: UN1476
Hazard Label: Oxidizer
IATA
Shipping Name: Magnesium Peroxide
Hazard Class: 5.1; Packing Group: II
UN Number: UN1476
Hazard Label: Oxidizer.

USA:
SARA 302: Not subject to the reporting requirements of SARA Title III, Section 302.
Section 313: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Reactivity Hazard, Acute Health Hazard.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives:
H272 - May intensify fire; oxidizer
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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