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Phosphoric acid BP ACS AR Analytical Reagent, FCC Food Grade Manufacturers, SDS GHS MSDS Sheet

Phosphoric acid: CAS Number: 7664-38-2, EINECS EC Number: 231-633-2, Molecular Formula: H3PO4, Molecular Weight: 98, HS Code ---**

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SDS MSDS Sheet of Phosphoric acid Manufacturers

Phosphoric acid
Pure BP ACS AR FCC Food Grade
Phosphoric Acid

Phosphoric acid (also known as orthophosphoric acid H3PO4) is a non-toxic acid. In addition to being a chemical reagent, phosphoric acid has a wide variety of uses, including as a rust inhibitor, food additive, dental and orthop(a)edic etchant, electrolyte, flux, dispersing agent, industrial etchant, fertilizer feedstock, and component of home cleaning products. Phosphoric acids is also important in biology. The most common source of phosphoric acid is an 85% aqueous solution; such solutions are colourless, odourless, and non-volatile. The 85% solution is a syrupy liquid, but still pourable.

Phosphoric Acid BP Grade
Concentrated Phosphoric Acid, Ph Eur
H3PO4 -- 98.0 -- 7664-38-2

DEFINITION
Content: 84.0 per cent m/m to 90.0 per cent m/m.

CHARACTERS
Appearance: Clear, colourless, syrupy liquid, corrosive.
Solubility: Miscible with water and with ethanol (96 per cent). When stored at a low temperature it may solidify into a mass of colourless crystals which do not melt at a temperature below 28C.
Relative density: About 1.7.

IDENTIFICATION
A. Dilute with water. The solution is strongly acid.
B. Solution S (see Tests) neutralised with dilute sodium hydroxide solution gives the reactions of phosphates.

TESTS
Solution S: Dilute 10.0 g to 150 ml with water R.
Appearance of solution: Solution S is clear and colourless.
Substances precipitated with ammonia: To 10 ml of solution S add 8 ml of dilute ammonia. Any opalescence in the solution is not more intense than that in a mixture of 10 ml of solution S and 8 ml of water.
Hypophosphorous acid and phosphorous acid: To 5 ml of solution S add 2 ml of silver nitrate solution and heat on a water-bath for 5 min. The solution shows no change in appearance.
Chlorides: Maximum 50 ppm, determined on solution S.
Sulphates: Maximum 100 ppm.
Arsenic: Maximum 2 ppm, determined on 7.5 ml of solution S.
Iron: Maximum 50 ppm.
Heavy metals: Maximum 10 ppm.

ASSAY
To 1.000 g add a solution of 10 g of sodium chloride in 30 ml of water. Titrate with 1 M sodium hydroxide, using phenolphthalein solution as indicator. 1 ml of 1 M sodium hydroxide is equivalent to 49.00 mg of H3PO4.

Phosphoric Acid ACS AR Analytical Reagent Grade
Orthophosphoric Acid
Phosphoric(V) Acid
H3PO4
Formula Wt 98.00 CAS Number 7664-38-2

REQUIREMENTS
Assay: >85.0% H3PO4
Color (APHA): 10
Insoluble matter: 0.001%
Chloride (Cl): 3 ppm
Nitrate (NO3): 5 ppm
Sulfate (SO4): 0.003%
Volatile acids (as CH3COOH): 0.001%
Antimony (Sb): 0.002%
Calcium: 0.002%
Magnesium: 0.002%
Potassium (K): 0.005%
Sodium (Na): 0.025%
Arsenic (As): 1 ppm
Heavy metals (as Pb): 0.001%
Iron (Fe): 0.003%
Manganese (Mn): 0.5 ppm
Reducing substances: Passes test

Phosphoric Acid FCC Food Grade
Orthophosphoric Acid
H3PO4 Formula wt 98.00
INS: 338 CAS: [7664-38-2]

DESCRIPTION
Phosphoric Acid occurs as a colorless, aqueous solution, usually available in concentrations ranging from 75.0% to 85.0%. It is miscible with water and with alcohol.
Function: Acidifier; sequestrant.

REQUIREMENTS
Labeling: Indicate the percent, or the percent range, of Phosphoric Acid (H3PO4).
Identification: A 1:10 aqueous solution gives positive tests for Phosphate.
Assay: Not less than the minimum or within the range of percentage claimed by the vendor.
Arsenic: Not more than 3 mg/kg.
Cadmium: Not more than 3 mg/kg.
Fluoride: Not more than 10 mg/kg.
Lead: Not more than 3 mg/kg.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) 91-22-23770100, 23726950
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e-mail: info@mubychem.com

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Last 14 August, 2017

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Borax; Sodium Borate Boric Acid
Calcium Acetate Calcium Chloride
Calcium Gluconate Calcium Hydroxide
Calcium Lactate Calcium Oxide
Calcium Saccharate Calcium Sulfate
Chromic Chloride Citric Acid
Calcium Citrate Copper Gluconate
Copper Sulfate, Cupric Sulphate Cupric Chloride
Ferrous Fumarate Ferrous Gluconate
Fumaric Acid Ferrous Sulphate
Ferric Sulfate Ferric Ammonium Citrate
Ferric Chloride  
Gentian Violet Mannitol
Magnesium Chloride Magnesium Gluconate
Magnesium Lactate Dihydrate Magnesium Sulfate
Magnesium Trisilicate Maleic Acid
Malic Acid BP USP Manganese Gluconate
Manganese Sulfate Manganese Chloride
Methylene Blue Potassium Bromide
Potassium Chloride Potassium Gluconate
Potassium Bitartrate, Cream of Tartar Potassium Hydroxide
Potassium Iodide Potassium Iodate
Potassium Sorbate Sodium Acetate
Sodium Bicarbonate Sodium Butyrate
Sodium Caprylate Sodium Fluoride
Sodium Gluconate Sodium Hydroxide Pellets
Sodium Iodide Sodium Lactate
Sodium Perborate Sodium Propionate
Sodium Thiosulfate Sodium Sulfate
Stannous Chloride Dihydrate Zinc Carbonate
Zinc Chloride Zinc Gluconate
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Phosphoric Acid SDS MSDS Sheet, Material Safety Data Sheet

Section 1: Product Identification

Synonyms: Phosphoric Acid
CAS No.: 7664-38-2
EINECS EC Number: 231-633-2
Molecular Weight: 98
Chemical Formula: H3PO4
Relevant identified uses of the substance or mixture and uses advised against: Laboratory chemicals, Manufacture of substances. For Industrial use.
Details of the supplier of the safety data sheet: As per letter head.

Section 2: Hazard Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Corrosive to Metals Category 1
Skin corrosion/irritation Category 1A, B, C

Labeling according Regulation (EC) No 1272/2008

GHS Label Elements
Corrosive
Corrosive

Signal Words: Danger

Hazard statements:
H290: May be corrosive to metals
H314: Causes severe skin burns and eye damage

Precautionary statements:
P234: Keep only in original container.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
C Corrosive
R35 Causes severe burns.
For the full text of the S-statement & R-phrases mentioned in this Section, see Section 16.

Section 3: Composition / Information on Ingredients

Ingredient: Phosphoric Acid
CAS No.: 7664-38-2
EINECS EC Number: 231-633-2
Percent: 99 - 100%

Section 4: First Aid Measures

Always seek medical attention after first aid measures are provided.

Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eye with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician, immediately. Wash clothing before reuse..
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to and unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
Medical Conditions generally Aggravated by Exposure: Repeated exposure of the eyes to a low level of Sodium hydroxide dust can produce eye irritation. Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage.

Section 5: Fire Fighting Measures

Flash Point: NA
Fire Extinguishing Media: Adapt extinguishing media to the environment. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Fire Fighting Procedures: Wear self contained breathing apparatus for firefighting if necessary.
Unusual Fire and Explosion Hazards: Flammable hydrogen gas may be produced on prolong contact with metals such as aluminum, tin lead and zinc.
Hazardous combustion products: Oxides of sodium.

Section 6: Accidental Release Measures

Steps to be Taken in Case Material is Released or Spilled: Evacuate the area of all unnecessary personnel. Wear suitable protective equipment. Eliminate any ignition sources until the area is determined to be free from explosion or fire hazards. Contain the release and eliminate its source, if this can be done without risk. Take up and containerize for proper disposal.  Comply with local, state and Federal regulations on reporting releases. Refer to regulatory information for reportable quantity and other regulatory data.
Methods for cleaning up: Take up liquid spill into absorbent material, e.g.: dry sand/earth or powdered limestone. Scoop absorbed substance into closing containers. Carefully collect the spill/leftovers. Small quantities of liquid spill may be neutralize with acid solution. Wash away neutralized product with plentiful water. Clean contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling.
Waste Disposal Methods: Dispose of waste according to Federal, State and Local Regulations.

Section 7: Handling and Storage

Keep in a tightly closed original container. Protect from physical damage. Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities. Containers may be hazardous when empty since they retain product residues; observe all warnings and precautions listed for the product.

Section 8: Exposure Controls / Personal Protection

Components with workplace control parameters
USA ACGIH TWA: 1 mg/m³
USA OSHA
: 1 mg/m³ OSHA PEL (TWA) (mg/m³)
Engineering Controls Ventilation required:  It should be handled or transferred in an approved fume hood or with adequate ventilation.
Personal Protection Equipment
Respiratory protection: If workplace exposure limit (s) of product or any component is exceeded (see TLV/PEL), a NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH/MSHA respirator (negative pressure type) under specified conditions (see your safety equipment supplier). Engineering and/or administrative controls should be implemented to reduce exposure.
Protective gloves: Nitrile or equivalent.
Skin protection: Impervious, protective clothing.
Eye protection: Safety glasses with side shields must be worn at all times.
Additional clothing and/or equipment: Eyewash and safety equipment should be readily available.
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Section 9 Physical and Chemical Properties

Appearance and Physical State: Phosphoric Acid 85% a clear colorless is liquid.
Odor (threshold): Odorless.
Specific Gravity (H2O=1): 1.6 to 1.7
Vapor Pressure (mm Hg): 1 - 4 mm Hg at 15.5C (60F)
Vapor Density (air=1): NA
Melting Point: 21C
Boiling Point: 158C
pH: 1-1.5 at 50gm/liter
Solubility in Water: Soluble

Section 10: Stability and Reactivity

Stability: It is stable under ordinary conditions of use and storage.
Reactivity: Exothermic reaction with water. Reacts with metals to release hydrogen.
Materials to Avoid (Incompatibility): Strong bases, Powdered metals.
Hazardous Decomposition Products: Thermal decomposition may produce toxic fumes of phosphorus oxides and/or phosphine.
Hazardous Polymerization: Will not occur.

Section 11: Toxicological Information

Results of component toxicity test:
LD50 (rat): 1,530 mg/kg (anhydrous) (IUCLID)
LD50 (rabbit): 2,740 mg/kg (anhydrous)(IUCLID)
Carcinogenicity: This product is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification.
Symptoms of overexposure: Coughing. Dry/sore throat. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. FOLLOWING SYMPTOMS MAY APPEAR LATER: Respiratory difficulties. Risk of lung oedema. Burns to the gastric/intestinal mucosa. Nausea. Abdominal pain. Blood in vomit. AFTER ABSORPTION OF HIGH QUANTITIES: Shock.

Section 12: Ecological Information

Toxicity to fish:
LC50 fishes 1: 138 mg/l (96 h; Pisces; Pure substance)
LC50 fish 2: 100 - 1000 mg/l (Pisces; Pure substance)
LC50 other aquatic organisms 1: 100 - 1000 mg/l (96 h; Protozoa; Pure substance)
The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Section 13 Disposal Considerations

State and local laws governing disposal of materials can differ. Ensure proper disposal compliance with proper authorities before disposal.

Section 14: Transportation Information

USA DOT & ADR/RID:
Proper shipping name: Phosphoric acid solution
Hazard Class: 8
Packaging group: III
UN Number: UN1805
IATA:
Proper shipping name: Phosphoric acid solution
Hazard Class: 8
Packaging group: III
UN Number: UN1805
IMO:
Proper shipping name: Phosphoric acid solution
Hazard Class: 8
Packaging group: III
UN Number: UN1805

Section 15: Regulatory Information

USA:
SARA Section 311/312 Hazard Classes: Immediate (acute) health hazard
SARA 302 Extremely Hazardous Substance: None present or none present in regulated quantities.
SARA 313 (TRI Reporting): None present or none present in regulated quantities.
TSCA 8(b) inventory: Listed
California Proposition 65: None
HMIS (Perceived): Health Hazard: 3, Fire Hazard: 0, Reactivity: 1, Personal Protection: J
NFPA (Perceived): Health: 3, Flammability: 0, Reactivity: 1

Canada WHMIS: CLASS E: Corrosive solid.
Canada DSL: Listed.

EINECS EC Number: 231-633-2
DSCL (EEC):
R35- Causes severe burns. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39- Wear suitable gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Section 16: Other Information

C Corrosive
R35 Causes severe burns.
H290: May be corrosive to metals
H314: Causes severe skin burns and eye damage
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.